Assessments of Strength Anisotropy and Deformation Behavior of Banded Amphibolite Rocks

Assessment of strength anisotropy in transversely isotropic rocks has been one of the most challenging subjects in rock engineering. However, far too little attention has been paid to banded amphibolite rocks. This study aim to evaluate strength and deformation anisotropy behavior of banded amphibolite rocks. The dynamic mechanical tests including ultrasonic pulse test, uniaxial compressive strength, Brazilian test and deformability test were performed on drilled rock samples as a function of foliation plane angle (β = 0°, 30°, 60° and 90°). The results obtained have shown that the dynamic mechanical properties of amphibolite rocks have different values concerning banding plane. Compression and shear waves taken parallel to the foliation plane show highest values than those obtained in the other directions. Under uniaxial test, the banded amphibolite has a U-shaped anisotropy with maximum strength at β = 90° and minimum strength is obtained when β = 30°. Strength anisotropic index ranges between 0.96 and 1.47. It seems that the high range value of anisotropic index is mainly due to slight undulation of foliation planes, that being not perfectly straight. The results of elastic deformation test show that there is no clear dependence on microstructures characteristics of subtype-amphibolite rocks that controlling modulus “shape-anisotropy”. However, in this study, Young modulus values of amphibolite rocks with β follow both types of shape-anisotropy, “U-shape” and “decreased order-shaped”. Thus, this study recommended that further research be undertaken regarding the role of modulus “shape-anisotropy” within the same lithotype.     

Sensitivity Analysis of Selected Input Parameters for an Advanced Constitutive Model

Experimental results and simulated behavior of a medium plasticity clay were compared to investigate the performance of an advanced soil constitutive model. The soil model employed for this study was the 3-SKH model. The performance of this model was compared to the performance of two other critical state models; the Cam Clay (CC) and Modified Cam Clay (MCC) models. In addition, the influences of some of the input parameters on the performance of the 3-SKH model were investigated by performing sensitivity analyses. The comparisons demonstrated that the CC model was able to predict normally consolidated compressive behavior of the remolded medium plasticity clay. The compression behavior of overconsolidated clay was better captured by both the 3-SKH and CC models. For extension behavior of the normally consolidated samples, the MCC model performed better than the CC and 3-SKH models in predicting the stress path. The 3-SKH model was found to be very sensitive to varying the exponent in the hardening function. In particular, a difference between the evaluated values as small as 0.01 had a noticeable effect on the predicted stress–strain values for the overconsolidated compression and extension samples.     

Mixing processes in hydrothermal spring systems and implications for interpreting geochemical data: a case study in the Cappadocia region of Turkey

Mixing is a dominant hydrogeological process in the hydrothermal spring system in the Cappadocia region of Turkey. All springs emerge along faults, which have the potential to transmit waters rapidly from great depths. However, mixing with shallow meteoric waters within the flow system results in uncertainty in the interpretation of geochemical results. The chemical compositions of cold and warm springs and geothermal waters are varied, but overall there is a trend from Ca–HCO₃ dominated to Na–Cl dominated. There is little difference in the seasonal ionic compositions of the hot springs, suggesting the waters are sourced from a well-mixed reservoir. Based on δ¹⁸O and δ²H concentrations, all waters are of meteoric origin with evidence of temperature equilibration with carbonate rocks and evaporation. Seasonal isotopic variability indicates that only a small proportion of late spring and summer precipitation forms recharge and that fresh meteoric waters move rapidly into the flow system and mix with thermal waters at depth. ³H and percent modern carbon (pmC) values reflect progressively longer groundwater pathways from cold to geothermal waters; however, mixing processes and the very high dissolved inorganic carbon (DIC) of the water samples preclude the use of either isotope to gain any insight on actual groundwater ages.     

Introducing a Comprehensive Data Reduction and Uncertainty Propagation Algorithm for U‐Th Geochronometry with Extraction Chromatography and Isotope Dilution MC‐ICP‐MS

We present an open‐source algorithm in Mathematica application (Wolfram Research) with a transparent data reduction and Monte Carlo simulation of systematic and random uncertainties for U‐Th geochronometry by multi‐collector ICP‐MS. Uranium and thorium were quantitatively separated from matrix elements through a single U/TEVA extraction chromatography step. A rigorous calibrator‐sample bracketing routine was adopted using CRM‐112A and IRMM‐035 standard solutions, doped with an IRMM‐3636a ²³³U/²³⁶U ‘double‐spike’ to account for instrumental mass bias and deviations of measured isotope ratios from certified values. The mean of ²³⁴U/²³⁸U and ²³⁰Th/²³²Th in the standard solutions varied within 0.42 and 0.25‰ (permil) of certified ratios, respectively, and were consistent with literature values within uncertainties. Based on multiple dissolutions with lithium metaborate flux fusion, U and Th concentrations in USGS BCR‐2 CRM were updated to 1739 ± 2 and 5987 ± 50 ng g^?1 (95% CI), respectively. The measurement reproducibility of our analytical technique was evaluated by analysing six aliquots of an in‐house reference material, prepared by homogenising a piece of speleothem (CC3A) from Cathedral Cave, Utah, which returned a mean age of 21483 ± 63 years (95% CI, 2.9‰). Replicate analysis of ten samples from CC3A was consistent with ages previously measured at the University of Minnesota by single‐collector ICP‐MS within uncertainties.     

The formation of iron hydroxide coatings in an Emscher Marl: inverse reactive transport modeling of reactive surface area

The possible effects of iron oxide coatings on the reactive surface area of calcite in column experiments have been studied and then modeled numerically. A column with six compartments separated by teflon filters was packed with Emscher Marl (essentially calcite). The marl was initially mixed with corundum as an internal standard. Hydrochloric acid with pH 3 was percolated through the column for a given period, after which the mineralogical changes were quantified by X-ray diffraction ex-situ. Then, the column compartments were re-filled and again percolated with HCl. This procedure was repeated five times. The losses and gains of calcite in the column compartments provided the data basis for modeling the entire experiment with the reactive transport code TOUGHREACT using a kinetic rate law. The experimental results showed that during the first period, loss of calcite in the first compartment is about 50 % less than that determined from the theoretical analysis. This showed the entrance of acid into the higher compartments through preferential flow paths (wormholes) which was observed at the boundary between sample and cell wall. This pattern could also be verified by the relatively high Peclet and low Damköhler numbers, showing a strongly advection-dominant system. Apart from calcite dissolution, structural Fe²⁺ released from calcite oxidized and formed iron hydroxide (FeOOH) coatings along preferential fluid pathways. Despite specific assumptions such as using pure calcite in the model, a comparison between modeling results and lab observations is instructive. The simulated calcite change patterns in the most compartments are consistent with the experiments. Some discrepancies are noted in the last compartment, which may bring the attention to a need for model improvements.     

Using combined AHP–genetic algorithm in artificial groundwater recharge site selection of Gareh Bygone Plain,Iran

Flood spreading is one of the suitable strategies to control and benefit from floods which in turn improve the groundwater recharge, makes soil more fertile, and increases nutrients in soil. It is also a method for reusing sediment, which is usually wasted. Thus, selection of suitable areas for flood spreading and directing the flood water into permeable formations are amongst the most effective strategies in flood spreading projects. Having combined analytic hierarchy process (AHP) of multi-criteria decision analysis and genetic algorithm (GA) of artificial intelligence approaches, this paper addresses the problem of finding the most suitable area location for flood spreading operation in the Gareh Bygone Plain of Iran. To this end, the nine effective geodata layers including slope, alluvium thickness, geology, morphology, electrical conductivity, land use, drainage density, aquifer transmissivity, and elevation were prepared in geographic information system environment. This stage was followed by elimination of the exclusionary areas for flood spreading while determining the potentially suitable ones. Having closely examined the potentially suitable areas using the proposed methodology, the land suitability map for flood spreading was produced. The AHP and GA were used for ranking all the alternatives and weighting the criteria involved, respectively. The results of the study showed that most suitable areas for the artificial groundwater recharge are located in Quaternary Qft ₂ and Qsf geologic units and in morphological units of pediment and Alluvial fans with slopes not exceeding 2 %. Finally, further evidence for the acceptable efficiency of the integrated AHP–GA method in locating most suitable flood spreading areas have been provided by such significant spatial coincidence between the produced map and the control areas located near Kowsar research station, where the earlier flood spreading projects were successfully performed.     

The effects of human activities and different land-use on trace element pollution in urban topsoil of Isfahan (Iran)

The excessive input of trace elements into urban soil has become one of the most important concerns in industrial and crowded cities all over the world. The contamination of urban soils can affect the health of people living in urban areas, and the surrounding ecosystems. Current study was conducted to assess the effects of human activities as well as different land-use on accumulation of trace elements in urban topsoil and also identify the potential risks to human health in Isfahan (Iran). A total of 95 topsoil samples were taken from different localities of Isfahan City and analyzed for Zn, Pb, Cu and Cr using the atomic absorption spectrophotometric method. Pollution index (PI) was calculated for each trace element to identify the rate of trace element accumulation with respect to the background values. Land-use map and geochemical maps were also created for evaluating of spatial distribution of pollution index and trace elements’ concentration in the studied area. Overlapping the concentrations’ map and land-use map revealed that the highest values of pollution index and trace elements’ concentration were located in central part of the city and highways with a great vehicle traffic load and also in the vicinity of industrial factories that increased potential health hazards to the local community. On the other hand, lowest values of trace elements were located in green-lands with strict vehicle traffic laws. These results indicated that different land-use and human activities have affected quality of urban topsoil of Isfahan resulting in great apprehensions regarding public health in crowded parts of the city.     

Coupling effect of ozone column and atmospheric infrared sounder data reveal evidence of earthquake precursor phenomena of Bam earthquake,Iran

Understanding the source mechanism of earthquakes may be the key to predict earthquakes. The testing of radioactive radiations and reactionary hypothesis of gases before and after quake events can help predict and monitor earthquake occurrence. In this study, the Atmospheric Infrared Sounder (AIRS) and the column ozone (O₃) were applied to evaluate the December 26, 2003 earthquake of Bam city in western Iran. The results show that ozone concentration (column density) decreased about 30 DU and or 807?×?10E15/cm² molecules. Using high-resolution AIRS data for the study area, we were able to discriminate gases that formed and changed before the main shock at least a day before the occurrence of the quake in Bam.     

Geochemical modeling and isotope analysis of the shallow groundwater aquifer of Baghdad Area

Baghdad City is characterized by high population density and wide variation in land use. It is covered by Quaternary flood plain deposits of variable nature where silt is the predominant component. The shallow aquifer is unconfined to semi-confined at some locations. The hydraulic properties of the aquifer are highly variable in the study area. A study of this groundwater shallow aquifer and the hydrochemical relation with the Tigris River were conducted using geochemical modeling approach. Baghdad Meteoric Water Line (BMWL) was also constructed using data of stable isotopes of hydrogen and oxygen. The hydrochemical parameters of the Tigris River show significant differences at high and low flow conditions, and there are clear difference among the selected stations. Groundwater parameters show also significant spatial and temporal variations in major and minor elements concentrations. Geochemical modeling results indicate that dissolution of dolomite, gypsum, chlorite, siderite, chalcedony, cation exchange of Ca²⁺/Na⁺ and precipitation of calcite, illite, kaolinite, and hematite are the main chemical reactions in the Rasafa side, whereas no specific reactions can be shown in the Karkh side. Mixing models of the shallow groundwater and Tigris River water show various patterns affected by other factors such as the aquifer recharge and evaporation, especially at the most shallow parts. The BMWL has been defined by the equation $ {\delta^2}\mathrm{H} = 8.6\ {\delta^{18}}\mathrm{O} + 17.48 $ and the stable isotopes of hydrogen and oxygen reveal different signatures in the Karkh and Rasafa sides, where clear zonation at Rasafa can be observed. We conclude that recharge water undergoes significant evaporation through its transit to the aquifer.     

A microseismic experiment in Abu Dhabi,United Arab Emirates: implications for carbonate reservoir monitoring

A microseismic experiment utilizing a single downhole array of eight 3-component receivers was conducted in an offshore oilfield in the emirate of Abu Dhabi in the United Arab Emirates. The Lower Cretaceous Thamama Group is the major carbonate reservoir in the field producing from six zones. Microseismic data was acquired in conjunction with gas injections that took place in the Thamama IV A and IV B reservoirs during 9 days of acquisition. The aim of the experiment was to monitor the microseismic activity arising in the carbonate reservoirs as a result of gas injection. A total of 103 microseismic events were detected from two of the receivers. For the majority of these events, there were no well-defined P wave arrivals, probably due to the presence of strong background noise and the very weak microseismic signals. The results from this experiment indicate that the detected events are probably related to the microseismic activities caused by the gas injection within the Thamama IV B reservoir. Therefore, downhole microseismic monitoring methods can potentially provide valuable information about the fracture systems within the carbonate reservoirs of Abu Dhabi's oilfields.