Grampian migmatites in the Buchan Block,NE Scotland

Rocks exposed along the Scottish coast between Fraserburgh and Inzie Head contain information critical to understanding the evolution of the Buchan Block, the type locality for low‐P, high‐T regional metamorphism, and its relationship with the rest of the Grampian terrane, one of the major tectonostratigraphic components of the Scottish Caledonides. The ~8 km long section traverses a regional network of shear zones and, at the highest grades around Inzie Head, passes into the core of the Buchan Anticline, a large‐scale open fold that is commonly regarded as a late structure, post‐dating metamorphism. The metasedimentary rocks increase in grade from upper amphibolite to granulite facies and preserve unequivocal evidence for partial melting. The diatexite migmatites around Inzie Head, along with other gneissose units within the Buchan Block, have been regarded as allochthonous Precambrian basement rocks that were thrust into their current position during the Grampian orogenesis. However, field observations show that the onset of in situ partial melting in metapelitic rocks, which was associated with the formation of garnet‐bearing aplites and associated pegmatites, occurred around Fraserburgh, where shear fabrics are absent. Thus, the rocks preserve a continuous metamorphic field gradient that straddles the shear zone network. This observation supports an alternative interpretation that anatexis was the result of mid‐Ordovician (Grampian) metamorphism, rather than an older tectonothermal event, and that the Inzie Head gneisses are autochthonous. Using an average mid‐Dalradian pelite as a plausible representative protolith, phase equilibria modelling satisfactorily reproduces the observed appearance and disappearance of key minerals providing that peritectic garnet produced with the first formed melts (represented by the garnet‐bearing aplites) depleted the source rocks in Mn. The modelled metamorphic field gradient records a temperature increase of at least 150 °C (from ~650 °C near Fraserburgh to in excess of 800 °C at Inzie Head) but is isobaric at pressures of 2.7–2.8 kbar, suggesting the Buchan Anticline developed synchronous with partial melting. The Buchan Anticline is likely an expression of crustal thinning and asthenospheric upwelling, which produced voluminous gabbroic intrusions that supplied the heat for Buchan metamorphism.     

Measured river leakages using conventional streamflow techniques: the case of Souhegan River, New Hampshire, USA

Multiple streamflow measurements were made at coupled discharge measurement stations to quantify rates of aquifer recharge and discharge on two reaches of the Souhegan River, New Hampshire, USA, flowing within a glacial-drift river-valley aquifer. The reaches included a predominantly losing (aquifer recharge) reach and a variable (aquifer recharge and discharge) reach located downstream of the former reach. River leakage, the differential between coupled upstream and downstream streamflow measurements along a reach, varied by almost 30 cubic feet per second (ft³/s) (0.85 m³/s) along the two reaches. The upper reach averaged 3.94 ft³/s (0.11 m³/s) loss whereas the lower reach averaged 4.85 ft³/s (0.14 m³/s) gain. At the upper reach, 13 losses were measured out of 19 coupled measurements. At the lower reach, ten out of 13 coupled measurements indicated gains in flow and suggest that this reach is primarily a gaining river reach. An important factor in river leakage appears to be antecedent trends in river stage. At the upper reach, gains were measured only during periods of declining river stage. Conversely, at the lower reach, streamflow loss was measured primarily during periods of rising river stage. Although some tendencies exist, several factors complicate the analysis of river leakage, most notably the inaccuracies in computed stream discharge.     

Zwei Diskussionsbeiträge zu: „Präkambrische Itabirite und Uran-Gold-Konglomerate als geochemische Zeitmarken in der Erdevolution“ von W. Fiebiger,Geol. Rdsch., 65, S. 1035–1055

Ohne Zusammenfassung     

Mg isotope constraints on soil pore-fluid chemistry: Evidence from Santa Cruz, California

Mg isotope ratios (²⁶Mg/²⁴Mg) are reported in soil pore-fluids, rain and seawater, grass and smectite from a 90 kyr old soil, developed on an uplifted marine terrace from Santa Cruz, California. Rain water has an invariant ²⁶Mg/²⁴Mg ratio (expressed as δ²⁶Mg) at −0.79 ± 0.05‰, identical to seawater δ²⁶Mg. Detrital smectite (from the base of the soil profile, and therefore unweathered) has a δ²⁶Mg value of 0.11‰, potentially enriched in ²⁶Mg by up to 0.3‰ compared to the bulk silicate Earth Mg isotope composition (although within the range of all terrestrial silicates). The soil pore-waters show a continuous profile with depth for δ²⁶Mg, ranging from −0.99‰ near the surface to −0.43‰ at the base of the profile. Shallow pore-waters (<1 m) have δ²⁶Mg values that are similar to, or slightly lower than the rain waters. This implies that the degree of biological cycling of Mg in the pore-waters is relatively small and is quantified as <32%, calculated using the average Mg isotope enrichment factor between grass and rain (δ²⁶Mg_grass-δ²⁶Mg_rain) of 0.21‰. The deep pore-waters (1-15 m deep) have δ²⁶Mg values that are intermediate between the smectite and rain, ranging from −0.76‰ to −0.43‰, and show a similar trend with depth compared to Sr isotope ratios. The similarity between Sr and Mg isotope ratios confirms that the Mg in the pore-waters can be explained by a mixture between rain and smectite derived Mg, despite the fact that Mg and Sr concentrations may be buffered by the exchangeable reservoir. However, whilst Sr isotope ratios in the pore-waters span almost the complete range between mineral and rain inputs, Mg isotopes compositions are much closer to the rain inputs. If Mg and Sr isotope ratios are controlled uniquely by a mixture, the data can be used to estimate the mineral weathering inputs to the pore-waters, by correcting for the rain inputs. This isotopic correction is compared to the commonly used chloride correction for precipitation inputs. A consistent interpretation is only possible if Mg isotope ratios are fractionated either by the precipitation of a secondary Mg bearing phase, not detected by conventional methods, or selective leaching of ²⁴Mg from smectite. There is therefore dual control on the Mg isotopic composition of the pore-waters, mixing of two inputs with distinct isotopic compositions, modified by fractionation. The data provide (1) further evidence for Mg isotope fractionation at the surface of the Earth and (2) the first field evidence of Mg isotope fractionation during uptake by natural plants. The coherent behaviour of Mg isotope ratios in soil environments is encouraging for the development of Mg isotope ratios as a quantitative tracer of both weathering inputs of Mg to waters, and the physicochemical processes that cycle Mg, a major cation linked to the carbon cycle, during continental weathering.     

ERRORS IN DEPTH DETERMINATION CAUSED BY WAVES IN THROUGH-WATER PHOTOGRAMMETRY

The determination of depths in shallow water from aerial platforms will become increasingly important as exploitation of coastal resources intensifies. Until a theoretical study of the errors in depth which could be reasonably expected from two-media photogrammetry was made by Okamoto in 1982, there was little relevant literature apart from some isolated case studies. This paper examines the magnitude and distribution of errors in depth caused by the presence of waves on the water surface. The effects of random errors of observational measurement, in combination with waves, are assessed. A conclusion is reached that the traditional method of underwater depth calculation should be modified when the scale of the two media photography is greater than 1:4000.     

Testing the Models for Jet Generation with Hubble Space Telescope Observations

Many magneto-hydrodynamic (MHD) models have been developed to describe the acceleration and collimation of stellar jets, in the framework of an infall/outflow process. Thanks to high angular resolution instrumentation, such as the one on-board the Hubble Space Telescope (HST), we are finally able to test observationally the proposed ideas. We present the results obtained by us from the first 0”.1 resolution spectra of the initial portion (within 100–200 AU from the source) of the outflows from visible T Tauri stars, taken with the Space Telescope Imaging Spectrograph (STIS). We obtain the jet morphology, kinematics and excitation in different velocity intervals, and we derive the jet mass and momentum fluxes. These results confirm the predictions of magneto-centrifugal models for the jet launch. Recently we have also found indications for rotation in the peripheral regions of several flows. The derived rotational motions appear to be in agreement with the expected extraction of angular momentum from the star/disk system caused by the jet, which in turn allows the star to accrete up to its final mass. Improvements to resolution are expected from observations with STIS in the ultraviolet, and with the forthcoming AMBER spectrometer to be mounted at the VLTI.     

A METHOD FOR THE IDENTIFICATION AND ELIMINATION OF CONTAMINATION DURING CARBON ISOTOPIC ANALYSES OF EXTRATERRESTRIAL SAMPLES

The study of carbon abundance and isotopic composition in extraterrestrial samples is fraught with problems related to contamination in the terrestrial environment and during sample handling. A stepped combustion method is described which demonstrates that progress can be made towards resolving the indigenous species from contamination which for the most part burns at low temperature (< 425 ± 25 ±C). The proposed method is not applicable to samples which have indigenous phases burning at low temperatures e.g. the C1 and C2 carbonaceous chondrites. A number of examples where its application is possible are given. Even meteorites collected immediately after their fall, such as Allende, contain a proportion of extraneous carbon which has deleterious effects on any bulk estimate of isotopic composition. “Falls” which have spent a considerable time in museum collections and “finds” (other than Antarctic samples) can be considered as grossly contaminated. Bulk isotope and carbon abundance measurements in the literature for most samples having less than 1 wt% C are thus of questionable value. Antarctic samples have much less contamination of an organic nature but all seem to contain a weathering component which can be easily recognised and hence disregarded in estimates of bulk composition. Stepped combustion, applied to an Apollo 11 lunar soil which has not been specially stored and which now contains, due to contamination, nearly twice as much carbon as when originally collected, can still afford data closely resembling those obtained from the sample when it was first returned to Earth.     

Apparent and real bias in numerical transfer functions in palaeolimnology

We present an evaluation of the procedure by which model prediction bias is examined in palaeolimnological transfer function inference models. We argue that most of the prediction biases commonly reported in the literature are, in fact, fallacious, and are the artificial consequence of the inappropriate manner in which residuals are traditionally examined. We show that the extent of the specious model bias is entirely predictable from first principles and is essentially determined by the strength of the predictive model. We suggest that the analysis of residuals should always be examined as a function of the model's predictions and we discuss the implications of the old and new approaches.