Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.     

Performance of Jacobi preconditioning in Krylov subspace solution of finite element equations

This paper examines the performance of the Jacobi preconditioner when used with two Krylov subspace iterative methods. The number of iterations needed for convergence was shown to be different for drained, undrained and consolidation problems, even for similar condition number. The differences were due to differences in the eigenvalue distribution, which cannot be completely described by the condition number alone. For drained problems involving large stiffness ratios between different material zones, ill‐conditioning is caused by these large stiffness ratios. Since Jacobi preconditioning operates on degrees‐of‐freedom, it effectively homogenizes the different spatial sub‐domains. The undrained problem, modelled as a nearly incompressible problem, is much more resistant to Jacobi preconditioning, because its ill‐conditioning arises from the large stiffness ratios between volumetric and distortional deformational modes, many of which involve the similar spatial domains or sub‐domains. The consolidation problem has two sets of degrees‐of‐freedom, namely displacement and pore pressure. Some of the eigenvalues are displacement dominated whereas others are excess pore pressure dominated. Jacobi preconditioning compresses the displacement‐dominated eigenvalues in a similar manner as the drained problem, but pore‐pressure‐dominated eigenvalues are often over‐scaled. Convergence can be accelerated if this over‐scaling is recognized and corrected for. Copyright © 2002 John Wiley & Sons, Ltd.     

Sub-micron scale distributions of trace elements in zircon

Sub-micron scale zoning of Ti concentrations and correlations between concentrations of Ti and other trace elements (P, Ce, and Y) and cathodoluminescent (CL) banding is observed in natural zircons. Ion images were made using the Caltech Microanalysis Center’s CAMECA NanoSIMS 50L with an O⁻ primary beam focused to ~300 nm on the sample surface. The high spatial resolution of this technique allows for interrogation of chemical variations at or below the scale of CL banding in natural zircons. Images produced in this manner display two types of correlations among Ti, P, Ce, and Y (which appears to be a proxy for CL intensity): strong (correlation coefficients >0.8) and subtle (correlation coefficients ~0.15–0.4). Strongly correlated images, which display Ti variations of ca. a factor of 3 between adjacent CL bands and overall elevated trace element concentrations in CL-dark bands, were found within an oscillatory-zoned, trace element enriched sector of a CL sector-zoned zircon. Three possible causes for such correlations include: temperature-dependent equilibrium partitioning, trace element partitioning limited by diffusion in the host melt and surface-controlled, non-equilibrium growth. Comparison of our data with the expected results of these processes suggests that: (1) Ti partitioning in zircon is dependent upon non-equilibrium effects in addition to temperature and/or (2) the incorporation of elements that co-vary with Ti in zircon (e.g., Y, P and Ce) is also temperature-dependent. Sub-micron scale, high-Ti regions are also found within Proterozoic Adirondack and >4 Ga Jack Hills zircons as well as trace element enrichments (including Ti) along cracks within Jack Hills zircons.     

Late Tertiary paleoclimatic interpretation from lacustrine rhythmites in the Gray Fossil Site,northeastern Tennessee,USA

The Gray Fossil Site (GFS) includes a small (<2 ha) paleosinkhole lake fill with an exceptionally well-preserved record of sedimentation and fossils from the latest Miocene to earliest Pliocene. The uppermost lacustrine stratigraphy is characterized by rhythmites that regularly alternate between coarse-grained and organic-rich (A) laminae and fine-grained, silty clay (B) laminae. Both the A and B components are almost exclusively comprised of exogenic sediment (including organic matter). Periodicities of 24 and 4.4 are recorded within a continuous 96 interpreted year sequence of rhythmite sediment. In a small lake with a poorly oxygenated bottom, the presence of laterally continuous laminated sediment that includes well-known periodicities in rhythmite thickness is interpreted as representing annually generated varves that correspond to seasonal variations in sedimentation. The distinctly larger fraction of medium sand-size quartz grains present within the A laminae, as well as the abrupt transitions between A and B components suggest that the rhythmites represent deposition during alternating high-energy and lower-energy seasons, which is consistent with a monsoonal precipitation pattern. The seasonal climate may relate to changes in the ocean circulation pattern prior to 4.6 Ma that resulted in an increased temperature and atmospheric pressure gradient between the east coast of North America and the Atlantic Ocean, but this climate phase seems to be only a temporary condition, as underlying and overlying sediment are both consistent with drier conditions. The periodicity at 24 interpreted years is consistent with the well-known Hale solar cycle. The 4.4 interpreted-year periodicity occurs within the ENSO frequency band, and if this documentation of ENSO-like interannual climate change is correct, then it suggests that ENSO operated at times during the warm Earth conditions characterizing the late Tertiary.     

From Soda Bottles To Super Labs: An Analysis Of North America's Dual Methamphetamine Production Networks

This article uses the global production network perspective to analyze the various actors involved in the production and distribution of methamphetamine in North America. The paper analyzes the organization and operation of the two dominant network typologies at work in the United States: small toxic labs and Mexican drug‐trafficking organizations. Particular emphasis is placed on how the networks have adapted to changes in the regulatory context in which they operate. I conclude with potential policy recommendations for curtailing methamphetamine production within both networks.     

The geography of water conflict and cooperation: internal pressures and international manifestations

Studies on transboundary water conflict and cooperation generally consider interstate relations over shared water resources as distinct from intrastate relations. While connections have been made between international water relations and regional relationships in general, it is conceivable that international water conflict and cooperation may also be influenced by domestic water events and vice versa. This paper seeks to investigate the dynamics of water interactions across geographic scale and their relationship to broader international affairs. The research approach involves the creation of an analytical framework for assessing possible linkages between external and internal interactions over freshwater resources. The framework is applied to three case studies – the Middle East, South Asia and Southern Africa – utilizing 'event data'. To validate the findings from the quantitative analyses, the results are compared with conventional qualitative understandings of water and overall relations in the three regions. The comparison demonstrates not only the efficacy of the analytical framework in general, but also highlights, at least in terms of the specific case studies selected, the disparate water dynamics across geographic regions and the importance of considering water events, both national and international, within larger political and historical contexts.