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The release of biocides, such as copper (Cu), from antifouling (AF) coatings on vessel hulls represents a significant proportion of overall Cu loading in those harbors and estuaries where substantial numbers of small craft or large vessels are berthed. Copper release rates were measured on several self-polishing, tin-free coatings and an ablative Cu reference coating applied to steel panels using three measurement methods. The panels were exposed in natural seawater in San Diego Bay, and release rates were measured both in the laboratory and field over 2 years. Results with the static (20 cm x 30 cm) panels indicated that Cu release rates were initially high (25-65 microg Cu cm(-2)day(-1)), with a large range of values between paint types. Release rates declined to substantially lower rates (8-22 microg cm(-2)day(-1)) with reduced variability within 2 months. Release rates continued to decrease over time for approximately 6 months when relatively constant release rates were observed for most coatings. Over time, relative differences in Cu release rates measured by three exposure methods decreased, with all coatings exhibiting similar behavior toward the end of the study. Lowest overall Cu release rates were observed with the self-polishing experimental paint no. 7 in static-dynamic and in situ treatments. The highest periodic release rates were measured from panels that experienced periods of both static and dynamic exposure (8.7 ms(-1) rotation). The lowest release rates were measured from panels that experienced static, constant depth exposure, and where release rates were evaluated in situ, using a novel diver-deployed measurement system. Results from this in situ technique suggests that it more closely reflects actual Cu release rates on vessel hulls measured with intact natural biofilms under ambient conditions than measurements using standardized laboratory release rate methods. In situ measurements made directly on the AF surface of vessels demonstrated typically lower release rates than from the panel studies, averaging 8.2 microg cm(-2)day(-1) on pleasure craft, and 3.8 microg cm(-2)day(-1) on Navy vessels. The data suggest that the presence of an established biofilm likely serves to moderate the release of Cu from field-exposed antifouling coatings both on panels and hull surfaces. 相似文献
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软土深层搅拌桩的水泥土抗腐蚀性室内试验 总被引:10,自引:0,他引:10
结合深港西部通道填海区深层搅拌桩在滨海地下水环境中施工的需要,对水泥土在自来水、地下水、海水及Na2SO4溶液环境下的抗腐蚀性进行了室内研究,研究表明以纯水泥为固化剂的水泥土在腐蚀性地下水环境中的抗腐蚀性能较差,增加矿渣、粉煤灰的含量,能增强水泥土抗腐蚀性;分析了固化剂中矿渣、粉煤灰掺入量对水泥土抗压强度及抗腐蚀性的影响规律,即固化剂掺入比不变的情况下,用矿渣、粉煤灰替代部分水泥能大幅度提高水泥土的抗压强度,同时改善其抗腐蚀性;得出了抗腐蚀性能良好的水泥土配方,即矿渣、粉煤灰的质量占固化剂的40%~60%,可供同类工程借鉴. 相似文献
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一、问题的提出在金刚石钻进中,人们往往采取控制机械钻速的办法来提高钻头寿命,降低每米钻头费用,许多队规定时效控制在3—3.5m/h以内。但也有的认为控制时效势必影响钻进效率的提高,这时即使钻头寿命较长,也会增加钻探成本。如安徽地质某队16号钻机,对时效不进行硬性限制,不把钻头寿命当作主要指标,注意充分发挥金刚石高钻速的优势,连续取得了高效率、低成本的好成绩。该机在1982年和1983年用不同钻速完成的工作量分别见表1和表2。 相似文献
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To reduce sediment exports discharging to the Great Barrier Reef (GBR), it is essential to identify the sources of exported sediment. We used modelling of spatial sediment budgets (the SedNet model) to identify sources and deposition of sediment as it is transported through river networks. Catchments with high levels of land clearing, cattle grazing and cropping show the largest increases in sediment export compared with natural conditions. Hillslope erosion supplies 63% of sediment to the rivers. Gully erosion and riverbank erosion are lower sources of sediment at the GBR catchment scale, but they are important in some catchments. Overall, 70% of sediment exported from rivers comes from just 20% of the total catchment area, showing that much of the problem can be addressed in a relatively small area. This is a much more manageable problem than trying to reduce erosion across the entire GBR catchment. Areas of high contribution are all relatively close to the coast because of the high erosion and high sediment delivery potential. 相似文献