Dissolution of Quartz, Albite, and Orthoclase in H2O-Saturated Haplogranitic Melt at 800{degrees}C and 200 MPa: Diffusive Transport Properties of Granitic Melts at Crustal Anatectic Conditions

We have conducted experiments on dissolution of quartz, albite,orthoclase, and corundum into H₂O-saturated haplogranite meltat 800°C and 200 MPa over a duration of 120–1488 hwith the aim of ascertaining the diffusive transport propertiesof granitic melts at crustal anatectic temperatures. Cylindersof anhydrous starting glass and a single mineral phase (quartzor feldspar) were juxtaposed along flat and polished surfacesinside gold or platinum capsules with 10 wt % added H₂O. Concentrationprofiles in glass (quenched melt) perpendicular to the mineral–glassinterfaces and comparison with relevant phase diagrams suggestthat melts at the interface are saturated in the dissolvingphases after 384 h, and with longer durations the concentrationprofiles are controlled only by diffusion of components in themelt. The evolution of the concentration profiles with timeindicates that uncoupled diffusion in the melt takes place alongthe following four linearly independent directions in oxidecomposition space: SiO₂, Na₂O, and K₂O axes (Si-, Na-, and K-eigenvectors,respectively), and a direction between the Al₂O₃, Na₂O, andK₂O axes (Al-eigenvector), such that the Al/Na molar ratio isequal to that of the bulk melt and the Al/(Na + K) molar ratiois equal to the equilibrium ASI (= mol. Al₂O₃/[Na₂O + K₂O])of the melt. Experiments in which a glass cylinder was sandwichedbetween two mineral cylinders—quartz and albite, quartzand K-feldspar, or albite and corundum—tested the validityof the inferred directions of uncoupled diffusion and exploredlong-range chemical communication in the melt via chemical potentialgradients. The application of available solutions to the diffusionequations for the experimental quartz and feldspar dissolutiondata provides diffusivities along the directions of the Si-eigenvectorand Al-eigenvector of (2·0–2·8) x 10^–15m²/s and (0·6–2·4) x 10^–14 m²/s, respectively.Minimum diffusivities of alkalis [(3–9) x 10^–11m²/s] are orders of magnitude greater than the tetrahedral componentsof the melt. The information provided here determines the rateat which crustal anatexis can occur when sufficient heat issupplied and diffusion is the only mass transport (mixing) processin the melt. The calculated diffusivities imply that a quartzo-feldspathicsource rock with initial grain size of 2–3 mm undergoinghydrostatic, H₂O-saturated melting at 800°C (infinite heatsupply) could produce 20–30 vol. % of homogeneous meltin less than 1–10 years. Slower diffusion in H₂O-undersaturatedmelts will increase this time frame. KEY WORDS: chemical diffusion; haplogranite; mineral dissolution experiments; crustal anatexis     

Synthesis of Staurolite in Melting Experiments of a Natural Metapelite: Consequences for the Phase Relations in Low-Temperature Pelitic Migmatites

We document experiments on a natural metapelite in the range650–775°C, 6–14 kbar, 10 wt % of added water,and 700–850°C, 4–10 kbar, no added water. Staurolitesystematically formed in the fluid-present melting experimentsabove 675°C, but formed only sporadically in the fluid-absentmelting experiments. The analysis of textures, phase assemblages,and variation of phase composition and Fe–Mg partitioningwith P and T suggests that supersolidus staurolite formed at(near-) equilibrium during fluid-present melting reactions.The experimental results are used to work out the phase relationsin the system K₂O–Na₂O–FeO–MgO–Al₂O₃–SiO₂–H₂Oappropriate for initial melting of metapelites at the upperamphibolite facies. The P–T grid developed predicts theexistence of a stable P–T field for supersolidus staurolitethat should be encountered by aluminous Fe-rich metapelitesduring fluid-present melting at relatively low temperature andintermediate pressures (675–700°C, 6–10 kbarfor X_H2O = 1, in the KNFMASH system), but not during fluid-absentmelting. The implications of these findings for the scarcityof staurolite in migmatites are discussed. KEY WORDS: metapelites; migmatites; partial melting; P–T grid; staurolite     

RUNOFF PRODUCTION AND EROSION PROCESSES ON A DEHESA IN WESTERN SPAIN*

ABSTRACT. Runoff generation and soil erosion were investigated at the Guadalperalón experimental watershed (western Spain), within the land‐use system known as dehesa, or open, managed evergreen forests. Season and type of surface were found to control runoff and soil‐loss rates. Five soil units were selected as representative of surface types found in the study area: hillslope grass, bottom grass, tree cover, sheep trails, and shrub cover. Measurements were made in various conditions with simulated rainfall to gain an idea of the annual variation in runoff and soil loss. Important seasonal differences were noted due to surface cover and moisture content of soil, but erosion rates were determined primarily by runoff. Surfaces covered with grass and shrubs always showed less erosion; surfaces covered with holm oaks showed higher runoff rates, due to the hydrophobic character of the soils. Concentrations of runoff sediment during the simulations confirmed that erosion rates at the study site depended directly on the sediment available on the soil surface.     

EVIDENCES FROM HISTORICAL DOCUMENTS OF LANDSCAPE EVOLUTION AFTER LITTLE ICE AGE OF A MEDITERRANEAN HIGH MOUNTAIN AREA,SIERRA NEVADA,SPAIN (EIGHTEENTH TO TWENTIETH CENTURIES)

The Sierra Nevada is the highest mountain system on the Iberian Peninsula (Mulhacén 3482 m; Veleta 3308 m) and is located in the extreme SE region of Spain (lat 37°N, long 3°W). Bibliographic resources, particularly from the eighteenth to twentieth centuries, provide insights into the changing summit landscape as the effects of cold, ice, snow and wind shaped its morphology. The selected references emphasize the Sierra's evolving climate reflected in the glaciers and snow hollows, and in the sparse vegetation above certain altitudes. Scientists had established bioclimatic conditions for the entire range in the early nineteenth century, and their works reflect the progression of ideas, particularly in the area of natural sciences, that influenced the period chosen for this study. This information, in addition to current knowledge about the morphogenetic dynamics of the Sierra Nevada, provides the basis for a comparison of the dominant environments from the Little Ice Age to the present, using the most significant high mountain morphological features as a guide. The most relevant findings indicate that cold climate processes (soli‐gelifluction, frost creep and nivation) were more predominant during the eighteenth and nineteenth centuries than they are today.