The effect of species on lacustrine δ18Odiatom and its implications for palaeoenvironmental reconstructions

The oxygen isotope composition of diatom silica (δ¹⁸O_diatom) is increasingly being used to reconstruct climate from marine and lacustrine sedimentary archives. Although diatoms are assumed to precipitate their frustule in isotopic equilibrium with their surrounding water, it is unclear whether internal processes of a given species affect the fractionation of oxygen between the water and the diatom. We present δ¹⁸O_diatom data from two diatom size fractions (3–38 and >38 µm) characterized by different species in a sediment core from Heart Lake, Alaska. Differences in δ¹⁸O_diatom between the two size fractions varies from 0 to 1.2‰, with a mean offset of 0.01‰ (n = 20). Fourier transform infrared spectroscopy confirms our samples consist of pure biogenic silica (SiO₂) and δ¹⁸O_diatom trends are not driven by contamination. The maximum offset is outside the range of error, but the mean is within analytical error of the technique (± 1.06‰), demonstrating no discernible species‐dependent fractionation in δ¹⁸O_diatom. We conclude that lacustrine δ¹⁸O_diatom measurements offer a reliable and valuable method for reconstructing δ¹⁸O_water. Considering the presence of small offsets in our two records, we advise interpreting shifts in δ¹⁸O_diatom only where the magnitude of change is greater than the combined analytical error.     

Optimizing bioventing in shallow vadose zones and cold climates

Abstract

This paper describes a bioventing study design and initial activities applied to a JP-4 jet fuel spill at Eielson Air Force Base, Alaska. The primary objectives of the project were to investigate the feasibility of using bioventing technology to remediate JP-4 jet fuel contamination in a sub-arctic environment and to determine to what degree the biodegradation rate of JP-4 soil contaminants could be enhanced by increasing soil temperature, both actively by circulating heated groundwater and passively by utilizing solar energy. Biodegradation rates at the bioventing site remained relatively high during the winter months in the active-warming test plot and were consistently higher than those observed in the passive-warming and control test plots. These studies suggest that an active-warming system operated in conjunction with bioventing is a useful method for remediating fuel-contaminated areas in cold climates.     

RECENT SPEED‐UP OF AN ALPINE ROCK GLACIER: AN UPDATED CHRONOLOGY OF THE KINEMATICS OF OUTER HOCHEBENKAR ROCK GLACIER BASED ON GEODETIC MEASUREMENTS

Surface velocities have been regularly monitored at the rock glacier in Outer Hochebenkar, Ötztal Alps, Austria since the early 1950s. This study provides an update to previously published surface velocity time series, showing mean profile velocities of four cross profiles since the beginning of the measurements (1951,1954, 1997; depending on the profile), as well as single block displacements from 1998 to 2015. Profiles P1, P2 and P3 have moved between 42 and 90 m, at mean velocities between 0.70 and 1.48 m yr^–1, since they were first established in the early 1950s (1951/54). Profile P0, established in 1997, has since moved 13 m or 0.75 m yr^–1. An acceleration can be observed at all profiles since the late 1990s, with a particularly sharp velocity increase since 2010. All profiles reached a new maximum velocity in 2015, with 1.98 m yr^–1 at the slowest profile (P0) and 6.37 m yr^–1 at the fastest profile (P1). Year‐to‐year variations in profile velocities cannot be clearly attributed to inter‐annual variations of climatic parameters like mean annual air temperature, summer temperature, positive degree days, or precipitation. However, higher correlation is found between velocities and cumulative anomalies of air temperature (mean annual air temperature and positive degree days) and summer precipitation, suggesting that these parameters play a key role for the movement of the rock glacier. The lower profiles (P0, P1) show more pronounced year‐to‐year variations than the upper profiles (P2, P3). It is considered likely that processes other than climatic forcing (e.g. sliding, topography) contribute to the different velocity patterns at the four profiles.     

Geothermal field interpretation in south-central Kansas for parts of the Nemaha Anticline and flanking Cherokee and Sedgwick basins

The first assessment of temperature conditions in Kansas was made by geothermal gradient computations from temperature measurements in shallow boreholes, and these conditions are related to structural patterns, sedimentary cover and underlying basement properties. The area of south-central Kansas was selected for detailed study of geothermal character in relation to the geology. The aim was to quantify the relations and to determine the relationship of different variables of the temperature field. Input parameters included geothermal variables of gradient and temperature, and structure and sediment thickness. Two approaches were used: (1) the numerical computation of theoretical temperature-depth models based on conductive heat transfer, and (2) a map-comparison technique based on algebraic methods. The temperature field information usable for the map comparison is different in response to different measurements (nonequilibrium BHTs and temperatures from logged measurements in equilibrium). Derived from modelled results (plotted isotherms on cross-sections), a close relation between gradients and thermal conductivity of the sediments was confirmed. The most noticeable effect on the geothermal field, as noted quantitatively from the map-comparison study, is the relation of thickness of outcropping Permo-Pennsylvanian units because of their different thermal conductivity. The eastward increase of mean gradients is inversely related to the total sediment thickness, but this is mostly recognizable using the shallow temperature gradients. This dissimilarity gives additional evidence for a close link between gradients and thermal conductivity of the sediments in which the temperature measurements were made. The effect caused by the structure in deeper (older) units is not important and seems not to be significant, nor is the influence of the basement rock composition as indicated by the temperature modelling.     

GEOMORPHOLOGICAL THEORY OF THE HYDROLOGICAL RESPONSE

The geomorphological theory of the hydrological response, originated by Rodriguez-Iturbe and Valdes, is reviewed with reference to the general framework of the formulation of transport processes by travel time distributions. This review, by no means exhaustive of the publications on this subject, collects in a reasonably organic manner some relevant theoretical developments and a few significant applications.     

Dolomite characteristics and diagenetic model of the Calcari Grigi Group (Asiago Plateau,Southern Alps – Italy): an example of multiphase dolomitization

A multidisciplinary study, conducted over the carbonate platform deposits of the Liassic Calcari Grigi Group (Southern Alps), highlighted how the use of outcrop analogues can contribute to better define the distribution of dolomitic bodies related to fault networks, to characterize the petrophysical properties of the dolomitic sequence and unravel a complex diagenetic history. This study was carried out in the Asiago Plateau (southernmost part of the eastern Southern Alps, northern Italy) which provides excellent outcrops of the Jurassic Calcari Grigi Group. The dolomitization of the Jurassic sequence is variable in terms of stratigraphic extension and geographic distribution. In the studied localities the dolomitization is generally limited to the Mount Zugna Formation and is characterized by an undulatory front, with ‘sub‐vertical dolomitic chimneys’ along the major faults. Within this unit, and often associated with faults, stacked high‐porosity and permeability bed‐parallel dolomitic bodies are developed that show excellent petrophysical properties. The dolomitic intervals are characterized by pervasive unimodal and patchy polymodal dolomite crystals. Thin section, cathodoluminescence, isotopic and fluid inclusion analyses were used to constrain the paragenetic evolution of the sequence which is similar in all the studied localities. The first dolomitization stage is marked by zoned dolomite crystals with a dull luminescent core. The porosity is thought to have increased after this stage, with dark blue luminescent dolomite accompanied by the corrosion of older crystals. The appearance of saddle dolomite marks the onset of the porosity reduction stage, ending with the infilling of vugs and the remaining open pores with calcite cement. The diagenetic evolution locally stopped at the saddle dolomite stage with the complete occlusion of the remaining pores. Paragenetic and fluid‐inclusion data suggest an evolutionary trend of increasing temperatures and decreasing salinity toward brackish fluids responsible for dolomite and calcite precipitation. The integration of the available data seem to indicate that the diagenetic evolution of the study area is related to: (i) the interplay between evolving fluids (from marine to brackish); (ii) the burial of the sequence (increasing temperature); and (iii) the evolution of the hydrogeological system (fault and fracture network, fluid mixing). This complex paragenetic evolution is strongly linked to the evolution of the porosity framework that evolved from a good, widespread network in the early stages of the burial history to a confined system in the later stages due to reduction of porosity by the deposition of late calcite and dolomite cements.     

THE DENDROCLIMATOLOGICAL POTENTIAL OF AN ALPINE SHRUB,CASSIOPE MERTENSIANA,FROM MOUNT RAINIER,WA, USA

The application of dendrochronological techniques to shrubs found in arctic and alpine plant communities is opening previously untapped regions to the exploration of plant‐climate ecological relationships and climate reconstruction. In this pilot study, we present growth (1963–2004), reproduction (1963–2004), and stable carbon isotope ratio (1975–2004) chronologies for Cassiope mertensiana from a subalpine site in Mount Rainier National Park, Washington, USA. Based on simple linear correlation analysis, positive correlations characterize plant growth and previous year mean maximum temperature in April and June, suggesting the influence of temperature on snowpack and, in turn, on growing season length, plant and soil insulation, and nutrient and moisture availability. Plant growth and reproduction are significantly correlated with current year July mean maximum temperature and total precipitation, indicating the importance of a warm and extended growing season for optimal plant development. Using step‐wise multiple linear regression analysis, we developed a preliminary calibration model for July mean maximum temperature (R = 0.63), extending over the 1974–2004 time period. This archive has the potential to elucidate multi‐scale, spatially‐explicit, ecological and climatic information for alpine ecosystems situated along a north‐south transect from the southern Yukon to the Pacific Northwest of the United States.     

Mud volcanoes, olistostromes and Argille scagliose in the Mediterranean region

Tectonic and sedimentary mélanges, rocks with block-in-matrix fabric often referred to as 'chaotic', are widespread in the circum-Mediterranean collisional orogenic belts as well as in submerged Mediterranean Arcs. These rock types have been defined originally as 'Argille scagliose' (Bianconi, 1840) and 'olistostromes' (Flores, 1955, 1959) in the outcrops of the Apennine chain (Italy). Both terminology and concepts have undergone a rather complex evolution through time owing to the gradual recognition of similar chaotic bodies in all the circum-Mediterranean orogenic belts. Submarine mud volcanoes of the Mediterranean region, also composed by block-in-matrix, more commonly referred to as mud breccias, have a much younger history. These mud breccias were discovered in 1981 and, since then, a growing number of sea-going geophysical and geological expeditions have allowed the recognition of a major mud volcano belt in the Eastern Mediterranean and of a number of mud diapirs and mud volcano fields from the Black Sea to the Gulf of Cadiz. Structural, textural and genetic similarities between the mud breccias of the Mediterranean mud volcanoes and the olistostromes and Argille scagliose of the Apennines were noted from the very beginning, but the matter has not been the focus of any detailed study. In this paper, the use of the terms in the geological literature is analysed, the distribution of these rock units in the Mediterranean region explored and the assumed genetic processes are identified in order to formulate a common genetic model that can be applied to the evolution of the circum-Mediterranean sedimentary basins.