The pathway of mercury in contaminated waters determined by association with organic carbon (Tagus Estuary,Portugal)

Reactive dissolved Hg (Hg_R), non-reactive dissolved Hg (Hg_NR), particulate Hg (Hg_P), dissolved organic C (DOC), particulate organic C (POC), salinity and other interpretative parameters were determined in water samples collected in the North Channel and in adjacent areas of the Tagus estuary (Portugal). Higher concentrations of both dissolved and particulate Hg in the North Channel indicate a pollution source and raise the possibility of Hg escaping to adjacent areas by tidal action. This transport was confirmed by the increase of Hg_R with salinity and Hg_NR with DOC, along a longitudinal axis paralleling the North Channel. Apparently, Hg leaving this channel is progressively complexed by inorganic and organic ligands. Near the mouth of the estuary, values decreased reflecting dilution with seawater. Moreover the Hg_P:POC ratio also increased seaward, suggesting mixing with Hg enriched particles that escaped the North Channel, or incorporation of dissolved Hg species in river-derived particles. These results suggest that the pathway of anthropogenic Hg in contaminated waters may be identified by their enrichment in organic matter, both in the dissolved and particulate fraction.     

Exact cosmological solutions in Brans and Dicke's scalar-tensor theory,I

The exact solution is sought for the cosmological equations of Brans and Dicke's scalar-tensor theory when a power law exists between the gravitational constant and the radius of curvature of the universe. For the space of negative curvature no solution is possible. On the contrary for a closed space the gravitational constant and the radius of curvature increase linearly with respect to the age of the universe. The parameter of the scalar-tensor theory is necessarily negative and can be determined by the present values of the mass-density of the universe, the Hubble-constant and the gravitational constant. The solution has no analogy in Einstein's theory with vanishing cosmological constant, even when the deviations from Einstein's values of the solar relativistic effects are small.     

Analyzing ice dynamics using Sentinel-1 data at the Solheimajoküll Glacier,Iceland

ABSTRACT

The climate in southern Iceland has warmed over the last 70 years, resulting in accelerated glacier dynamics at the Solheimajoküll glacier. In this study, we compare glacier terminus locations from 1973 to 2018, to changes in climate across the study area, and we derive ice-surface velocities (2015–2018) from satellite remote-sensing imagery (Sentinel-1) using the offset-tracking method. There have been two regional temperature trends in the study period: cooling (1973–1979) and warming (1980–2018). Our results indicate a time lag of about 20 years between the onset of glacier retreat (?53 m/year since 2000) and the inception of the warming period. Seasonally, the velocity time series suggest acceleration during the summer melt season since 2016, whereas glacier velocities during accumulation months were constant. The highest velocities were observed at high elevations where the ice-surface slope is the steepest. We tested several scenarios to assess the hydrological time response to glacier accelerations, with the highest correlations being found between one and 30 days after the velocity estimates. Monthly correlation analyses indicated inter-annual and intra-annual variability in the glacier dynamics. Additionally, we investigate the linkage between glacier velocities and meltwater outflow parameters as they provide useful information about internal processes in the glacier. Velocity estimates positively correlate with water level and negatively correlate with water conductivity between April and August. There is also a disruption in the correlation trend between water conductivity and ice velocity in June, potentially due to a seasonal release of geothermal water.     

Electrical structure of the upper mantle beneath Central Europe: Results of the CEMES project

In the years 2001–2003, we accomplished the experimental phase of the project CEMES by collecting long-period magnetotelluric data at positions of eleven permanent geomagnetic observatories situated within few hundreds kilometers along the south-west margin of the East European Craton. Five teams were engaged in estimating independently the magnetotelluric responses by using different data processing procedures. The conductance distributions at the depths of the upper mantle have been derived individually beneath each observatory. By averaging the individual cross-sections, we have designed the final model of the geoelectrical structure of the upper mantle beneath the CEMES region. The results indicate systematic trends in the deep electrical structure of the two European tectonic plates and give evidence that the electrical structure of the upper mantle differs between the East European Craton and the Phanerozoic plate of west Europe, with a separating transition zone that generally coincides with the Trans-European Suture Zone.     

A Search for Warm Neutral Gas Associated with the Giant HII Region NGC 604

The characteristics of the halo gas and its interaction with the galactic disk in spiral galaxies are poorly known; this is particularly true for the warm neutral gas associated with HVCs and galactic chimneys. The detection of absorption features such as the NaI D or the CaII (H,K)lines is instrumental to study its detailed physical properties but requires very long integration times. In this work very deep optical spectra of NGC 604, the brightest giant HII region among the nearby spirals, are presented. The detection of two absorption components at LSR velocities -255 km/s and −20 km/s respectively, is reported; the first component is associated with the HII region. The inferred line width after deconvolution is 155 km/s; this large width is produced by the blending of the multiple absorption components produced by the diverse sources of internal motion (expanding shells and general turbulence). The radial velocity of the CaII absorption is slightly larger than the measured in the HII emission lines suggesting a possible flow of gas into the halo above the young star cluster. The large ratio x = W _λ (NaID_2)/W _λ (CaIIK) = 0.7indicates the probable presence of shocks which release Ca from the dust grains into the gas phase. The lower velocity component most likely trace galactic gas. This revised version was published online in July 2006 with corrections to the Cover Date.     

Changes in the onset and length of seasons from an ensemble of regional climate models over Spain for future climate conditions

This study analyses the length and onset of the four seasons based on the annual climatic cycle of maximum and minimum temperatures. Previous studies focused over climatically homogeneous mid-high latitude areas, employing fixed temperature thresholds (related to climatic features such as freezing point) that can be inadequate when different climate conditions are present. We propose a method related to the daily minimum and maximum temperature 25th and 75th point-dependent climatic percentiles. It is applied to an ensemble of regional climate models (RCMs) of 25-km horizontal resolution over the peninsular Spain and Balearic Islands, where a large variety of climatic regimes, from alpine to semi-desertic conditions, are present. First, baseline climate (1961–2000) ERA40-forced RCM simulations are successfully compared with the Spain02 daily observational database, following astronomical season length (around 90 days). This result confirms the validity of the proposed method and capability of the RCMs to describe the seasonal features. Future climate global climate model-forced RCMs (2071–2100) compared with present climate (1961–1990) simulations indicate the disappearance of winter season, a summer enlargement (onset and end) and a slight spring and autumn increase.     

Temporal and spatial variation of soil erosion in wooded rangelands of southwest Spain

Changes in land use are common in Mediterranean areas and are reported as having produced changes in the intensity of soil erosion. Dehesas are rangelands with a disperse tree cover, widespread in the south-western part of the Iberian Peninsula and similar ecosystems are also common in other areas with a Mediterranean climate. The aim of the present study is to analyse temporal and spatial variations of soil erosion rates estimated along three hillsides, located in two farms (Buitrera and Parapuños) in southwest Spain. To understand the temporal variation, soil erosion rates were studied in light of land use-management changes that took place during the last few centuries. Results indicate very low erosion rates prior to the 18^th century in both farms. In Buitrera, a first increase of soil loss rates was identified during the period 1831-1897, amounting to 7.4 t ha^-1 y^-1. A further increase took place during the 20^th century, reaching a mean erosion rate of 29.1 t ha^-1 y^-1. In Parapuños, data points to a significant increase from 1881 onwards, with an estimated mean erosion rate of 18.5 t ha^-1 y^-1. Those increases were presumably connected with an intensification of land use, such as cultivation and excessive livestock populations. Regarding spatial variation, the bare surface and the erosive power of run-off along the hillsides accounts for 76% of the soil erosion rates dispersion. At a local scale, the variability of erosion rates could not be explained, because of (i) uncertainty related to the micromorphology of the past soil surface and (ii) the role of tillage erosion in the past. However, the results obtained offer valuable data on the temporal and spatial variation of erosion rates in dehesas at the hillslope scale and a similar approach could be used for other rangelands with a disperse tree cover. © 2019 John Wiley & Sons, Ltd.     

Using a regional numerical weather prediction model for GNSS positioning over Brazil

The global navigation satellite system (GNSS) can provide centimeter positioning accuracy at low costs. However, in order to obtain the desired high accuracy, it is necessary to use high-quality atmospheric models. We focus on the troposphere, which is an important topic of research in Brazil where the tropospheric characteristics are unique, both spatially and temporally. There are dry regions, which lie mainly in the central part of the country. However, the most interesting area for the investigation of tropospheric models is the wet region which is located in the Amazon forest. This region substantially affects the variability of humidity over other regions of Brazil. It provides a large quantity of water vapor through the humidity convergence zone, especially for the southeast region. The interconnection and large fluxes of water vapor can generate serious deficiencies in tropospheric modeling. The CPTEC/INPE (Center for Weather Forecasting and Climate Studies/Brazilian Institute for Space Research) has been providing since July 2012 a numerical weather prediction (NWP) model for South America, known as Eta. It has yield excellent results in weather prediction but has not been used in GNSS positioning. This NWP model was evaluated in precise point positioning (PPP) and network-based positioning. Concerning PPP, the best positioning results were obtained for the station SAGA, located in Amazon region. Using the NWP model, the 3D RMS are less than 10 cm for all 24 h of data, whereas the values reach approximately 60 cm for the Hopfield model. For network-based positioning, the best results were obtained mainly when the tropospheric characteristics are critical, in which case an improvement of up to 7.2 % was obtained in 3D RMS using NWP models.