Investigation of iron sulfide impact crater residues: A combined analysis by scanning and transmission electron microscopy

Abstract– Samples returned from comet 81P/Wild 2 by the Stardust mission provided an unequaled opportunity to compare previously available extraterrestrial samples against those from a known comet. Iron sulfides are a major constituent of cometary grains commonly identified within cometary interplanetary dust particles (IDPs) and Wild 2 samples. Chemical analyses indicate Wild 2 sulfides are fundamentally different from those in IDPs. However, as Wild 2 dust was collected via impact into capture media at approximately 6.1 km s^?1, it is unclear whether this is due to variation in preaccretional/parent body processes experienced by these materials or due to heating and alteration during collection. We investigated alteration in pyrrhotite and pentlandite impacted into Stardust flight spare Al foils under encounter conditions by comparing scanning and transmission electron microscope (SEM, TEM) analyses of preimpact and postimpact samples and calculating estimates of various impact parameters. SEM is the primary method of analysis during initial in situ examination of Stardust foils, and therefore, we also sought to evaluate the data obtained by SEM using insights provided by TEM. We find iron sulfides experience heating, melting, separation, and loss of S, and mixing with molten Al. These results are consistent with estimated peak pressures and temperatures experienced (approximately 85 GPa, approximately 2600 K) and relative melting temperatures. Unambiguous identification of preserved iron sulfides may be possible by TEM through the location of Al‐free regions. In most cases, the Ni:Fe ratio is preserved in both SEM and TEM analyses and may therefore also be used to predict original chemistry and estimate mineralogy.     

Breaking the Grenville–Sveconorwegian link in Rodinia reconstructions

The Grenville, Sveconorwegian, and Sunsas orogens are typically inferred to reflect collision between Laurentia, Baltica, and Amazonia at ca. 1.0 Ga, forming a central portion of the Rodinia supercontinent. This triple‐junction configuration is often nearly identical in otherwise diverse Rodinia reconstructions. However, available geological data suggest that although the Grenville and Sveconorwegian provinces shared a similar tectonic evolution from pre‐1.8 to ca. 1.5 Ga, they record distinctly different tectonic histories leading up to, during, and possibly following Grenville–Sveconorwegian orogenesis. Moreover, palaeomagnetic data suggest the two continents were separated at peak orogenesis, further invalidating any direct correlation. A number of possible interpretations are permissible with available geological and palaeomagnetic data, of which a “classic” triple‐junction configuration appears least likely. In contrast to the commonly inferred intertwined Proterozoic evolution of Baltica and Laurentia, the possibility remains that they were unrelated for a billion years between 1.5 and 0.45 Ga.     

Sustainable Household Capability: which households are doing the work of environmental sustainability?

This paper presents a framework for analysing which households are doing ‘their bit’ for sustainability in an era of climate change, using a two-stage cluster analysis of sustainable household capabilities. The framework segments households by their reported level of commitment to ‘pro-sustainability’ practices common to conventional government policies. Results are presented from a large-scale survey of Wollongong households, New South Wales, Australia. Results illustrate the importance of approaching household sustainability through everyday practices. Attention is drawn to the wide variation in participation in specific household sustainability practices. Investigation into sustainable household capability by household segments shows the limits of even the most committed households. Results show the importance of socio-cultural contexts in differentiating sustainable household capabilities—with women, suburban-detached households and lower income segments of the population ultimately doing most of the work of being sustainable.     

Chemical and mineralogical characterisation of weathered historical bricks from the Venice lagoonal environment

Surficial and bulk samples of historical bricks of different age (from XII to XVIII centuries) recovered from a campaign of archaeological excavations recently carried out at the site of a medieval monastery in the S. Giacomo in Paludo Island in theVenice Lagoon have been characterised by FT-IR, TGA-DTG and DTA, XRD, SEM + EDS. The samples belong to a particular brick type commonly used in the Venice region: the "altinella brick". The bulk relative abundance of primary (i.e. calcite and dolomite) and secondary firing minerals (i.e. diopside and wollastonite) in the bricks coupled with their relative geometrical dimensions allows placing the samples in a chronological sequence according to known historical changes in brickmaking firing temperatures and practices. Most of the bricks were used as paving material and have been exposed to the action of seawater salts (chlorides and sulphates) due to periodical submersion following high tide episodes. Salt-laden (gypsum, halite, mirabilite) surficial patinas are indeed present but salt weathering does not appear to have affected the overall structural soundness of the bricks in this now abandoned island as it is the case with brickwork located in other more populated (and polluted) areas in Venice and its lagoon.     

Soiling of limestone in an urban environment characterized by heavy vehicular exhaust emissions

The inorganic and organic chemical composition of weathering sulphate patinas on the limestone walls of Emmanuel College, Cambridge, UK, have been analysed by FT-IR spectroscopy, pyrolysis gas-chromatography/mass spectrometry and scanning electron microscopy. The College location is characterized by heavy vehicular exhaust emissions including those from diesel powered public transport vehicles due to its proximity to the main Cambridge coach station. A complex mixture of gaseous and particulate air pollutants are found deposited in the weathering patinas including organic compounds (such as PAHs), which represent markers for present-day vehicular pollution. Slight differences in composition between patinas collected at different heights on the building facades with, in particular, more evidence for a biogenic overprint in samples collected at roof level as opposed to ground (street) level are found. Analytical results confirm how building stones in urban areas acted in the past and still do today as passive repositories for any kind of gaseous and particulate air pollutant present in the surrounding atmosphere; accordingly, weathering patinas are slowly changing their composition to accommodate new classes of present-day air pollutants.     

Long-term impacts of dust storms on transport systems in south-eastern Iran

Natural Hazards - Dust storms are frequent in the Sistan region of south-eastern Iran and cause a wide range of problems, but few studies have assessed their negative impacts. This paper makes an...     

Identifying transboundary aquifers in need of international resource management in the Southern African Development Community region

Transboundary aquifer (TBA) management, in part, seeks to mitigate degradation of groundwater resources caused either by an imbalance of abstraction between countries or by cross-border pollution. Fourteen potential TBAs were identified within a hydrogeological mapping programme based on simple hydrogeological selection criteria for the Southern African Development Community (SADC) region. These have been reassessed against a set of data associated with five categories: (1) groundwater flow and vulnerability (which is perceived as the over-arching influence on the activity level of each TBA), (2) knowledge and understanding, (3) governance capability, (4) socio-economic/water-demand factors, and (5) environmental issues. These assessments enable the TBAs to be classified according to their need for cross-border co-operation and management. The study shows that only two of the 14 TBAs have potential to be the cause of tension between neighbouring states, while nine are potentially troublesome and three are unlikely to become problematic even in the future. The classification highlights the need to focus on data gathering to enable improved understanding of the TBAs that could potentially become troublesome in the future due to, for example, change in demographics and climate.