Hospital Laundry Wastewater Disinfection with Catalytic Photoozonation

Wastewater production in a hospital laundry and the treatment of the most critical wastewater stream, are assessed. Hospital laundry wastewaters are hazardous to the environment due to their high pollutant concentrations and the chemicals added during the clothes washing process. Heterogeneous photocatalysis with UV, O₃ and TiO₂ and their possible combinations were used for disinfection purposes. A ramp‐type reactor was used for TiO₂ (P25 Degussa) fixation and for photochemical diffusion of the ozonized air. After assessing 5‐day biological oxygen demand, chemical oxygen demand, pH, turbidity, and surfactant content, and checking for the presence of thermotolerant coliforms and Escherichia coli, it was concluded that UV/O₃/TiO₂ was the best process/combination, yielding a 100% disinfection rate and a microbiological inactivation of 0.5070 min^–1 for E. coli and of 0.5505 min^–1 for thermotolerant coliforms.     

Paleoproterozoic bimodal post-collisional magmatism in the southwestern Amazonian Craton,Mato Grosso,Brazil: Geochemistry and isotopic evidence

This paper discusses geological and geochemical aspects of a Paleoproterozoic volcano-plutonic association that crops out in southwestern Amazonian Craton, Mato Grosso, Brazil. The study area was divided into undeformed and deformed domains, based on structural and geochronology studies. The undeformed domain is composed mainly of felsic explosive and effusive flows. Inter-layered mafic flows of basalts and sedimentary rocks are also present. The deformed domain is mainly composed of titanite and hornblende-bearing monzogranite to syenogranite and biotite monzogranite, while granodiorite is less common. U–Pb single zircon analyses yielded ages of 1.8–1.75 Ga in granites and felsic volcanic rocks for both domains. Basalts from the undeformed domain are phaneritic, fine-grained, and are often hydrothermally altered. They show tholeiitic affinity and are LREE enriched. Their trace element composition resembles those of within-plate associations. The ε_Nd (t = 1.75 Ga) for all these rocks are positive, ranging from 0.12 to 1.49, which reflect a juvenile source. The felsic volcanism comprises subalkaline rocks with high K contents and is divided into two groups: crystal enriched ignimbrites and effusive rhyolites. REE patterns of effusive rocks show negative-Eu anomalies and are smooth in the ignimbrites. Trace element patterns similar to those of the effusive rocks and ignimbrites are found in magmatic rocks derived from sources affected by subduction-related metasomatism. Hornblende and biotite granites occur in the deformed felsic plutonic domain. These rocks show evidence of low-temperature metamorphism and deformation, and in some places, of hydrothermal alteration. The LREE/Nb (or Ta) ratios of these rocks are consistent with those observed in granites of post-collisional settings. The ε_Nd (t = 1.75 Ga) values are slightly negative on average, with few positive values (?1.41 to +2.96). These data are interpreted as indicative of a magmatism produced during a post-collisional event from mixed sources: a metasomatised mantle and a Paleoproterozoic continental crust. An intracontinental shearing with age of 1.7–1.66 Ga created the Teles Pires–Juruena lineament which partially controlled this magmatism.     

Biogeochemical Behavior of Arsenic Species at Paranaguá Estuarine Complex, Southern Brazil

The behavior and dynamics of arsenic at Ilha do Mel, Guaraque?aba, and Paranaguá, located in the Paranaguá Estuarine Complex, Brazil, were investigated in this work. Samples were collected in March, September, and December of 2005. With respect to arsenic behavior, the total concentrations were higher for Paranaguá (22.5?±?2.5?μg?L^?1) on average, followed by the samples of Guaraque?aba (14.4?±?3.2?μg?L^?1) and Ilha do Mel (8.7?±?1.1?μg?L^?1). The concentrations found in this work were consistently greater when compared to other estuaries. The results can be attributed to geological factors. Nevertheless, it was also possible to realize that higher concentrations were found in Paranaguá, the more impacted environment. These results represent a strong indication that human activities in the area contribute to the enrichment of the estuary with this metalloid. Arsenic was mainly present in the dissolved phase, which corresponded to more than 70% of the total concentration. This behavior can represent a greater residence time of this metalloid in the water column. The marine phytoplankton presence was decisive in dictating the distribution of As in the waters of Paranaguá estuary. Organic species, which are considered the less toxic, were found in higher concentrations in the eutrophic areas such as Guaraque?aba and Paranaguá. This was a typical behavior during the summer probably due to higher biological activity.     

Impact of coal tar pavement on polycyclic hydrocarbon distribution in lacustrine sediments from non-traditional sources

The evaluation of potential environmental impacts from polycyclic aromatic hydrocarbon is a subject that requires investigation, especially related to emission sources from highway roads with high traffic. In this paper, the distribution of polycyclic aromatic hydrocarbons was investigated in the surface sediments from a subtropical lake, located in the south of Brazil and away from urban areas. The results showed that all sediments presented such compounds in significant concentration, ranging from 9.50 to 29.88???g/g. The highest total concentration was found in those sites close to the highway (bridges) and the deepest area of the lake. Moreover, a high concentration of polycyclic aromatic hydrocarbons of high molecular weight, such as benzo(a)anthracene and dibenzo(a,h)anthracene was found. It was laso found that high concentrations might be related to asphalt and coal tar pavement used in the highway construction close to the lake. In addition, the potential capacity of sediment toxicity was compared with values of the interim sediment quality guidelines values. The results indicate that most of the sediment presents concentrations of hydrocarbons above these limits. Only fluoranthene and chrysene were found in concentrations below the guideline values. The concentrations of most of the polycyclic hydrocarbons are higher than the quality guidelines. However, the main concern is associated with the presence of benzo(a)anthracene whose concentration is 416 times higher than the limit establisehed by guidelines. The same observation can be done to traces of benzo(a)pyrene and dibenz(a,h)anthracene, with concentration values of 13 and 1,993 times higher.     

Impedances of rigid cylindrical foundations embedded in transversely isotropic soils

A complete formulation and implementation for assessment of the response to dynamic loads of cylindrical rigid structures embedded in transversely isotropic elastic half‐spaces is presented. The analysis is performed in the frequency domain and the steady‐state structure response is obtained. The method is based on a non‐singular version of the indirect boundary element method which uses influence functions, instead of Green's functions, as fundamental solutions. These influence functions are the response of an elastic half‐space to distributed, internally applied loads. The proposed method imposes full bonding contact between the foundation and the surrounding soil. Numerical results for displacement (vertical and horizontal) and rotation (twisting and rocking) impedances, showing the influence of the soil anisotropy, are presented. Results for the soil–structure interface tractions and for the displacement field throughout the half‐space are also shown. Copyright © 2006 John Wiley & Sons, Ltd.     

Coda wave attenuation in the Parecis Basin,Amazon Craton,Brazil: sensitivity to basement depth

Small local earthquakes from two aftershock sequences in Porto dos Gaúchos, Amazon craton—Brazil, were used to estimate the coda wave attenuation in the frequency band of 1 to 24 Hz. The time-domain coda-decay method of a single backscattering model is employed to estimate frequency dependence of the quality factor (Q _c) of coda waves modeled using Q_c = Q₀ f^hQ_{\rm c} =Q_{\rm 0} f^\eta , where Q ₀ is the coda quality factor at frequency of 1 Hz and η is the frequency parameter. We also used the independent frequency model approach (Morozov, Geophys J Int, 175:239–252, 2008), based in the temporal attenuation coefficient, χ(f) instead of Q(f), given by the equation c(f)=g+\fracpfQ_e \chi (f)\!=\!\gamma \!+\!\frac{\pi f}{Q_{\rm e} }, for the calculation of the geometrical attenuation (γ) and effective attenuation (Q_e^-1 )(Q_{\rm e}^{-1} ). Q _c values have been computed at central frequencies (and band) of 1.5 (1–2), 3.0 (2–4), 6.0 (4–8), 9.0 (6–12), 12 (8–16), and 18 (12–24) Hz for five different datasets selected according to the geotectonic environment as well as the ability to sample shallow or deeper structures, particularly the sediments of the Parecis basin and the crystalline basement of the Amazon craton. For the Parecis basin Q_c = (98±12)f^(1.14±0.08)Q_{\rm c} =(98\pm 12)f^{(1.14\pm 0.08)}, for the surrounding shield Q_c = (167±46)f^(1.03±0.04)Q_{\rm c} =(167\pm 46)f^{(1.03\pm 0.04)}, and for the whole region of Porto dos Gaúchos Q_c = (99±19)f^(1.17±0.02)Q_{\rm c} =(99\pm 19)f^{(1.17\pm 0.02)}. Using the independent frequency model, we found: for the cratonic zone, γ = 0.014 s^− 1, Q_e^-1 = 0.0001Q_{\rm e}^{-1} =0.0001, ν ≈ 1.12; for the basin zone with sediments of ~500 m, γ = 0.031 s^− 1, Q_e^-1 = 0.0003Q_{\rm e}^{-1} =0.0003, ν ≈ 1.27; and for the Parecis basin with sediments of ~1,000 m, γ = 0.047 s^− 1, Q_e^-1 = 0.0005Q_{\rm e}^{-1} =0.0005, ν ≈ 1.42. Analysis of the attenuation factor (Q _c) for different values of the geometrical spreading parameter (ν) indicated that an increase of ν generally causes an increase in Q _c, both in the basin as well as in the craton. But the differences in the attenuation between different geological environments are maintained for different models of geometrical spreading. It was shown that the energy of coda waves is attenuated more strongly in the sediments, Q_c = (78±23)f^(1.17±0.14)Q_{\rm c} =(78\pm 23)f^{(1.17\pm 0.14)} (in the deepest part of the basin), than in the basement, Q_c = (167±46)f^(1.03±0.04)Q_{\rm c} =(167\pm 46)f^{(1.03\pm 0.04)} (in the craton). Thus, the coda wave analysis can contribute to studies of geological structures in the upper crust, as the average coda quality factor is dependent on the thickness of sedimentary layer.