A MULTIBLOCK PARTIAL LEAST SQUARES ALGORITHM FOR INVESTIGATING COMPLEX CHEMICAL SYSTEMS

The details of a general multiblock partial least squares(PLS)algorithm based on one originallypresented by Wold et al.have been developed and are completely presented.The algorithm can handlemost types of relationships between the blocks and constitutes a significant advancement in the modelingof complex chemical systems.The algorithm has been programmed in FORTRAN and has been testedon two simulated multiblock problems,a three-block and a five-block problem.The algorithm combinesthe score vectors for all blocks predicting a particular block into a new block.This new block is used topredict the predicted block in a manner analogous to the two-block PLS.In a similar manner if one blockpredicts more than one other block,the score vectors of all predicted blocks are combined to form a newblock,which is then predicted by the predictor block as in the two-block PLS.Blocks that both predictand are predicted are treated in such a way that both of these roles can be taken into account whencalculating interblock relationships.The results of numerical simulations indicate that the computerprogram is operating properly and that the multiblock PLS produces meaningful and consistent results.     

Multi-technique approach to characterise the effects of cryopreservation on larval development of the Pacific oyster (Crassostrea gigas)

Cryopreservation experiments were conducted on D-stage larvae of the Pacific oyster (Crassostrea gigas) to investigate the effects of two cryoprotectant solutions and three cooling rates on larval development from 1 to 22 days post-fertilisation. Cryoprotectant solutions were made up to final concentrations (after 1:1 dilution with larvae) of 10% ethylene glycol, 1% polyvinylpyrrolidone and either 0.2 or 0.4 M trehalose. Three cooling rates (0.5, 1 and 2 °C min^?1 between ?10 and ?35 °C post-holding) were tested in an orthogonal design with the two cryoprotectants. Results indicate that control larvae out-performed all cryopreservation treatments for survival, feeding consumption and shell length parameters. However, larvae exposed to 0.4 M trehalose did considerably better than those exposed to 0.2 M trehalose, regardless of cooling rate conditions. Scanning electron and light microscopy observations were used to assess larval morphology and organogenesis, indicating that treatments with surviving larvae were morphologically and developmentally similar to control larvae.     

Distribution of heavy metals in Gaborone urban soils (Botswana) and its relationship to soil pollution and bedrock composition

The capital city of Botswana, Gaborone, has seen unprecedented population, economic, and industrial growth in recent years. In order to assess how this rapid urbanisation process impacts the environment, 106 silt and clay (particle size <0.053 mm) samples, separated from Gaborone surface soil samples representing urban, agricultural and rural sites, were investigated. The concentrations of nine heavy metals (Sc, Cr, Co, Ni, Cu, Zn, Nb, Cd, and Pb) were measured using ICP–MS and GFAAS, and the resulting patterns were correlated to the bedrock composition and anthropogenic activities. As expected, we found that samples from soils on top of dolerites show higher levels of Cr, Ni, and Cu than those on top of granites and rhyolites. However, our studies also show that Gaborone city centre soils are moderately polluted by Pb (up to 222 mg/kg, i.e. 5.7-fold the concentration in comparable rural soils), as a result of heavy traffic. Furthermore, Cr and Ni pollution originating from agrochemicals were shown to be accumulating in Gaborone crop soils. Our studies also showed moderate levels of Zn pollution and low level, dot-shaped pollution of Cr, Co, Ni, Cu detected in Gaborone residential and industrial soils that are correlated to waste disposal. Interestingly, the highest levels of Sc, Cr, Co, Ni and Zn pollution are found near two abandoned sewage works. The results of sequential extraction indicate that the polluting Co and Ni exist in all speciations; the polluting Cu mainly exists in the residue of the sequential extraction, whereas the polluting Pb is mostly bound to organic matters and Fe- and Mn-oxides. These results highlight the need for instituting a systematic and continuous monitoring of heavy metals and other forms of pollutants in Gaborone to ensure that pollution does not become a serious problem in the future.     

Volcanological and petrological evolution of Nyiragongo volcano,Virunga volcanic field,Zaire

Three major phases are distinguished during the growth of Nyiragongo, an active volcano at the western limit of the Virunga Range, Zaire. Lavas erupted during phase 1 are strongly undersaturated melilitites characterized by the presence of kalsilite phenocrysts, perovskite, and the abundance of calcite in the matrix. Such lavas crop out mainly on the inner crater wall and progressively evolve toward more aphyric melilite nephelinites well represented on the flanks of the volcano. Adventive vents lying at the base of the cone developed along radial fracture systems and erupted olivine and/or clinopyroxene – rich melilitites or nephelinites. Stage 2 lavas are melilite-free nephelinites. Clinopyroxene is the main phenocryst and feldspathoids are abundant in the lavas exposed on the crater wall. These flows result from periodic overflowing of a magma column from an open crater. Extensive fissure flows which erupted from the base of the cone at the end of this stage are related to widespread draining out of magma which in turn induces the formation of the summit pit crater. Magmas erupted during stage 3 are relatively aphyric melilite nephelinites and the main volcanological characteristic is the permanent lava lake observed into the pit crater until the 1977 eruption. Fluctuations of the level of the lava lake was responsible for the development of the inner terraces. Periodic overflowing of the lava lake from the central pit formed the nepheline aggregate lava flows. Petrography and major element geochemistry allow the determination of the principal petrogenetic processes. Melilitites and nephelinites erupted from the summit crater are lavas derived, via clinopyroxene fractionation, from a more primitive melt. The abundance of feldspathoids in these lavas is in keeping with nepheline flotation. Aphyric melilite nephelinites covering the flanks and the extensive fissure flows have a homogeneous chemical composition; rocks from the historical lava lake are slightly more evolved. All these lavas differentiated in a shallow reservoir. Lavas erupted from the parasitic vents are mainly olivine and/or clinopyroxene-phyric rocks. Rushayite and picrites from Muja cone are peculiar high-magnesium lavas resulting from the addition of olivine xenocrysts to melilitic or nephelinitic melts. Fluid and melt inclusions in olivine and clinopyroxene phenocrysts indicate a crystallization depth of 10–14 km. A model involving two reservoirs located at different depths and periodically connected is proposed to explain the petrography of the lavas; this hypothesis is in accordance with geophysical data. Received: July 8, 1993/Accepted: September 10, 1993     

The Neoproterozoic Mwashya–Kansuki sedimentary rock succession in the central African Copperbelt, its Cu–Co mineralisation, and regional correlations

Rocks of the Neoproterozoic Mwashya Subgroup (former Upper Mwashya) form the uppermost sedimentary unit of the Roan Group. Based on new field and drill hole observations, the Mwashya is subdivided into three formations: (1) Kamoya, characterized by dolomitic silty shales/siltstones/sandstones and containing a regional marker (the “Conglomerate de Mwashya” bed or complex); (2) Kafubu, formed by finely bedded black carbonaceous shales; and (3) Kanzadi, marked by feldspathic sandstones. Rocks of the Mwashya Subgroup are overlain by the Sturtian age Grand Conglomérat diamictite (equivalent to the Varianto/Brazil and Chuos/Namibia diamictites), and conformably overlie rocks of the Kansuki Formation (former Lower Mwashya), a carbonate unit containing volcaniclastic beds. New geochemical data confirm the continental rift context of this magmatism, which is contemporaneous with rift-related volcanism of the Askevold Formation (Nosib Group, Namibia). A gradational lithological transition between rocks of the Kansuki and the underlying Kanwangungu Formations, and similar petrological composition of these two formations, support the hypothesis that the Kansuki is the uppermost unit of the carbonate-dominated Dipeta/Kanwangungu sequence, and does not form part of the Mwashya Subgroup. Base metal deposits, mostly hosted in rocks of the Kansuki Formation, include weakly disseminated early-stage low-grade Cu–Co mineralisation, which was reworked and enriched, or initially deposited, by metamorphic fluids associated with the Lufilian orogenic event.     

Observation of Conditions Preceding Peak Indoor Air Volatile Organic Compound Concentrations in Vapor Intrusion Studies

Temporal and spatial variability of indoor air volatile organic compound (VOC) concentrations can complicate vapor intrusion (VI) assessment and decision-making. Indicators and tracers (I&T) of VI, such as differential temperature, differential pressure, and indoor radon concentration, are low-cost lines of evidence to support sampling scheduling and interpretation of indoor air VOC sampling results. This study compares peak indoor air chlorinated VOC concentrations and I&T conditions before and during those peak events at five VI sites. The sites differ geographically and in their VI conceptual site models (CSM). Relative to site-specific baseline values, the results show that cold or falling outdoor temperatures, rising cross slab differential pressures, and increasing indoor radon concentrations can predict peak VOC concentrations. However, cold outdoor air temperature was not useful at one site where elevated shallow soil temperature was a better predictor. Correlations of peak VOC concentrations to elevated or rising barometric pressure and low wind speed were also observed with some exceptions. This study shows how the independent variables that control or predict peak indoor air VOC concentrations are specific to building types, climates, and VI CSMs. More I&T measurements at VI sites are needed to identify scenario-specific baseline and peak related I&T conditions to improve decision-making.     

Geology and health：closing the gap

It was discovered several decades ago that the natural geo-environment could substantially impact on the health of animals and humans. However, despite the growth of evidence supporting this discovery, there has not been a close interaction between geoscientists and health scientists in assessing the need to study the various facets of the relationships between human and animal health and air, water, soils and rocks. This book is timely in closing that gap as stated in its title.     

Earth Science Education in Botswana

In Botswana, the Earth Science Education programme is based at the University of Botswana in the Department of Geology, which is one of seven departments in the Faculty of Science. Initially the new department had three academic staff members; this number has later increased to eight and, most recently, to ten academic posts. Since the programme's inception in 1980, 84 graduates completed the undergraduate geological studies. The Geology B.Sc. programme gives a choice between a single major in Geology and three combined majors: Geology/Environmental Sciences, Geology/Chemistry and Geology/Physics. Postgraduate programmes are currently under preparation. All Geology graduates are employed by the Botswana Government institutions and private companies. An active research programme, related to both local and international projects is conducted. This involves co-operation with national institutions and international organisations.