Tectonometamorphic evolution of an intracontinental orogeny inferred from P–T–t–d paths of the metapelites from the Rehamna massif (Morocco)

New petrographic and microstructural observations, mineral equilibria modelling and U/Pb (monazite) geochronological studies were carried out to investigate the relationships between deformation and metamorphism across the Rehamna massif (Moroccan Variscan belt). In this area, typical Barrovian (muscovite to staurolite) zones developed in Cambrian to Carboniferous metasedimentary rocks that are distributed around a dome‐like structure. First assemblages are characterized by the presence of locally preserved andalusite, followed by prograde evolution culminating at 6 kbar and 620 °C in the structurally deepest staurolite zone rocks. This Barrovian sequence was subsequently uplifted to supracrustal levels, heterogeneously reworked at greenschist facies conditions, which was followed locally by static growth of andalusite, indicating heating to 2.5–4 kbar and 530–570 °C. The ²⁰⁶Pb/²³⁸U monazite age of 298.3 ± 4.1 Ma is interpreted as minimum age of peak metamorphic conditions, whereas the ages of 275.8 ± 1.7 Ma and 277.0 ± 1.1 Ma date decompression and heating at low pressure, in agreement with previous dating of Permian granitoids intruding the Rehamna massif. The prograde metamorphism occurred during thickening and associated horizontal flow in the deeper crust (S1 horizontal schistosity). The horizontally disposed metamorphic zones were subsequently uplifted by a regional scale antiform during ongoing N–S compression. The re‐heating of the massif follows late massive E–W shortening, refolding and retrograde shearing of all previous fabrics coevally with regionally important intrusions of Permian granitoids. We argue that metamorphic evolution of the Rehamna massif occurred several hundred kilometres from the convergent plate boundaries in the interior of continental Gondwanan plate. The tectonometamorphic history of the Rehamna massif is put into Palaeozoic plate tectonic perspective and Late Carboniferous reactivation of (Devonian)–Early Carboniferous basins formed during stretching of the north Gondwana margin and formation of the Palaeotethys Ocean. The inherited heat budget of these magma‐rich basins plays a role in the preferential location of this intracontinental orogen. It is shown that rapid transition from lithospheric stretching to compression is characterized by specific HT type of Barrovian metamorphism, which markedly differs from similar Barrovian sequences along Palaeozoic plate boundaries reported from Variscan Europe.     

Performance of a conceptual and physically based model in simulating the response of a semi‐urbanized watershed in San Antonio,Texas

The need for accurate hydrologic analysis and rainfall–runoff modelling tools has been rapidly increasing because of the growing complexity of operational hydrologic and hydraulic problems associated with population growth, rapid urbanization and expansion of agricultural activities. Given the recent advances in remote sensing of physiographic features and the availability of near real‐time precipitation products, rainfall–runoff models are expected to predict runoff more accurately. In this study, we compare the performance and implementation requirements of two rainfall–runoff models for a semi‐urbanized watershed. One is a semi‐distributed conceptual model, the Hydrologic Engineering Center‐Hydrologic Modelling System (HEC‐HMS). The other is a physically based, distributed‐parameter hydrologic model, the Gridded Surface Subsurface Hydrologic Analysis (GSSHA). Four flood events that took place on the Leon Creek watershed, a sub‐watershed of the San Antonio River basin in Texas, were used in this study. The two models were driven by the Multisensor Precipitation Estimator radar products. One event (in 2007) was used for HEC‐HMS and GSSHA calibrations. Two events (in 2004 and 2007) were used for further calibration of HEC‐HMS. Three events (in 2002, 2004 and 2010) were used for model validation. In general, the physically based, distributed‐parameter model performed better than the conceptual model and required less calibration. The two models were prepared with the same minimum required input data, and the effort required to build the two models did not differ substantially. Copyright © 2012 John Wiley & Sons, Ltd.     

Implementing Digital Imaging for Improved Understanding of Microfine Cement Grout Permeation and Filtration

Geotechnical and Geological Engineering - Permeation grouting is a ground improvement method commonly used for strengthening and/or reducing permeability of soils with minimal disturbance to the...     

Tonian–Ediacaran Tectonometamorphic History of the Sa’al Complex, Sinai (Egypt): Implications for the Tectonostratigraphic Framework of the Northern Arabian–Nubian Shield

The Sa''al Metamorphic Complex (SMC; southern Sinai) encompasses the oldest arc rocks in the Arabian–Nubian Shield, comprising two non-consanguineous metavolcanic successions (the Agramiya Group and the Post-Ra''ayan Formation) separated by the metasediments of the Ra''ayan Formation. It experienced three distinct deformational events (D1–D3) and two low-medium grade regional metamorphic events (M1–M2). The Agramiya Group and the Ra''ayan Formation experienced all tectonometamorphic events (D1–D3 and M1–M2), whereas the Post-Ra''ayan volcanic rocks were only affected by the D3 and M2 events. D1 is an extensional event and is connected to the late Rodinia break-up (~Tonian; 900–870 Ma). The M1 metamorphism variably affected the older Agramiya Group, the rhyolitic tuffs experiencing lower to upper greenschist facies conditions and the basic and intermediate volcanic rocks undergoing amphibolite facies metamorphism. The Ra''ayan Formation metasediments experienced upper greenschist to amphibolite facies metamorphism. The upper greenschist facies M2 affected the youngest Post-Ra''ayan volcanic rocks and other stratigraphic successions. The compressive D2 and D3 events were coeval with the accretion of dismembered terranes in the assembly of Gondwana. D2 can be linked to the Tonian–Cryogenian arc-arc assembly (~880–760 Ma; in Elat and Sinai), whereas D3 and the accompanying M2 is constrained to 622–600 Ma (Ediacaran).     

Microscopic impactor debris in the soil around Kamil crater (Egypt): Inventory,distribution, total mass,and implications for the impact scenario

We report on the microscopic impactor debris around Kamil crater (45 m in diameter, Egypt) collected during our 2010 geophysical expedition. The hypervelocity impact of Gebel Kamil (Ni‐rich ataxite) on a sandstone target produced a downrange ejecta curtain of microscopic impactor debris due SE–SW of the crater (extending ~300,000 m², up to ~400 m from the crater), in agreement with previous determination of the impactor trajectory. The microscopic impactor debris include vesicular masses, spherules, and coatings of dark impact melt glass which is a mixture of impactor and target materials (Si‐, Fe‐, and Al‐rich glass), plus Fe‐Ni oxide spherules and mini shrapnel, documenting that these products can be found in craters as small as few tens of meters in diameter. The estimated mass of the microscopic impactor debris (<290 kg) derived from Ni concentrations in the soil is a small fraction of the total impactor mass (~10 t) in the form of macroscopic shrapnel. That Kamil crater was generated by a relatively small impactor is consistent with literature estimates of its pre‐atmospheric mass (>20 t, likely 50–60 t).     

Experimental and Numerical Study of Strip Footing Supported on Stabilized Sand Slope

The paper presents the results of laboratory model tests and theoretical analysis on the behavior of a strip footing supported on sheet pile wall-stabilized sandy slope and loaded vertically to failure. The parameters varied in the study include the height, stiffness and location of the sheet pile wall, the location of the footing relative to the slope crest and the relative density of sand. Two-dimensional plane strain finite element analyses was used to analyze a prototype strip footing on sandy slope with same conditions. The results indicate that the inclusion of sheet pile wall has significant effect in improving the response of the strip footing and the slope itself. The theoretical results confirm the experimental results of the model footing tests and show reasonable agreement. Based on the numerical and experimental results, critical values of the sheet pile wall parameters for maximum stabilizing effect are established.     

Adenine oxidation by pyrite-generated hydroxyl radicals

Cellular exposure to particulate matter with concomitant formation of reactive oxygen species (ROS) and oxidization of biomolecules may lead to negative health outcomes. Evaluating the particle-induced formation of ROS and the oxidation products from reaction of ROS with biomolecules is useful for gaining a mechanistic understanding of particle-induced oxidative stress. Aqueous suspensions of pyrite particles have been shown to form hydroxyl radicals and degrade nucleic acids. Reactions between pyrite-induced hydroxyl radicals and nucleic acid bases, however, remain to be determined. Here, we compared the oxidation of adenine by Fenton-generated (i.e., ferrous iron and hydrogen peroxide) hydroxyl radicals to adenine oxidation by hydroxyl radicals generated in pyrite aqueous suspensions. Results show that adenine oxidizes in the presence of pyrite (without the addition of hydrogen peroxide) and that the rate of oxidation is dependent on the pyrite loading. Adenine oxidation was prevented by addition of either catalase or ethanol to the pyrite/adenine suspensions, which implies that hydrogen peroxide and hydroxyl radicals are causing the adenine oxidation. The adenine oxidation products, 8-oxoadenine and 2-hydroxyadenine, were the same whether hydroxyl radicals were generated by Fenton or pyrite-initiated reactions. Although nucleic acid bases are unlikely to be directly exposed to pyrite particles, the formation of ROS in the vicinity of cells may lead to oxidative stress.