Water Quality Estimation Based on the Structural Analysis of Diatomic Complexes

Two types of plots characterizing the undisturbed structure of the biotopic spectrum of diatom algae are recognized. The first of them has a hyperbolic form and the second is a sigmoid curve (normal distribution). It was shown that, under adverse external impact, both types of plots change their shape and the extent of their distortion reflects the general level of anthropogenic load on this water body or its part. The proposed method of graphical comparison was developed for lakes of Kola Peninsula. Later it was successfully used in the biomonitoring of watercourses of the Volga–Akhtuba interfluve area (Astrakhan Province) and in paleoenvironmental reconstruction for Galichskoe Lake (Kostroma Province).     

Allochthonous and autochthonous organic matter in surface waters in Karelia

A relationship between indirect chemical indices of organic matter content of surface waters and light absorption in the visible and ultraviolet ranges is discussed. The allochthonous and autochthonous types of organic matter are found to essentially differ in the rate of light absorption. Techniques are proposed for the calculation of the concentrations of allochthonous and autochthonous organic matter by the integral rate of light consumption in the visible region and the bichromate oxidability of water, as well as by three indirect indices: chemical oxygen demand, permanganate oxidability, and water color index. The mean concentrations of allochthonous and autochthonous organic matter in large lakes (Ladoga, Onega, and Baikal) and in rivers and smaller water bodies in Karelia (>300 water objects) are analyzed. Allochthonous organic matter was found to predominate in most surface waters of Karelia (>80%), while allochthonous organic matter predominates only in lakes with a small specific catchment area (supposedly, <5) and in highly eutrophic lakes.     

In memory of I. K. Korolyuk

Chronicle

In memory of I. K. Korolyuk     

Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).     

Long-term dynamics of phosphorus in the Narochanskie Lakes and factors determining it

The Narochanskie Lakes (Batorino, Myastro, and Naroch) (Belarus) are a focus of many-year hydroecological studies. The modern evolution of the ecosystem of the lakes includes four stages: anthropogenic eutrophication in the 1970s, de-eutrophication because of nature protection measures in their drainage area in the 1980s, benthification because of invasion of mollusk-filterer Dreissena polymorpha Pallas in the 1990s, and the present-day state. Retrospective analysis of many-year dynamics of total phosphorus (1978–2010) in water of the Narochanskie Lakes is given for different stages of their ecosystems restructuring. The complex response of water bodies comprising a single ecosystem to external impacts is described and its causes are discussed.     

Concentration and Diffusion of Nutrients in the Interpore–Bottom Water System of the Ob River Estuary

Oceanology - On cruise 76 in 2019, the R/V Akademik Mstislav Keldysh completed the Gulf of Ob–Kara Sea slope transect. Samples of bottom water and two sediment layers 1 cm thick were obtained...     

“Pure” supernovae and accelerated expansion of the Universe

A special class of type Ia supernovae that is not subject to ordinary and additional intragalactic gray absorption and chemical evolution has been identified. Analysis of the Hubble diagrams constructed for these supernovae confirms the accelerated expansion of the Universe irrespective of the chemical evolution and possible gray absorption in galaxies.     

Hydrodynamic processes in young binaries as a source of cyclic variations in circumstellar extinction

Hydrodynamic models of a young binary accreting matter from the remnants of a protostellar cloud have been calculated by the SPH method. Periodic variations in column density in projection onto the primary component are shown to take place at low inclinations of the binary plane to the line of sight. These can result in periodic extinction variations accompanied by brightness variations in the primary. Generally, there can be three periodic components. The first component has a period equal to the orbital one and is attributable to the streams of matter penetrating into the inner regions of the binary. The second component has a period that is a factor of 5–8 longer than the orbital one and is related to the density waves generated in a circumbinary (CB) disk. Finally, the third, longest period is attributable to the precession of the inner CB disk regions. The relationship between the amplitudes of these cycles depends on the model parameters as well as on the inclination and orientation of the binary in space. We show that at a dust-togas ratio of 1: 100 and amass extinction coefficient of 250 cm² g^?1, the amplitude of the V-band brightness variations in the primary component can reach 1 ^m at a mass accretion rate onto the binary components of 10.8^?8 M _⊙ yr^?1 and a 10° inclination of the binary plane to the line of sight. We discuss possible applications of the model to young, pre-main-sequence stars.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

The limits of validity of the Frequency Ratio Method: The particular case of γ Doradus stars

This work provides a general vision of the limits of validity of the Frequency Ratio Method applied to the g‐mode pulsators in asymptotic regime, the γ Doradus stars. In particular, the work is mainly focused on the role of rotation which is found one of the most important source of uncertainty of the method. The particular case of the moderately rotating γ Doradus star HD48501 is discussed. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)