A note on estimating the vertical eddy diffusion coefficient from LANDSAT imagery

Boundary-Layer Meteorology - The vertical eddy diffusion coefficient (K z) for five smoke plumes entrapped in a stable marine layer is estimated from the published LANDSAT imagery data sets of...     

Weak Contrast PP Wave Displacement R/T Coefficients in Weakly Anisotropic Elastic Media

—Approximate PP plane wave displacement coefficients of reflection and transmission for weak contrast interfaces separating weakly but arbitrarily anisotropic elastic media are presented. The PP reflection coefficient for such an interface has been derived recently by Vavry?uk and P?en?ík (1997). The PP transmission coefficient presented in this paper was derived by the same approach. The coefficients are given as a sum of the coefficient for the weak contrast interface separating two nearby isotropic media and a term depending linearly on contrasts of the so-called weak anisotropy (WA) parameters (parameters specifying deviation of properties of the medium from isotropy), across the interface. While the reflection coefficient depends only on 8 of the complete set of the WA parameters describing P-wave phase velocity in weakly anisotropic media, the transmission coefficient depends on their complete set. The PP reflection coefficient depends on "shear-wave splitting parameter" γ. Tests of accuracy of the approximate formulae are presented on several models.     

Instability of gradient dependent elasto-viscoplasticity for clay

A gradient-dependent viscoplastic constitutive model for water saturated clay is proposed to describe the strain localization phenomena and pattern formation during deformation. Second- and fourth-order gradients of volumetric viscoplastic strain are introduced into the constitutive equations to account for the non-local effects due to the motion of microstructures. A linear perturbation analysis is applied to this model. The instability of the government equations (i.e. the constitutive equations and the equations of motion for the clay skeleton and pore water) is discussed for both the one-dimensional and the two-dimensional situations. In addition, issues concerned with the formulation of boundary value problems by finite element analysis in relation to the formulation and the boundary conditions are presented. Copyright © 1999 John Wiley & Sons, Ltd.     

Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

A soil chronosequence in Late Glacial and Neoglacial moraines, Humboldt Glacier, northwestern Venezuelan Andes

Late Glacial and Neoglacial (Little Ice Age) deposits on the Humboldt Massif were analyzed for relative-age dating parameters, including geomorphic and weathering characteristics, geochemical and soil properties. The soil chronosequence, formed in chemically uniform parent materials, provides an important database to study soil evolution in a tropical alpine environment. Extractable and total Fe and Al concentrations, examined to assess their use in relative-age determination, and as paleoenvironmental indicators, provide an important measure of the accumulation and downward profile movement over time of organically-bound Al, ferrihydrite and other crystalline forms (hematite and goethite) of extractable Fe. Ferrihydrite is particularly useful in determining former perched water levels in soils with relation to paleoclimate. The ratios of most Fe extracts are time dependent. The Fe_d/Fe_t ratio, within statistical limits, shows a slow increase from LIA (Little Ice Age) to Late Glacial soils, which closely correlates with other alpine soil studies in the middle latitudes and other tropical alpine locales. Values of Al_d (dithionite) and Al_o (oxalate extractable) generally do not correlate with time; however, Al_p (pyrophosphate extractable) measured against Al_t (total) provides insight on the downward translocation over time of organically-bound Al. Low leaching rates in this chronosequence are further supported by clay mineralogy trends and the geochemical data.     

Estimating the predictability of the seismicity rate: The 1964 eruption of Shiveluch Volcano

This paper describes a method for estimating the predictability of the seismicity rate for volcanic edifices. The mathematical model is a nonlinear second-order differential equation, with our own algorithms for optimization and for estimating predictability. The method is illustrated by the 1964 eruption on Shiveluch Volcano. Calculations showed that the seismicity rate can be predicted with success for a time interval ranging between a few days and a few tens of days during the active phase and between a few tens of days and a few hundreds of days during the decay phase. The level of predictability is rather high, with the prediction distance exceeding the mean error by two to four orders of magnitude. The nonlinear character of both the active phase of the process and of its decay phase is close to the law of an equilateral hyperbola. The method, as developed in this paper, allows a realistic approach to the prediction of that part of the volcanic process which involves brittle deformation and/or rapid displacements of material along the newly arisen cracks.     

Impact of fertilizer phosphorus application on phosphorus release kinetics in some calcareous soils

Phosphate reactions and retention in the soil are of paramount importance from the perspective of plant nutrition and fertilizer use efficiency. The objective of this work was to study the kinetics of phosphorus (P) desorption in different soils of Hamadan in fertilized and unfertilized soils. Soils were fertilized with 200 mg P kg⁻¹. Fertilized and unfertilized soils were incubated at 25 ± 1°C for 6 months. After that, release of P was studied by successive extraction with 0.5 M NaHCO₃ over a period of 1,752 h. The results showed that phosphorus desorption from the fertilized and unfertilized soils began with a fast initial reaction, followed by a slow secondary reaction. The amount of P released after 1,752 h in fertilized and unfertilized soils ranged from 457 to 762.4 and 309.6 to 586.7 mg kg⁻¹, respectively. The kinetics of cumulative P release was evaluated using the five kinetic equations. Phosphorus desorption kinetics were best described by parabolic diffusion law, first order, and power function equations. Rate constants of these equations were higher in fertilized than unfertilized soils. Results from this study indicate that release rate of P plays a significant role in supplying available P and released P in runoff.