Structure of the αFexAl1:xOOH solid solution

The three-dimensional local organisation around Fe atoms in a natural diaspore (Al_0.9955Fe_0.0045OOH) has been investigated by angular measurements of X-ray absorption spectra. It is demonstrated that in a single crystal of diaspore, the absorption cross-section exhibits the special case of trichroism where three independent measurements are needed to determine the absorption cross-section for any direction of polarization. Extended X-ray absorption fine structure (EXAFS) spectra were thus recorded at the following orientations of the polarization vector: , , and . The incoming white beam was monochromatized using two Si(331) crystals, which deliver at the Fe K-edge a completely linearly polarized X-ray beam. The reliability of our measurements was checked by comparing the isotropic EXAFS spectrum calculated from the three orthogonal measurements to the one of the diaspore powder recorded at the magic angle. It is shown that Fe³⁺ ions are not randomly distributed within the diaspore framework. Furthermore, only part of the Fe³⁺ ions substitutes Al, the others being located in the channels of the structure. The 3D local structure of the Fe domains has been modeled assuming hematite-like clusters of three Fe octahedra topotactically grafted to aluminous chains. These Fe clusters are thought to represent ancient multinuclear Fe surface complexes having formed at the time of the diaspore growth, and being sealed in its bulk structure. The whole crystal of diaspore is then thought to have kept the memory of the heterogeneous nucleation mechanism of these hematite nuclei. In addition to the well-known examples of atom segregations, ion vacancies, and intergrowths of discrete phases, this new type of crystal defect represents another evidence of non-equilibrium crystallization process under the thermodynamic and kinetic conditions that prevail at the earth's surface.     

Composition and heterogeneity of the microbial community in a coastal microbial mat as revealed by the analysis of pigments and phospholipid-derived fatty acids

The beaches of the North Sea barrier island Schiermonnikoog (The Netherlands) are covered by microbial mats. Five types of microbial mats were distinguished based on a variety of characteristics, located along a transect perpendicular to the coast. Biomass abundance and composition of the microbial community were analyzed in these mats using pigments and phospholipid-derived fatty acids (PLFA) as biomarkers. Biomass per gram sediment increased more than six-fold from the mats at the low water mark to mats found at the edge of the dunes. Microscopic analysis revealed that the increase in biomass was accompanied by a change in species composition. Pigment- and PLFA composition reflected the changes in species composition. The PLFA data could be used to estimate the relative group abundance using the matrix factorization program CHEMTAX., whereas the pigment data were found not to be suitable for this purpose.     

Aeolian dune migration along the Ceará coast, north-eastern Brazil

Aeolian dune dimensions and migration rates are analysed along the Ceará coast, north-east Brazil. Dunes that are currently mobile along the Ceará coast are composed of barchans and sand sheets. The results show that barchans maintain an equilibrium form, which can be characterized by values of dimensionless shape parameters H/W and W/L , where H is the dune height, W is the wing-to-wing width and L is the dune length. Dunes are highly mobile, with average migration rates of 17·5 m year⁻¹ for barchans and 10 m year⁻¹ for sand sheets. The calculated migration rates were found to depend strongly on dune dimensions for both barchans and sand sheets, i.e. the larger the dune is, the lower the migration rate will be. This size dependence was associated with the existence of a representative common transport rate along the dune fields, which induces a different dune migration rate dependent on dune size. Finally, from the observed dune evolution, an aggregated scale aeolian sediment transport was inferred. This bulk transport rate, of the order of 90–100 m³ m⁻¹ year⁻¹, is only valid for a timescale of years to decades, which is the timescale used in dune evolution analysis.     

Clustering of groundwater chemistry data with implications for reservoir appraisal in West Siberia

Division of sedimentary strata according to groundwater chemistry is discussed with implications for petroleum reservoir potential. It is suggested to process multiparametric water chemistry data from West Siberia using formalized clustering techniques. The efficiency of this approach has been tested for Neocomian clinoform reservoirs with reference to regional-scale appraisal and subregional petroleum division.     

Organic tracers in sediments from the coastal zone of Ras Abu el-Darag,Gulf of Suez

Sediment samples from the coastal zone of the Gulf of Suez contain a variety of organic compounds from anthropogenic and natural sources. A total of 12 surface samples of bottom sediments were collected with an Ekman grab sampler along an off-shore transect south of Ras Abu el-Darag. The samples were extracted with a mixture of dichloromethane and methanol (3:1 v/v) after drying and sieving through 250 μm mesh. The extracts were derivatized and analyzed by gas chromatography–mass spectrometry in order to characterize the chemical composition and sources of the organic components. Marine with minor terrestrial biota were the major natural sources of organic tracers and included n-alkanoic acids, sterols and saccharides (5.7–76.7%). Anthropogenic sources, from petroleum related activities, detergent usage for spill cleaning and littering, are indicated by the presence of n-alkanes with carbon preference index ≤1.0, hopanes, steranes, unresolved complex mixture of branched and cyclic hydrocarbons, alkyl nitriles, alkamides and plasticizers. Their total relative concentrations ranged from 23.3 to 97.3% of the total extracts. Petroleum residues from natural seepage may also be part of these hydrocarbons. The levels of anthropogenic inputs decrease from about 94% in coastal zone sediments to about 20% in sediments from the reef front.     

Magnetometer Array Study in North-Northeast Brazil: Conductivity Image Building and Functional Induction Modes

—Magnetovariational fields recorded by an array of magnetometers in the equatorial region of north-northeast Brazil are analyzed to infer the configuration of internal induced currents in and around the extensive intracratonic Parnaíba basin. Only nighttime magnetovariational fields were used because of the prevailing uniform source field conditions. For periods exceeding 40 min. the vertical fields at all inland sites are dominated by the effects of electric currents originating in the northeast, in the deep Atlantic Ocean. Below this period, although best developed in the 12–15 min. period range, the anomalous signatures are principally controlled by two distinct continental current paths. The first is associated with a N60°E trending graben-like structure in the southeastern part of the basin (named the Parnaíba Basin Conductivity Anomaly—PBCA) and the second appears as a subsurface sedimentary channel, from the NW corner of the array to the central part of the basin. This is named the LINK anomaly, as it connects the northwestern Marajó basin with the Parnaíba basin. While the PBCA is shown to highlight the importance of basement tectonics in the geological evolution of the Parnaíba basin, the LINK anomaly provides strong geophysical evidence of the direction of the sea intrusion into the region of the basin and possibly indicates the connectivity of the Parnaíba basin to the adjoining Amazon basin through the Marajó basin. Frequency and polarization dependence suggest that the induction response of individual structures is not determined by the local conductivity alone but also by their interconnectivity as well as by their linkage to the continental shelf and deep oceanic region.     

阿尔泰山东缘主要活动断裂影像特征分析

文中采用遥感资料,对阿尔泰山东缘的主要活动断裂———科布多(Hovd)断裂与哈尔乌苏湖(Har-Nuur)断裂进行研究,从地貌特征上对断裂进行详细分析,揭示其几何学和运动学特征。初步研究表明阿尔泰山东缘的活动断裂规模、滑动速率和强地震活动并不弱于其西南缘。其中科布多断裂走向NNW,右旋走滑,长约600km,中更新世(Q2p)以来最大水系右旋位错约9.0km,滑动速率可达3.8～12.3mm/a,平均滑动速率约7.8mm/a;哈尔乌苏湖断裂走向NNW,右旋走滑,长约480km,全新世以来活动性明显增强,第四纪洪积扇上发现有最新的断裂迹象。阿尔泰山东缘的新构造运动与强地震活动,除了与印度-欧亚板块碰撞作用有关外,可能还与局部地区的动力学过程有关     

A petrographic and fluid inclusion comparison of silver-poor and silver-rich zinc-lead ores,N.E. Washington State

Many of the zinc-lead deposits of NE Washington State are poorly known examples of Mississippi Valley Type (MVT) mineralization. This study compares inclusion fluids from the Josephine Breccia ores with the later cross-cutting sulfide-bearing quartz veins. The breccia ores are cemented mainly by open space fillings of dolomite, sphalerite, quartz, galena, jasperoid and calcite. Replacement is of minor importance. Ore and gangue deposition occurred over the range 150–250 °C with most of the temperatures less than 200 °C. The aqueous brines typically contain 17–23 equivalent weight percent NaCl with often substantial amounts of Ca and/or Mg chlorides. Homogenization temperatures do not delineate any cooling or paragenetic sequence. The cross-cutting vein quartz contains CO₂-rich inclusions with overall densities usually less than 0.7 g/cc and homogenization temperatures from 250–325 °C. Sulfur isotope analyses yield two populations with the quartz vein ores being lighter (<13 permil CDT) than the average for the conformable ores. The later veins are not remobilized MVT sulfides but represent a separate, high-silver period of mineralization.