Evaluation of cold-water carbonates as a possible paleoclimatic indicator

The common belief currently shared by many geoscientists concerning the climatic interpretation of limestones is that a warm-water environment is essential. This concept is not necessarily true because the rate and extent of terrigenous sediment dilution, rather than water temperature, is the primary factor determining whether or not a limestone forms at nearshore or continental shelf depths. Because carbonate productivity is lowest in cold climates, however, CaCO₃ abundance and the thickness of carbonate accumulations tend to be least at high latitudes. In this regard present-day continental shelves and beaches offer a poor model for comparing cold-water and warm-water carbonates because of the generally emergent continental tectonic framework, recent eustatic sea-level changes, and the presence of ice caps at the modern poles.Typically, the influence of climate on non-reef continental shelf and beach environments cannot be clearly distinguished by the presence or absence of major taxonomic groups. Faunal diversity and equitability are more sensitive in this regard. The absence of shelf-depth inorganic carbonate precipitates, micrite envelopes, and peloids may also point to the cold-water origin of a rock. Skeletal mineralogy and oxygen isotopes of certain unrecrystallized carbonates may be good paleoclimatic indicators; however, trace elements and physical-textural attributes of the carbonate fraction are probably temperature insensitive.Previous studies of high-latitude continental shelves have concentrated merely on the abundance of calcareous material and there is seemingly a disproportionate amount of information with respect to low-latitude carbonate studies. Further research on cold-water carbonates may open up new avenues for alternative paleoenvironmental and paleoclimatic interpretations.     

Blaubleibender covellite and its relationship to normal covellite

Both natural and synthetic samples of blaubleibender (blue-remaining) covellite have been studied by reflected light microscopy, electron probe microanalysis and electron microscopy and diffraction. The natural sample of composition Cu_1.20S has a 19a × 19a superstructure based on the hexagonal coveilite subcell (side a). The synthetic sample of composition Cu_1.10S has a 27 a × 2 7a superstructure. In both cases the phases are homogeneous. The evidence suggests that the recognition of two distinct types of blaubleibender covellite may be an oversimplification, and that a series of metastable superstructures based on the covellite structure may exist.Work done while on leave at the Department of Mineralogy and Petrology, Cambridge     

Tectonothermal history of the basement rocks in the western zone of the North China Craton and its tectonic implications

The basement of the North China Craton can be divided into the eastern, central and western zones, based on lithological, structural, metamorphic and geochronological data. The western zone comprises two different petrotectonic units: Archaean tonalitic–trondhjemitic–granodioritic (TTG) grey gneisses and metamorphic mafic rocks, and Palaeoproterozoic khondalite series. The former is characterized by isobaric cooling (IBC)-type anticlockwise P–T paths in the north-northwestern part of the zone and near-isothermal decompression (ITD)-type clockwise P–T paths in the eastern part, adjacent to the central zone. On the other hand, the tectonothermal evolution of Palaeoproterozoic khondalite series rocks is characterized exclusively by nearly isothermal decompression following the peak of metamorphism and then cooling, defining clockwise P–T paths. The Archaean TTG gneisses and associated mafic rocks with anticlockwise metamorphic P–T paths reflects an origin related to underplating and intrusion of mantle-derived magmas which may be derived from mantle plumes. They represent a late Archaean continental block in the western part of the North China Craton. The Palaeoproterozoic khondalite series rocks represent passive continental margin deposits. They were metamorphosed and deformed in the late Palaeoproterozoic during the amalgamation of the western continental block with another continental block in the east part of the North China Craton. The ITD-type clockwise P–T–t paths of the Palaeoproterozoic khondalite series rocks record the tectonothermal histories of the collision of the western and eastern continental blocks which resulted in the final assembly of the North China Craton at c. 1800 Ma.     

The study of intermittent hydrophysical fields in the vicinity of the frontal zone

CTD data provided by the MGI-4204 and MARK-III probes are used to study the quasistationary subpolar front structure in the north-western Sea of Japan. In order to provide further insights into the intermittent scalar hydrophysical fields, the method of inhomogeneity identification using temperature pulsations calculated by the moving interval is suggested. The experimentally-derived inhomogeneity distribution is satisfactorily approximated by the exponential law.Translated by V. Puchkin.     

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

Mercury in bottom sediments of marginal seas of northeast Asia

The analysis of the concentrations and distribution of mercury in bottom sediments of marginal seas in northeastern Asia revealed that its maximum contents are characteristic of areas with an active geodynamic regime and some areas of the Amur Bay in the Sea of Japan subjected to anthropogenic impact. The geochemical associations of mercury with other chemical elements and its background concentrations in bottom sediments of these sea basins are defined.     

The Uryakh ore field (NE Transbaikalia): Formation of structural assemblages in the centroid-type seismic regime

Syn-ore centroid type deformations that produced unusual structural assemblages are identified in the Uryakh ore field. The regularities of the deformation process comparable to a mechanism of the centroid-type seismic focus are established. The results of studying fluid inclusions suggest that the pressure—temperature parameters of the system correspond to conditions typical of the seismic regime. A model of formation of structural assemblages in a centroid-type dynamic regime with the participation of fluids is proposed for the first time.     

Solar coronal heating by magnetic cancellation – III. Thermodynamics

We present two-dimensional numerical magnetohydrodynamics simulations of a coronal X-ray bright point (XBP) caused by a cancelling magnetic feature (CMF). Cancellation is driven by converging motions of two magnetic bipolar sources. These sources are initially disconnected from each other so that both, the CMF and the associated reconnection/heating event (i.e. the XBP), are modelled in a self-consistent way. In the initial state, there is no X-point but two separatrices are present. Hence, the reconnection/heating and the cancellation phases have not yet started. Our numerical experiments end shortly after the converging magnetic bipole has fully cancelled. By this time, reconnection in the inner domain has ceased and occurs only at the base. Solving the energy equation with various heating and cooling terms included, and considering different bottom boundary conditions, reveals that the unrealistically high temperatures produced by Ohmic heating are reduced to more moderate temperatures of 1.5–2 MK consistent with observations of XBPs, if thermal conduction is included and density and temperature are fixed at the base.     

Common features of the tectonosphere deep structure in the Western Pacific Margins (Northeast Asia Region and Australia)

This paper analyses the spatial distributions of gravity sources and density contrast of geological media between the centers of mass of density heterogeneities and surfaces of some layers, which is reflected by the values of parameter μ_z, in the Northeast Asia Region and Australia. Statistical images of complex distributions of density heterogeneities are generally consistent with the shallowest tectonic structures, wave velocity, and electric anomalies. The correlation of μ_z minimums with high heat flow suggests melted magmas beneath the crust base and in the asthenosphere. In the lower crust layer, large μ_z maximums correlate with major continental megaelements, which are divided by extended linear μ_z minimums, high conductivity anomalies, and Vp/Vs maximums marking zones of lower viscosity. Deep boundaries and a thickness of lithospheric plates and asthenosphere lenses have been defined in the Northeast Asia Region. In Australia, two roughly NS-striking low-viscosity zones crossing the continent reflect the deep setting of the Lasseter (in the west) and the Tasman (in the east) lines. These zones are displayed in a wide depth range (15–120 km) and are confined to the Archean–Proterozoic and Proterozoic–Phanerozoic boundaries in the Australian lithosphere. Statistical gravity models derived without external (relatively to gravity) geological and geophysical information prove the multilayered tectonosphere structure of both continents and the similar deep structure features of their margins.