An assessment of geologic sequestration potential in the panhandle of Florida USA

One alternative to reduce global greenhouse gas emissions is to store the emissions in underground geologic sequestration repositories. The efficacy of this approach has been favorably evaluated by numerous authors over the last 15 years. This paper discusses an assessment of the overall feasibility of storing emissions in three different repositories in the Florida panhandle located in the Southeastern United States. The feasibility assessment evaluates both saline aquifers and oil reservoirs located in the panhandle region. The overall feasibility is driven by the available geologic sequestration capacity, the transportation cost to deliver emissions to a respective repository, and other engineering and regulatory issues. The geologic sequestration capacity is generally controlled by the so-called storage efficiency, a variable dependent on the site-specific geology, reservoir conditions, and the injected fluid characteristics. For this paper, storage efficiency for saline repositories was assessed in more detail using numerical modeling. Based on the work completed, the 3 repositories studied have at least 4.55 gigatonnes of capacity to sequester CO₂.     

The contribution of sulphur dioxide from ablating micrometeorites to the atmospheres of Earth and Mars

Atmospheric composition is a key control on climate and the habitability of planetary surfaces. Ablation of infalling micrometeorites has been recognised as one way in which atmospheric chemistry can be changed, especially at times in solar system history when the infall rates of exogenous material were high. Despite its potential to influence climate and habitability, extraterrestrial sulphur dioxide is currently an unquantified contribution to the atmospheres of the terrestrial planets. We have used flash pyrolysis to simulate the atmospheric entry of micrometeorites and Fourier-transform infrared spectroscopy to identify and quantify the sulphur dioxide produced from the carbonaceous meteorites Orgueil (CI1), ALH 88045 (CM1), Cold Bokkeveld (CM2), Murchison (CM2) and Mokoia (CV3). We have used this approach to understand the introduction of sulphur dioxide to the atmospheres of Earth and Mars from infalling micrometeorites. Sulphates, present in carbonaceous chondrites at a few wt.%, are resistant to thermal decomposition, limiting the yields of sulphur dioxide from unmelted micrometeorites. Infalling micrometeorites are a minor source of present-day sulphur dioxide on Earth and Mars, calculated to be up to around 2400 tonnes and about 350 tonnes, respectively. During the Late Heavy Bombardment (LHB), the much greater infall rates of micrometeoritic dust are calculated to be associated with average production rates of sulphur dioxide of around 20 Mt yr⁻¹ for the early Earth and 0.5 Mt yr⁻¹ for early Mars, for a LHB of 100 Myr. These rates of delivery of sulphur dioxide at high altitudes would have reduced the solar energy reaching the surfaces of these planets, via scattering of sunlight by stratospheric sulphate aerosols, and may have had detrimental effects on developing biospheres by promoting cooler climates and reducing the probability of liquid water on planetary surfaces.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

Assimilating data into open ocean tidal models

The problem of deriving tidal fields from observations by reason of incompleteness and imperfectness of every data set practically available has an infinitely large number of allowable solutions fitting the data within measurement errors and hence can be treated as ill-posed. Therefore, interpolating the data always relies on some a priori assumptions concerning the tides, which provide a rule of sampling or, in other words, a regularization of the ill-posed problem. Data assimilation procedures used in large scale tide modeling are viewed in a common mathematical framework as such regularizations. It is shown that they all (basis functions expansion, parameter estimation, nudging, objective analysis, general inversion, and extended general inversion), including those (objective analysis and general inversion) originally formulated in stochastic terms, may be considered as utilizations of one of the three general methods suggested by the theory of ill-posed problems. The problem of grid refinement critical for inverse methods and nudging is discussed.     

Uranium and thorium in the Kupferschiefer formation,Lower Zechstein,Poland

The Kupferschiefer in Poland has an increased U content. The facies high in organic matter are significantly enriched in U. The maximum values of U are mostly in the lower part of the Kupferschiefer sequence. The mean (x) U content in the Kupferschiefer from the Lubin-Sieroszowice district is 61.5 ppm and from the rest of the Polish Zechstein basin is about 26 ppm. Thorium occurs only in small quantities (x) = 1.5 and 5 ppm respectively). The high variance of U and Th in the Kupferschiefer is due to multistage diagenetic processes. The main U carrier is thucholite. The investigated thucholite showed a Th-content below 0.36 ppm. Thucholite with uraninite exolutions showed small (up to 1.0 wt.%) admixtures of U and thucholite without microscopically visible exsolutions (up to 37.85 wt.% U). The phosphates showed significant amounts of U (up to 0.24 wt.). The U content in the Kupferschiefer is significantly lower than in black shales from other part of the world. Uranium in the Lubin district is not economic.     

Geoeffective Disturbances in the Solar Wind near the Solar Activity Minimum according to the Data of a Two-year Series of Observations of Interplanetary Scintillations with the BSA LPI Radio Telescope

Astronomy Reports - A joint analysis of the monitoring data of interplanetary scintillations with solar and geophysical data showed that at the descending phase of the 24 solar activity cycle, the...     

Peculiarities of surface air temperature variations over the Far East regions in 1976–2005

Peculiarities are investigated of the air temperature variation tendencies at some stations of the Far East in 1976–2005. The estimate of linear trend equation coefficients is computed according to the air temperature observation data using the least squares method. It is demonstrated that the air temperature trend in northern regions possesses a small probability at small values of residual variability. In the southern regions, the trend significance increases for almost all seasons at small values of residual variability. At midlatitude stations, the trend significance in January and February decreases considerably due to the large values of residual variability.     

Geochronology of anthropogenic pollutants in riparian wetland sediments of the Lippe River (Germany)

Anthropogenic pollutants were determined in a dated sediment core, collected from a riparian wetland of the Lippe River (Ruhr district, Germany). The historical trend in heavy metals, polycyclic aromatic hydrocarbons, organochlorines, polychlorinated biphenyls and linear alkylbenzenes as well as more recent contaminants such as industrial additives, organotins, synthetic musks, methyltriclosan and some other compounds were determined for the time period between 1930 and 1986. Emission sources, information on technical production and usage, as well as on the individual pollution pathways, with appropriate environmental stability, were considered in the interpretation of the sediment contamination over the past 50 years.Contaminants were analysed and interpreted according to two different criteria: (a) the origin of the main contaminants as related to mining and industrial activities as well as municipal sewage and agricultural effluents and (b) the pollution history. Due to a significant appearance of formerly missing contaminants in sediments deposited since 1970, we suggest classifying contaminants as either common (predating 1970) or modern (postdating 1970).In summary, the study provided a comprehensive reconstruction of the pollution history of the Lippe River system.     

Size and shape of near-spherical Allegan chondrules

Chondrules were extracted from a disaggregated sample of the Allegan meteorite. Individual chondrules were examined with apparatus incorporating two orthogonal binocular microscopes, and their three major axes measured. Maximum chondrule diameters ranged from 0.15 to 2.75 mm with a peak in distribution between 0.35 and 0.75 mm. The chondrule size distribution was found not to conform to Rosin's law. The chondrules were found to depart from sphericity by only small amounts. The authors still believe that the melting of nebula dust-ball agglomerates by some high-energy event was the most probable mechanism for the formation of chondrules.     

Mars data analysis program special issue no. 2

An extended photometric time series in the J and K bands of Neptune has a complex appearance which appears to require the simultaneous presence of three periodicities plus related harmonics in the (J-K) color. The most apparent of the fundamental periods is N1 = 17.73 hr. The two others are at N2 = 18.56 and N3 = 18.29 hr and may be the result of amplitude modulation of a previously reported period of 18.42 hr. We interpret the presence of multiple periodicity as indicating that distinct systems of zonal winds exist on the planet. We argue that these wind systems are probably confined to moderate or high latitudes on the basis of recent omages of the planet taken in a spectral region of strong CH₄ absorption, and, by analogy to the zonal wind systems that exist in Jupiter's atmosphere, deduce a period of rotation for the body of the planet of 18.2 ± 0.4 hr. Zonal wind contrasts of up to 109 m sec^?1 are implied in the atmosphere of Neptune by these observations.