Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.     

Evidence for a mid‐Pleistocene shift of ice‐drift pattern in the Nordic seas

Sediment proxy records from a continuous, 1.5 million year long deep‐sea sediment core from a site in the western Norwegian Sea were used to obtain new insights into the nature of palaeoceanographic change in the northern North Atlantic (Nordic seas) during the climatic shift of the Mid‐Pleistocene Revolution (MPR). Red‐green sediment colour and magnetic susceptibility records both reveal significant differences in their mean values when comparing the intervals older than 700 000 yr (700 ka) with those from the past 500 kyr. The timing and duration of these changes indicates that the MPR in the Nordic seas is characterised by a gradual transition lasting about 200 kyr. Together with further sedimentological evidence this suggests that the mid‐Pleistocene climate shift was accompanied by a general change in ice‐drift pattern. It is further proposed that prior to the onset of the major late Pleistocene glaciations in the Northern Hemisphere a significant proportion of the ice in the eastern Nordic seas originated from a southern provenance, whereas later it dominantly came from the surrounding landmasses. Copyright © 2003 John Wiley & Sons, Ltd.     

Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002     

Ionprobe U-Pb zircon ages from the high-pressure/low-temperature mélange of Syros, Greece: age diversity and the importance of pre-Eocene subduction

The Cycladic blueschist belt in the central Aegean Sea has experienced high‐pressure (HP) metamorphism during collisional processes between the Apulian microplate and Eurasia. The general geological and tectonometamorphic framework is well documented, but one aspect which is yet not sufficiently explored is the importance of HP mélanges which occur within volcano‐sedimentary successions. Unresolved issues concern the range in magmatic and metamorphic ages recorded by mélange blocks and the significance of eventual pre‐Eocene HP metamorphism. These aspects are here addressed in a U‐Pb zircon study focusing on the block–matrix association exposed on the island of Syros. Two gneisses from a tectonic slab of this mélange, consisting of an interlayered felsic gneiss‐glaucophanite sequence, yielded zircon ²⁰⁶Pb/²³⁸U ages of 240.1 ± 4.1 and 245.3 ± 4.9 Ma, respectively, similar to Triassic ages determined on zircon in meta‐volcanic rocks from structurally coherent sequences elsewhere in the Cyclades. This strongly suggests that parts of these successions have been incorporated in the mélanges and provides the first geochronological evidence that the provenance of mélange blocks/slabs is neither restricted to a single source nor confined to fragments of oceanic lithosphere. Zircon from a jadeitite and associated alteration zones (omphacitite, glaucophanite and chlorite‐actinolite rock) all yielded identical ²⁰⁶Pb/²³⁸U ages of c. 80 Ma. Similar Cretaceous U‐Pb zircon ages previously reported for mélange blocks have been interpreted by different authors to reflect magmatic or metamorphic ages. The present study adds a further argument in favour of the view that zircon formed newly in some rock types at c. 80 Ma, due to hydrothermal or metasomatic processes in a subduction zone environment, and supports the interpretation that the Cycladic blueschist belt records both Cretaceous and Eocene HP episodes and not only a single Tertiary HP event.     

Size and shape evolution of pores in a viscoplastic matrix under compression

The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd.     

Seasonal variations in prey selection by estuarine black-headed gulls (Larus ridibundus)

The number of black-headed gulls (Larus ridibundus) in the Clyde Estuary is large. In summer the average density has reached 1350 gulls km^?2 and in winter 180 gulls km^?2. This paper compares prey selection and feeding efficiency in gulls during summer and winter on tidal flats, and considers how seasonal differences may be adaptations to cope with seasonal changes in prey availability.Gross and net rates of energy intake were highest in summer because gulls captured more of the polychaete N. diversicolor than the amphipod C. volutator. In winter, gulls selected for C. volutator and therefore an energetically less profitable diet. Throughout the year gulls selected more C. volutator relative to N. diversicolor than expected on energetic grounds and so apparently did not maximize potential net rate of energy intake.Gulls used three techniques to capture prey and made most intensive use of the ‘crouch’ technique. Crouching gulls attained a much higher net rate of energy intake than ‘upright’ or ‘paddling’ gulls.A log-linear model showed that (a) season, water depth and gull density determined feeding technique and (b) feeding technique and season independently determined foraging success and prey selection. Thus gull density and water depth acted on prey selection through imposed variations in feeding technique.Reasons for gulls selecting energetically unprofitable C. volutator and for the use of several distinct feeding techniques are discussed.     

A neural network approach to ship track-keeping control

This paper presents an on-line trained neural net work controller for ship track-keeping problems. Following a brief review of the ship track-keeping control development since the 1980's, an analysis of various existing backpropagation-based neural controllers is provided. We then propose a single-input multioutput (SIMO) neural control strategy for situations where the exact mathematical dynamics of the ship are not available. The aim of this study is to build an autonomous neural controller which uses rudder to regulate both the tracking error and heading error. During the whole control process, the proposed SIMO neural controller adapts itself on-line from a direct evaluation of the control accuracy, and hence the need for a “teacher” or an off-line training process can be removed. With a relatively modest amount of quantitative knowledge of the ship behavior, the design philosophy enables real time control of a nonlinear ship model under random wind disturbances and measurement noise. Three different track-keeping tasks have been simulated to demonstrate the effectiveness of the training method and the robust performance of the proposed neural control strategy     

Generalized strain probing of constitutive models

Advanced material constitutive models are used to describe complex soil behaviour. These models are often used in the solution of boundary value problems under general loading conditions. Users and developers of constitutive models need to methodically investigate the represented soil response under a wide range of loading conditions. This paper presents a systematic procedure for probing constitutive models. A general incremental strain probe, 6D hyperspherical strain probe (HSP), is introduced to examine rate‐independent model response under all possible strain loading conditions. Two special cases of HSP, the true triaxial strain probe (TTSP) and the plane‐strain strain probe (PSSP), are used to generate 3‐D objects that represent model stress response to probing. The TTSP, PSSP and general HSP procedures are demonstrated using elasto‐plastic models. The objects resulting from the probing procedure readily highlight important model characteristics including anisotropy, yielding, hardening, softening and failure. The PSSP procedure is applied to a Neural Network (NN) based constitutive model. It shows that this probing is especially useful in understanding NN constitutive models, which do not contain explicit functions for yield surface, hardening, or anisotropy. Copyright © 2004 John Wiley & Sons, Ltd.