Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

Performance analysis of the spaceborne laser ranging system

The Spaceborne Laser Ranging System is a proposed short pulse laser on board an orbiting spacecraft.^1,2,3,4 It measures the distance between the spacecraft and many laser retroreflectors (targets) deployed on the Earth’s surface. The precision of these range measurements is assumed to be about ±2 cm (M. W. Fitzmaurice, private communication). These measurements are then used together with the orbital dynamics of the spacecraft, to derive the relative position of the laser ground targets. Assuming a six day observing period with 50% cloud cover, uncertainties in the baseline for target separations of 50 km to 1200 km were estimated to be on the order of 1 to 3 cm and the corresponding values in the vertical direction, ranged from 1 cm to 12 cm. By redetermining the measurements of the relative target positions, the estimated precision in the baseline for a target separation of 50 km is less than 0.3 cm and for a separation of 1200 km is less than 1 cm. In the vertical direction, the estimated precision ranged from 0.4 cm to 4.0 cm respectively. As a result of the repeated estimation of the relative laser target positions, most of the non-temporal effects of error sources as exemplified by the errors in geopotential are reduced. The Spaceborne Laser Ranging System’s capability of determining baselines to a high degree of precision provides a measure of strain and strain rate as shown byCohen, 1979. These quantities are essential for crustal dynamic studies which include determination and monitoring of strain near seismic zones, land subsidence, and edifice building preceding volcanic eruptions. It is evident that such a system can also be used for geodetic surveys where such precisions are more than adquate.     

A soil chronosequence in Late Glacial and Neoglacial moraines, Humboldt Glacier, northwestern Venezuelan Andes

Late Glacial and Neoglacial (Little Ice Age) deposits on the Humboldt Massif were analyzed for relative-age dating parameters, including geomorphic and weathering characteristics, geochemical and soil properties. The soil chronosequence, formed in chemically uniform parent materials, provides an important database to study soil evolution in a tropical alpine environment. Extractable and total Fe and Al concentrations, examined to assess their use in relative-age determination, and as paleoenvironmental indicators, provide an important measure of the accumulation and downward profile movement over time of organically-bound Al, ferrihydrite and other crystalline forms (hematite and goethite) of extractable Fe. Ferrihydrite is particularly useful in determining former perched water levels in soils with relation to paleoclimate. The ratios of most Fe extracts are time dependent. The Fe_d/Fe_t ratio, within statistical limits, shows a slow increase from LIA (Little Ice Age) to Late Glacial soils, which closely correlates with other alpine soil studies in the middle latitudes and other tropical alpine locales. Values of Al_d (dithionite) and Al_o (oxalate extractable) generally do not correlate with time; however, Al_p (pyrophosphate extractable) measured against Al_t (total) provides insight on the downward translocation over time of organically-bound Al. Low leaching rates in this chronosequence are further supported by clay mineralogy trends and the geochemical data.     

Estimating the predictability of the seismicity rate: The 1964 eruption of Shiveluch Volcano

This paper describes a method for estimating the predictability of the seismicity rate for volcanic edifices. The mathematical model is a nonlinear second-order differential equation, with our own algorithms for optimization and for estimating predictability. The method is illustrated by the 1964 eruption on Shiveluch Volcano. Calculations showed that the seismicity rate can be predicted with success for a time interval ranging between a few days and a few tens of days during the active phase and between a few tens of days and a few hundreds of days during the decay phase. The level of predictability is rather high, with the prediction distance exceeding the mean error by two to four orders of magnitude. The nonlinear character of both the active phase of the process and of its decay phase is close to the law of an equilateral hyperbola. The method, as developed in this paper, allows a realistic approach to the prediction of that part of the volcanic process which involves brittle deformation and/or rapid displacements of material along the newly arisen cracks.     

Impact of fertilizer phosphorus application on phosphorus release kinetics in some calcareous soils

Phosphate reactions and retention in the soil are of paramount importance from the perspective of plant nutrition and fertilizer use efficiency. The objective of this work was to study the kinetics of phosphorus (P) desorption in different soils of Hamadan in fertilized and unfertilized soils. Soils were fertilized with 200 mg P kg⁻¹. Fertilized and unfertilized soils were incubated at 25 ± 1°C for 6 months. After that, release of P was studied by successive extraction with 0.5 M NaHCO₃ over a period of 1,752 h. The results showed that phosphorus desorption from the fertilized and unfertilized soils began with a fast initial reaction, followed by a slow secondary reaction. The amount of P released after 1,752 h in fertilized and unfertilized soils ranged from 457 to 762.4 and 309.6 to 586.7 mg kg⁻¹, respectively. The kinetics of cumulative P release was evaluated using the five kinetic equations. Phosphorus desorption kinetics were best described by parabolic diffusion law, first order, and power function equations. Rate constants of these equations were higher in fertilized than unfertilized soils. Results from this study indicate that release rate of P plays a significant role in supplying available P and released P in runoff.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

Some modifications of Stokes' formula that account for truncation and potential coefficient errors

 Stokes' formula from 1849 is still the basis for the gravimetric determination of the geoid. The modification of the formula, originating with Molodensky, aims at reducing the truncation error outside a spherical cap of integration. This goal is still prevalent among various modifications. In contrast to these approaches, some least-squares types of modification that aim at reducing the truncation error, as well as the error stemming from the potential coefficients, are demonstrated. The least-squares estimators are provided in the two cases that (1) Stokes' kernel is a priori modified (e.g. according to Molodensky's approach) and (2) Stokes' kernel is optimally modified to minimize the global mean square error. Meissl-type modifications are also studied. In addition, the use of a higher than second-degree reference field versus the original (Pizzetti-type) reference field is discussed, and it is concluded that the former choice of reference field implies increased computer labour to achieve the same result as with the original reference field. Received: 14 December 1998 / Accepted: 4 October 1999