Observations of OH maser lines at an 18-cm wavelength in 9P/Temper1 and Lulin C/2007 N3 comets with RT-22 at the Crimean Astrophysical Observatory

Investigations on OH maser lines in comets have been performed with the RT-22 at CrAO. The results of observations of 9P/Temper1 and Lulin C/2007 N3 comets in the OH molecule line at a wavelength of 18 cm are presented. An original technique for observation data analysis has been developed. The gas production rate of OH molecules in these comets is estimated.     

Petrography and provenance of Laecanius Amphorae from Istria,northern Adriatic region,Croatia

Amphorae sherds from the Laecanius workshop of Roman Istria (10–5 B.C. and 78 A.D.), Croatia, were studied by integrating archaeological and geological techniques including fabric analysis, thin‐section petrography, X‐ray diffractometry (XRD), and heavy mineral analysis. The fabric of the sherds showed distinctive characteristics, permitting their classification and allocation into nine fabric groupss. Petrography revealed that quartz is the dominant clastic component, whereas carbonate is common as temper; XRD provided information on firing temperatures that ranged between 750 and 900°C. The sherds contain diverse heavy mineral suites with generally high epidote and garnet proportions; zircon is occasionally important. Garnet/epidote ratios and the presence of diagnostic species (pyroxene, hornblende) showed systematic variations that coincided with similar variations in fabric characteristics. Heavy mineral signatures of amphorae produced in other workshops proved essential in differentiating them from Laecanius sherds. A comparative heavy mineral analysis of terra rossa samples from the vicinity of the workshop indicated that terra rossa was the major source for the paste. Differences observed in the heavy mineral composition of the sherds and terra rossa were interpreted by the spatial heterogeneity of the latter and the mixing of the paste with sandy temper. Fresh Adriatic sponge spicules in the majority of Laecanius sherds and the temper‐derived, generally immature heavy mineral assemblages suggest that sandy deposits from the Adriatic were used for the clastic temper. © 2006 Wiley Periodicals, Inc.     

Geological, mineralogical and geochemical characteristics of the Radzimowice Au–As–Cu deposit from the Kaczawa Mountains (Western Sudetes, Poland): an example of the transition of porphyry and epithermal style

The sheeted quartz–sulfide veins of the Radzimowice Au–As–Cu deposit in the Kaczawa Mountains are related to Upper Carboniferous post-collisional potassic magmatism of the composite Zelezniak porphyry intrusion. Multiple intrusive activity ranges from early calc-alkaline to sub-alkaline and alkaline rocks and is followed by multiple hydrothermal events. Early crustally derived dacitic magma has low mg# (<63) and very low concentrations of mantle-compatible trace elements, high large-ion lithophile elements (LILE), moderate light rare-earth elements (LREE), and low high-field-strength elements (HFSE). Later phases of more alkaline rocks have higher mg# (60–70), and LILE, LREE, and HFSE characteristics that indicate mafic magma contributions in a felsic magma chamber. The last episode of the magmatic evolution is represented by lamprophyre dikes which pre-date ore mineralization and are spatially related to quartz–sulfide–carbonate veins. The dikes consist of kersantite and spessartite of calc-alkaline affinity with K₂O/Na₂O ratios of 1.1–1.9, mg# of 77–79, and high abundances of mantle-compatible trace elements such as Cr, Ni, and V. They have high LILE, low LREE, and low HFSE contents suggesting a subduction-related post-collisional arc-setting. The mineralization started with arsenopyrite that was strongly brecciated and overprinted by multiple quartz–carbonate phases associated with base-metal sulfides and Au–Ag–Bi–Te–Pb±S minerals. The sulfur isotope composition of sulfides ranges from –1.1 to 2.8 ³⁴S and suggests a magmatic source. At least two generations of gold deposition are recognized: (1) early refractory, and (2) subsequent non-refractory gold mineralization of epithermal style. Co-rich arsenopyrite with refractory gold and pyrite are the most abundant minerals of the early stage of sulfide precipitation. Early arsenopyrite formed at 535–345°C along the arsenopyrite–pyrrhotite–loellingite buffer and late arsenopyrite crystallized below 370°C along the arsenopyrite–pyrite buffer. Non-refractory gold associated with base-metal sulfides and with Bi–Te–Ag–Pb–S mineral assemblages has an average fineness of about 685, and is represented by electrum of two generations, and minor maldonite (Au₂Bi). Fluid inclusions from various quartz generations co-genetic with base-metal sulfides and associated with carbonates, tellurides and non-refractory gold indicate fluids with moderate salinity (9–15 wt% NaCl equiv.) and a temperature and pressure drop from 350 to 190°C and 1.2 to 0.8 kbar, respectively. According to the result of the sulfur isotope fractionation geothermometer the temperature of base-metal crystallization was in the range from 322 to 289°C. Preliminary results of oxygen isotope studies of quartz from veins indicate a gradual increase in the proportion of meteoric water in the epithermal stage. The gold to silver ratio in ore samples with >3 ppm Au is about 1:5 (geometric mean). Hydrothermal alteration started with sericitization, pyritization, and kaolinitization in vein selvages followed by alkaline hydrothermal alteration of propylitic character (illitization and chloritization), albitization and carbonatization. The mineralization of the Radzimowice deposit is considered as related to alkaline magmatism and is characterized by the superposition of low-sulfidation epithermal mineralization on higher-temperature and deeper-seated mesothermal/porphyry style.Editorial handling: B. Lehmann     

Rock salt mass in the Paleoproterozoic sequence of the Onega trough in Karelia (from the Onega parametric well data)

A thick (200 m) rock salt mass covering Late Archean granitoids was exposed for the first time in the Early Proterozoic volcanogenic-sedimentary formations in the Onega trough of the east Baltic Shield by the Onega parametric well. The mineral composition of salts, their geochemical features, and the isotopic composition of carbonate carbon and oxygen have been studied. After fluid inclusions present in salts, their metamorphism temperature and isotopic composition of helium and argon were determined. The obtained results give evidence of the fact that rock salts and magnesites associated with them were formed in an evaporate basin with participation of deep crustal processes. The age of the underlying granitoids (2.716 ± 9 Ma) is determined using the Pb—Pb method.     

The Karoo Basin of South Africa: type basin for the coal-bearing deposits of southern Africa

The coal-bearing sediments and coal seams of the Karoo Basin, Southern Africa are described and discussed. The Karoo Basin is bounded on its southern margin by the Cape Fold Belt, onlaps onto the Kaapvaal Craton in the north and is classified as a foreland basin. Coal seams are present within the Early Permian Vryheid Formation and the Triassic Molteno Formation.The peats of the Vryheid Formation accumulated within swamps in a cool temperate climatic regime. Lower and upper delta plain, back-barrier and fluvial environments were associated with peat formation. Thick, laterally extensive coal seams have preferentially accumulated in fluvial environments. The coals are in general inertinite-rich and high in ash. However, increasing vitrinite and decreasing ash contents within seams occur from west to east across the coalfields. The Triassic Molteno coal seams accumulated with aerially restricted swamps in fluvial environments. These Molteno coals are thin, laterally impersistent, vitrinite-rich and shaly, and formed under a warm temperate climatic regime.Palaeoclimate, depositional systems, differential subsidence and basin tectonics influence to varying degrees, the maceral content, thickness and lateral extent of coal seams. However, the geographic position of peat-forming swamps within a foreland basin, coupled with basin tectonics and differential subsidence are envisaged as the primary controls on coal parameters. The Permian coals are situated in proximal positions on the passive margin of the foreland basin. Here, subsidence was limited which enhanced oxidation of organic matter and hence the formation of inertinitic coals. The coals in this tectonic setting are thick and laterally extensive. The Triassci coals are situated within the tectonically active foreland basin margin. Rapid subsidence and sedimentation rates occurred during peat formation which resulted in the preservation of thin, laterally impersistent, high ash, vitrinite-rich, shaly coals.     

Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Free convection effects on the oscillatory flow in the Stokes's problem past an infinite porous vertical limiting surface with constant suction — I

An analysis of Rayleigh's problem (also Stokes's problem) for the flow of a viscous fluid (e.g. of a stellar atmosphere) past an impulsively started infinite, vertical porous limiting surface (e.g. of a star) with constant suction, when the free stream velocity oscillates in time about a constant mean, has been carried out. On solving the coupled non-linear equations in approximate way, expressions for the mean velocity, the mean temperature, the mean skin-friction and the mean rate of heat transfer, expressed in terms of Nusselt number, are obtained. The effects of Grashof numberG, Eckert numberE and Prandtl numberP, on these quantities, is discussed for the cases of an externally heating and cooling of the limiting surface, by the free convection currents, and the variations of them are shown graphically.