Input of atmospheric lead to marine sediments in a south-east Pacific coastal area (approximately 36 degrees S)

Atmospheric input of Pb to coastal sediments in the south-east Pacific (approximately 36 degrees S) was estimated using: (1) a salt marsh (non-local emission sources) as a natural collector of atmospheric fluxes and (2) Pb concentrations in rain and air samples, both considered to be representative of the atmospheric input in the study area. A radioisotopic geochronology technique ((210)Pb) was used to estimate the total Pb atmospheric supply to the sediments. The results show that atmospheric input to Concepción Bay accounts for 13-68% of Pb in near shore sediments, evaluated through salt marsh and rain, both showing comparable results. Consequently, there are other relevant Pb sources to explain the higher concentrations in this area. Sediments in the shelf are subject to important influence of upwelling waters, estimated by Salamanca [Sources and sinks of (210)Pb in Concepción Bay, Chile (1993) PhD thesis, Marine Science Research Center, State University of New York at Stony Brook, USA] using (210)Pb. The atmospheric input, however, is mainly responsible for the total Pb input, since the salt marsh (natural atmospheric collector) shows similar Pb(xs) inventories than the shelf, corresponding to a regional-scale Pb emissions.     

False waves in wave records

A methodology to define discrete waves from free sea surface elevation time series is presented. The method allows an objective discrimination of false waves among small waves, avoiding the use of arbitrary criteria associated with zero-up-crossing, zero-down-crossing, or other definitions. The method uses the Hilbert Transform and the representation of the time series in the complex plane. A discrete wave corresponds to a 2π phase-advance in the complex plane. The waves between zero crossings which do not show 2π phase advance are considered false waves. Wave rider buoy records, measured off the west coast of Portugal, were employed in assessing some of the statistical implications of this methodology.     

Nature and composition of shore-zone sediments between Jeddah and Yanbu, eastern Red Sea

The shore-zone sediments between Jeddah and Yanbu, west coast of Saudi Arabia, are composed mostly of skeletal carbonate sands. The nearshore sediments containing benthic foraminifera, algal fragments and molluscs are multimodal, the mean grain size varying between 0.76 and 2.35 ø. The beach sediments, except samples dominated by cerithid gastropods in some localities, are relatively finer than the nearshore sediments. Although the beaches to a great extent comprise sand-sized material, fine lime muds and coarse clastic gravels occur in certain areas. The dune sediments comprising mostly algal grains and ooids are very fine with 50 percent of the material in the 0.25–0.18 mm size grade. Except a general northward decrease in mean grain size, regional trends in the textural parameters of the sediments between Jeddah and Yanbu are not quite apparent. Lateral variations in the textural characteristics suggest a landward migration of the sediments in the shore zone under the influence of northerly and northwesterly winds. The carbon and oxygen (δ ¹³C + 4.80 to 4.84‰ PDB) (δ ¹³O − 0.04 to + 0.53‰ PDB) isotopic ratios of the lime muds occurring in certain shallow margins in the shore-zone, which are much higher than those of the green algae, indicate that the fine carbonates are at least in part inorganic in origin.

Like the shallow-water carbonates in tropical seas, aragonite and high Mg-calcite are the dominant carbonate minerals in the shore-zone sediments. There is a landward increase in aragonite contents caused by the landward migration of fine material from the nearshore. The dominant clay mineral in the nearshore sediments is kaolinite with subordinate swelling chlorite and little illite. Kaolinite is contributed by the coastal regions under the sub-tropical humid climate. Swelling chlorite is considered to have been formed in the nearshore by mechanical mixture of chlorite and montmorillonite derived from the metamorphic and igneous terrains of the Tertiary mountains bordering the coastal plain.     

Long-term recovery of a Louisiana brackish marsh plant community from oil-spill impact: vegetation response and mitigating effects of marsh surface elevation

Oil spills can have significant, short-term, negative impacts on coastal marshes, but the long-term effects and eventual recovery are not well documented, particularly in brackish marshes. The goals of this investigation were to: (1) document the long-term recovery of a Louisiana brackish marsh plant community impacted by a 1985 oil spill; (2) separate the effect of the oil spill on marsh deterioration from ambient rates of marsh deterioration; and (3) assess the relative importance of residual oil in the sediment and decreased marsh surface elevation in the failure of certain areas to recover. A total of 68 permanent plots previously established in 1985 were re-surveyed for plant and soil recovery in the fall of 1989. Although substantial (and near total) vegetative recovery was evident by significant increases in live and total vegetative cover, many of the plots that were initially heavily impacted by oil still displayed elevated levels of total saturated hydrocarbons in the soil. August 1990 measurements of plant photosynthetic response and edaphic variables revealed no significant differences between control plots and plots heavily impacted by oil that displayed vegetative regrowth. Rates of wetland land loss in the oiled marsh during an 8-year period that bracketed the time of the spill were within the historical range measured for this site and similar to the land loss rates of adjacent reference marshes. Results from a manipulative field transplant experiment indicated that the long-term failure of certain small areas to revegetate was primarily due to a decrease of marsh surface elevation (increased flooding stress), not a residual oil effect.     

Model estimates for the mean gas exchange between the ocean and the atmosphere under the conditions of the present-day climate and its changes expected in the 21st century

Annual mean fluxes of CO₂ and oxygen across the sea surface are estimated with the use of numerical modeling for several regions located in the Gulf Stream and Kuroshio zones. The present-day climatic conditions and the climatic conditions expected in the middle and at the end of the 21st century are considered. Specific features of gas exchange under a strong wind that are associated with gas exchange by bubbles and with changes in the air-water difference of the gas concentrations were taken into account in the calculations. The estimates obtained differ substantially from the results based on the traditional approach, which disregards the above features. A considerable increase in the absorption of CO₂ by the ocean, which is mainly caused by the continuing increase in the CO₂ concentration in the air during its small changes in the ocean, is expected in the 21st century. At the same time, no trends are revealed in the annual mean fluxes of oxygen across the ocean surface. The conclusion is made that, in calculations of CO₂ absorption by the world ocean, it is necessary to take into account both specific features of gas transfer under a strong wind and an increase in the atmospheric concentration of CO₂.