Geochemical signatures of two different coastal depositional environments within the same catchment

The geochemistry of lake (Renstradträsket) and estuarine (Pieni Pernajanlahti Bay) sediment was investigated in a medium sized watershed draining to the Gulf of Finland, Baltic Sea. Catchment land-use types were compared and found similar. Sediment cores were dated using ²¹⁰Pb- and ¹³⁷Cs-chronologies and analyzed for Al, K, Cu, Zn, Fe, Mn, phosphorus fractions, TN, TC and biogenic silica (BSi). Differences between the sediment cores were studied by using linear regression analysis and principal components analysis (PCA). Despite similarities in catchment land-use and history, the sediment geochemical profiles of the sites varied significantly. Some of the differences could be related to differences in chemical sedimentation environment (lacustrine versus estuarine). TP concentration was found to be positively correlated with sediment iron content in estuarine sediment but negatively correlated with Fe in lake sediment. In the estuarine core sedimentary iron was not correlated to lithogenic potassium and aluminum but in the lake core the iron seemed to be lithogenic in origin, as suggested by the strong positive correlations (r ² = 0.95–0.96) between these three variables. Most similarities among the cores were found in Al concentrations. Estuarine nutrient profiles appeared relatively monotonous compared to the lake core. This is probably due to more vigorous mixing of the sediments that may ensure more rapid and complete consumption of the organic matter deposited on the bottom of the estuary. Therefore the lake sediment appeared to preserve the historical record of eutrophication better. Biologically less active and more particle-bound materials like the trace metals Cu and Zn seemed to retain good records of anthropogenic impact also in the estuarine core. The study highlights the need to take the sedimentation environment into account when interpreting geochemical record.     

A numerical model of the partitioning of trace chemical solutes during drop freezing

Partitioning of volatile chemicals among the gas, liquid, and solid phases during freezing of liquid water in clouds can impact trace chemical distributions in the troposphere and in precipitation. We describe here a numerical model of this partitioning during the freezing of a supercooled liquid drop. Our model includes the time-dependent calculation of the coupled processes of crystallization kinetics, heat transport, and solute mass transport, for a freezing hydrometeor particle. We demonstrate the model for tracer partitioning during the freezing of a 1000 μm radius drop on a 100 μm ice substrate, under a few ambient condition scenarios. The model effectively simulates particle freezing and solute transport, yielding results that are qualitatively and quantitatively consistent with previous experimental and theoretical work. Results suggest that the ice shell formation time is governed by heat loss to air and not by dendrite propagation, and that the location of ice nucleation is not important to freezing times or the effective partitioning of chemical solutes. Even for the case of nucleation at the center of the drop, we found that dendrites propagated rapidly to form surface ice. Freezing then proceeded from the outside in. Results also indicate that the solid-liquid interfacial surface area is not important to freezing times or the effective partitioning of chemical solutes, and that the rate aspects of trapping are more important than equilibrium solid-liquid partitioning to the effective partitioning resulting from freezing.     

Relationships between southern Chilean varved lake sediments,precipitation and ENSO for the last 600 years

In this paper, the relationships between paleo-precipitation and the regional influence of El Nino Southern Oscillation (ENSO) in South America are assessed from a high-resolution calendar varve-thickness record. Two short laminated sediment cores (53 and 61 cm length) from Lago Puyehue (40° S) are analysed by continuous varve measurements through the last 600 years. The calendar varve years are determined by the occurrence of graded planktonic-rich layers. The annual sediment accumulation rates are reconstructed by using the standard varve-counting methods on thin sections. The 1980–2000 varve-thickness record is interpreted in terms of climate through correlation with limnological and local monthly instrumental climate databases. The comparison between the standardized varve thickness with the instrumental records reveals a strong correlation (r = 0.75, р = 0.07) between the total varve thickness and the austral autumn/winter precipitation. We argue that strong austral winter winds and precipitation are the forcing factors for the seasonal turn-over and phytoplankton increase in the lake sediments. During strong El Nino events the precipitation and the winds decrease abnormally, hence reducing the thickness of the biogenic sediments deposited after the winter turn-over. Our results show one significant regional maximum peak of winter precipitation (>900 mm) in the mid 20th century and a significant period with lower winter precipitation (<400 mm) before the 15th century, i.e., the late Medieval Warm Period. The first peak in the mid 20th century is confirmed by the regional precipitation database. The influence of ENSO cycles over the last 600 years is assessed by spectral analysis in Fagel et al. (2007). The possible influence of the regional volcanism and/or the seismic activity on the local climate record is also discussed. This is the sixth in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M. -F. Loutre and E. Chapron.     

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.     

Density and conductivity properties of Na−CO3−Cl−SO4 brine from Mono Lake, California, USA

Relationships among conductivity, temperature, total dissolved solids (TDS), and density were determined for hypersaline brine (TDS, 83 g kg⁻¹) from Mono Lake. A theoretical estimate of density based on ionic composition and calculated partial molar volumes compared well with actual measurements (difference, 390 ppm). However, an empirically derived equation of state based on temperature and conductivity provides the most accurate density estimates (residual errors, 190 ppm) and can be used with data collected with CTD profilers.     

Assessment of Nitrate—Nitrogen Distribution in Kansas Groundwater, 1990–1998

Nitrate-nitrogen (nitrate-N) in groundwater is a potential problem in many parts of Kansas.From 1990 to 1998, 747 water samples were collected from domestic, irrigation, monitoring,and public water supply wells primarily from the western two-thirds of the state, and analyzedfor nitrate-N by the Kansas Geological Survey. Nitrate-N concentrations of the 747 samplesanalyzed range from 29% with less than or equal to 3 mg/L, 51% between 3 and 10 mg/L,and 20% greater than or equal to 10 mg/L. Factors that show a statistically significantrelationship with the occurrence of nitrate-N in Kansas groundwater in this assessment includegeographic area of the state, depth of well, and age of well. Nitrate-N levels of wells screenedin the High Plains aquifer in south-central Kansas showed a statistically higher concentrationthan samples collected from the High Plains aquifer in the western portion of the state.Comparison of nitrate-N with depth of well indicated that shallower wells throughout the stategenerally have higher nitrate-N values than deeper wells. Irrigation wells older than 1975showed statistically higher nitrate-N concentration than wells installed during and since 1975,possibly related to changes in well-construction practices and regulations that occurred in 1975.     

Geoinformational Mapping of Landscapes in the Northwestern Part of Western Siberia Using the Hansen Mosaic Dataset

Presented are the technique and results of studying the landscape structure of the north-west of Western Siberia on the basis of the Hansen mosaic dataset consisting of elements covering the entire territory of the Earth. To study this area used a synthesis of classical methods of thematic system mapping as described in the doctrine of geosystems of V. B. Sochava, and automated interpretation of remote sensing data and mapping using GIS technologies. The method of geoinformational mapping of the landscape structure with the use of MultiSpec and Quantum GIS software programs for the purpose of drawing up real-time raster landscape maps is shown. In drawing up the map and the legend, the principle of geomic system-hierarchical representation of the territory as a complex multi-level “bottom-up” structure from topological-level geosystems (groups and classes of landscape facies) to regional-level geosystems (geoms, groups and classes of geoms) was used. Compilation of operational raster landscape maps of the north-west of Western Siberia involved multilevel automated interpretation of the Hansen mosaic dataset and mapping of areas (clusters) on images with different brightness characteristics, with the landscape structure of key areas and stationary physical and geographical profiles. A characteristic of this approach also implies using a dynamic classification of geosystems based on the study of their variable states. Such an approach permits a monitoring of changes in landscape structure and its areas and the intensity of anthropogenic impacts on forest and marsh landscapes, and determination of permissible pressure on geosystems in areas with high technogenic pressure of the oil and gas complex represented by the north-west of Siberia. An automated processing of data based on a supervised classification of territorial objects allows for the elimination of inaccuracies arising in visual image interpretation. Raster landscape maps can be used both for a further generation of vector maps and as a real-time information base for purposes of environmental management and protection.     

Time‐series high‐resolution spectroscopy and photometry of ε Aurigae from 2006–2013: Another brick in the wall

We present continuous and time‐resolved R = 55 000 optical échelle spectroscopy of ε Aurigae from 2006–2013. Data were taken with the STELLA Echelle Spectrograph of the robotic STELLA facility at the Observatorio del Teide in Tenerife. Contemporaneous photometry with the Automatic Photoelectric Telescopes at Fairborn Observatory in Arizona is presented for the years 1996–2013. Spectroscopic observations started three years prior to the photometric eclipse and are still ongoing. A total of 474 high‐resolution échelle spectra are analyzed and made available in this paper. We identify 368 absorption lines of which 161 lines show the characteristic sharp disk lines during eclipse. Another 207 spectral lines appeared nearly unaffected by the eclipse. From spectrum synthesis, we obtained the supergiant atmospheric parameters T_eff = 7395 ± 70 K, log g ≈ 1, and [Fe/H] = +0.02 ± 0.2 with ξ_t = 9 km s^–1, ζ_RT = 13 km s^–1, and v sin i = 28 ± 3 km s^–1. The residual average line broadening expressed in km s^–1 varies with a period of 62.6 ± 0.7 d, in particular at egress and after the eclipse. Two‐dimensional line‐profile periodograms show several periods, the strongest with ≈110 d evident in optically thin lines as well as in the Balmer lines. Center‐of‐intensity weighted radial velocities of individual spectral lines also show the 110‐d period but, again, additional shorter and longer periods are evident and are different in the Balmer lines. The two main spectroscopic Hα periods, ≈ 116 d from the line core and ≈ 150 d from the center‐of‐intensity radial velocities, appear at 102 d and 139 d in the photometry. The Hβ and Johnson V I photometry on the other hand shows two well‐defined and phase‐coherent periods of 77 d and 132 d. We conclude that Hα is contaminated by changes in the circumstellar environment while the Hβ and V I photometry stems predominantly from the non radial pulsations of the F0 supergiant. We isolate the disk‐rotation profile from 61 absorption lines and found that low disk eccentricity generally relates to low disk rotational velocity (but not always) while high disk eccentricity always relates to high velocity. There is also the general trend that the disk‐absorption in spectral lines with higher excitation potential comes from disk regions with higher eccentricity and thus also with higher rotational velocity. The dependency on transition probability is more complex and shows a bi‐modal trend. The outskirts of the disk is distributed asymmetrically around the disk and appears to have been built up mostly in a tail along the orbit behind the secondary. Our data show that this tail continues to eclipse the F0 Iab primary star even two years after the end of the photometric eclipse. High‐resolution spectra were also taken of the other, bona‐fide, visual‐binary components of ε Aur (ADS 3605BCDE). Only the C‐component, a K3‐4‐giant, appears at the same distance than ε Aur but its radial velocity is in disagreement with a bound orbit. The other components are a nearby (≈ 7 pc) cool DA white dwarf, a G8 dwarf, and a B9 supergiant, and not related to ε Aur. The cool white dwarf shows strong DIB lines that suggest the existence of a debris disk around this star. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Tsunamis as geological agents

When a tsunami wave series approaches and interacts with a coast, the consequent passage shorewards of great volumes of water and their invasion of the land, especially within bays and up river valleys, results in the disturbance of existing sediment and the removal seawards of land debris and coastal and shallow‐water marine sediments. Tsunami action builds up sequences of peculiar sediments in shallow water; it at least assists in the formation and maintenance of submarine canyons and, through them, produces turbidity currents of a particularly powerful kind. Tsunami action may explain many puzzling sedimentary phenomena, for example, sudden and drastic changes in near‐shore bathymetry; the formation of chaotic sediments such as some paraconglomerates and edgewise conglomerates. It offers solutions to problems arising from the study of turbiditic sequences, both modern and ancient.