Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Regime interplay: the case of biodiversity and climate change

In this paper, the interplay between the biodiversity and climate change regimes is examined in the context of a case study. An understanding of how the regimes interact is crucial to their successful operation, since it provides insight into how policy options might be drawn up to create synergy rather than conflict among the respective regimes’ objectives. Despite the increasing importance of the study of regime interplay, due to its potential influence on regime effectiveness, there is limited understanding of why regimes interact and how their interplay may affect their successful operation, since few empirical studies have been conducted in this area. By analysing the causes of the regime interplay and the potential effects thereof, this paper draws policy implications regarding how the interacting regimes might be better co-ordinated to create synergy.     

On the relation between cloud cover amount and sunshine duration

Summary The total cloud cover is deduced from measurements of monthly mean averages of the percent of possible sunshine duration at three locations in Egypt, Cairo, Bahtim and Sedi-Barrani stations during the period 1987–1995. This sunshine-derived total cloud cover (C_s) is compared to conventional ground-based observations of total cloud covers (C_g) made by meteorological observers. A linear relationship between the two estimates is calculated, and the difference between the two estimates as a function of C_s and C_g is fitted with a least-squares linear equation. It is found that on the average the sunshine-derived values of total cloud cover are about 7% lower than the corresponding ground-based estimated of total cloud cover. Both of these parameters are mainly used in solar radiation models and the error sources are mainly depending upon the way to describe sky cover.     

Two decades of progress in sodar techniques: a review of 11 ISARS proceedings

Summary For 20 years the biennial symposia organized by the International Society for Acoustic Remote Sensing of the Atmosphere and Oceans and Associated Techniques (ISARS) have been held in different countries. The original papers collected in the proceedings of the symposia reflect the development of ideas, equipment, and methods, plus results obtained in the area. The spectrum of themes discussed at the symposia is broad. More than 60% of the papers were devoted to the role of sodars in atmospheric boundary-layer research. This paper presents an overview of the development of sodar technique as elucidated in the proceedings of 11 ISARS symposia. Topics include (1) instrumentation, (2) methods of measuring different meteorological quantities and their turbulence characteristics, and (3) validating the methods by comparison of sodar data with in situ measurements.     

Seasonal and Diurnal Variation of Surface Ozone and a Preliminary Analysis of Exceedance of its Critical Levels at a Semi-arid Site in India

The mixing ratios of surface O₃ were measured at St. John's College, Agra, an urban and traffic influenced area for the period of 2000–2002. The monthly averaged O₃ mixing ratios ranged between 8 to 40 ppb with an annual average of 21 ppb. Strong diurnal and seasonal variations in O₃ mixing ratios were observed throughout the year except for monsoon season. The mixing ratios of O₃ follow the surface temperature cycle and solar radiation (r = 0.72 and r = 0.65 with temperature and solar radiation, respectively). Concentrations were higher with winds associated with NE and NW direction indicating the impact of pollution sources on surface O₃ concentration. Exceedance of ozone critical level was calculated using the AOT 40 index and found to be 840 ppb.h and 2430 ppb.h for summer and winter seasons, respectively. The present O₃ exposures are lower than the critical level of O₃ and suggest that the present level of O₃ does not have any impact on reduction in crop yields.     

The ACPI Climate Change Simulations

The Parallel Climate Model (PCM) has been used in the Accelerated ClimatePrediction Initiative (ACPI) Program to simulate the global climateresponse to projected CO₂, sulfate, and other greenhouse gasforcingunder a business-as-usual emissions scenario during the 21st century. In these runs, the oceans were initialized to 1995 conditions by a group from the Scripps Institution of Oceanography and other institutions. An ensemble of three model runs was then carried out to the year 2099 using the projected forcing. Atmospheric data fromthese runs were saved at 6-hourly intervals (hourly for certain criticalfields) to support the ACPI objective of accurately modeling hydrologicalcycles over the western U.S. It is shown that the initialization to1995 conditions partly removes the un-forced oceanic temperature and salinity drifts that occurred in the standard 20th century integration. The ACPI runs show a global surface temperature increase of 3–8 °C over northern high-latitudes by the end of the 21st century, and 1–2 °C over the oceans. This is generally within ±0.1°Cof model runs without the 1995 ocean initialization. The exception is in theAntarctic circumpolar ocean where surface air temperature is cooler in theACPI run; however the ensemble scatter is large in this region. Althoughthe difference in climate at the end of the 21st century is minimalbetween the ACPI runs and traditionally spun up runs, it might be largerfor CGCMs with higher climate sensitivity or larger ocean drifts. Ourresults suggest that the effect of small errors in the oceans (such asthose associated with climate drifts) on CGCM-simulated climate changesfor the next 50–100 years may be negligible.     

柳伊河水电站大坝右岸坝区研究

In the paper in order to ascertain the condition of the right-bank of the dam at the Vilyui hydroelectric power plant measurements are applied to obtain experimental date such as drilling borehole,hydrolocation and so forth. By finding out the distribution of the temperature field some corresponding measures are taken to improve the stability of the dam during the change of the ground temperature. And finally some conclusions are draw to the study.     

探测冰盖和多年冻土层的融冰探头研发

The exploration of ice sheets by melting vertical holes into the ground has some tradition in terrestrial glaciology. Such probes have been used since the 1960's to investigate the vertical structure of the ice in Greenland and Antarctica and in alpine glaciers. In this paper we look into the possibility to develop similar devices for use on extraterrestrial icy bodies, like e.g. the polar areas on Mars or the icy satellites of the outer solar system. We report on some basic experiments performed in the cryo-vacuum laboratory of the Space Research Institute of the Austrian Academy of Sciences, Graz. In these experiments the penetration of a simple melting probe into compact and porous water ice (with a snow-like texture) was monitored, both under vacuum conditions and under air pressure. The observed penetration speeds for a given power supply are compared with a simple mathematical model. We conclude that a miniature melting probe with small overall dimensions and a reasonable power demand could well be part of the payload of a future planetary mission, for example to the poles of Mars. Such missions are currently under discussion in several space agencies. Moreover such probes could also e? ectively be used in terrestrial environments. A possible design is presented at the end of the paper.