The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.     

INDUSTRIAL IMPACTS OF FOREIGN ENTERPRISE: A CANADIAN TECHNOLOGICAL PERSPECTIVE

The technological underdevelopment of secondary manufacturing in Canada is inferred from patterns of trade, industrial structure, and the range of industrial functions performed within firms in Canada. These patterns are explained by reference to the behavior of foreign subsidiaries that have major direct and indirect effects on the linkages and developmental potential of the Canadian industrial system. Canadian manufacturing is found to have a low level of innovative capability because of inadequate R & D and product and design engineering in foreign and domestic firms. In view of the strong need for new policy initiatives, the components of a techno-industrial strategy are evaluated.     

Biogeochemistry of nitrous oxide in groundwater in a forested ecosystem elucidated by nitrous oxide isotopomer measurements

The biological and physical controls on microbial processes that produce and consume N₂O in soils are highly complex. Isotopomer ratios of N₂O, with abundance of ¹⁴N¹⁵N¹⁶O, ¹⁵N¹⁴N¹⁶O, and ¹⁴N¹⁴N¹⁸O relative to ¹⁴N¹⁴N¹⁶O, are promising for elucidation of N₂O biogeochemistry in an intact ecosystem. Site preference, the nitrogen isotope ratio of the central nitrogen atom minus that of the terminal nitrogen atom, is useful to distinguish between N₂O via hydroxylamine oxidation and N₂O via nitrite reduction.We applied this isotopomer analysis to a groundwater system in a temperate coniferous-forested ecosystem. Results of a previous study at this location showed that the N₂O concentration in groundwater varied greatly according to groundwater chemistry, i.e. NO₃⁻, DOC, and DO, although apportionment of N₂O production to nitrification or denitrification was ambiguous. Our isotopic analysis (δ¹⁵N and δ¹⁸O) of NO₃⁻ and N₂O implies that denitrification is the dominant production process of N₂O, but definitive information is not derived from δ¹⁵N and δ¹⁸O analysis because of large variations in isotopic fractionations during production and consumption of N₂O. However, the N₂O site preference and the difference in δ¹⁵N between NO₃⁻ and N₂O indicate that nitrification contributes to total N₂O production and that most measured N₂O has been subjected to further N₂O reduction to N₂. The implications of N₂O biogeochemistry derived from isotope and isotopomer data differ entirely from those derived from conventional concentration data of DO, NO₃⁻, and N₂O. That difference underscores the need to reconsider our understanding of the N cycle in the oxic-anoxic interface.     

Linear and nonlinear vibration of non-uniform beams on two-parameter foundations using p-elements

A hierarchical finite element is presented for the geometrically nonlinear free and forced vibration of a non-uniform Timoshenko beam resting on a two-parameter foundation. Legendre orthogonal polynomials are used as enriching shape functions to avoid the shear-locking problem. With the enriching degrees of freedom, the accuracy of the computed results and the computational efficiency are greatly improved. The arc-length iterative method is used to solve the nonlinear eigenvalue equation. The computed results of linear and nonlinear vibration analyses show that the convergence of the proposed element is very fast with respect to the number of Legendre orthogonal polynomials used. Since the elastic foundation and the axial load applied at both ends of the beam affect the ratios of linear frequencies associated with the internal resonance, they influence the nonlinear vibration characteristics of the beam. The axial tensile stress of the beam in nonlinear vibration is investigated in this paper, and attention should be paid to the geometrically nonlinear vibration resulting in considerably large axial tensile stress in the beam.     

Relationship between Magmatic,Metamorphic, and Hydrothermal Processes within the Baikal–Muya Terrane (Eastern Siberia): Constraints from High-Precision Geochronological Study of the Kedrovskii Granitoid Massif

Doklady Earth Sciences - High-precision dating of granitoids is of key significance for age identification of the main stages of crust formation in various blocks of the continental crust. Here we...     

Spatio-temporal changes in rate of soil loss and erosion vulnerability of selected region in the tropical forests of Borneo during last three decades

An attempt has been made to analyze the spatial-temporal characteristics of soil erosion vulnerability and soil loss from the forested region in the north-eastern Borneo, Sarawak, Malaysia during the last three decades (1991–2015) using the revised universal soil loss equation (RUSLE) and geographical information systems (GIS). The components of RUSLE such as rainfall erosivity (R), soil erodibility (K), slope-length and steepness (LS), cover management (C) and conservation practice (P) factors were grouped into two categories by keeping one set as temporally changing and others as static. Among them the R and C factors are calculated for the years 1991, 2001 and 2015 whereas the K and LS factors are considered for the single time frame. Because of the forested nature of the study area, the P factor is kept constant for the whole analysis. The R factor and C factor is shown changes in values and its distribution over the years, which reflected in the final soil loss and erosion vulnerability map as a change in the rate of erosion and spatial domain. The analysis of three time slices has shown that the maximum value of the soil loss per unit area i.e. at erosion hotspots, is relatively similar throughout at around 1636 to 1744 t/ha/y. This is the result of maximum values of R factor and C factor i.e. high rainfall erosivity combined with lack of vegetation cover in those hotspots, which are generally steeply sloping terrain. The reclassification of annual soil loss map into erosion vulnerability zones indicated a major increase in the spatial spread of erosion vulnerability from the year 1991 to 2015 with a significant increase in the high and critical erosion areas from 2.3% (1991) to 31.5% (2015). In 1991, over 84% of the study area was under low erosion vulnerability class but by the year 2015 only 12% was under low erosion vulnerability class. Moreover, a dynamic nature in the erosion pattern was found from the year 1991 to 2015 with more linear areas of land associated with higher rate of soil loss and enhanced erosion vulnerability. The linearity in the spatial pattern is correlated with the development of logging roads and logging activities which has been confirmed by the extraction of exposed areas from satellite images of different years of analysis. The findings of the present study has quantified the changes in vegetation cover from dense, thick tropical forest to open mixed type landscapes which provide less protection against erosion and soil loss during the severe rainfall events which are characteristic of this tropical region.     

Using amphibole phenocrysts to track vapor transfer during magma crystallization and transport: An example from Mount St. Helens,Washington

In order to evaluate and further constrain models for volatile movement and vapor enrichment of magma stored at shallow levels, amphibole phenocrysts from 2004–2005 Mount St. Helens dacite were analyzed for major and selected trace elements (Li, Cu, Zn, Mn, and REE) and Li isotopes. Several recent studies have examined fluid-mobile trace element abundances in phencryst phases and melt inclusions as a means of tracking volatile movement within subvolcanic magmatic systems, and high Li contents in plagioclase phenocrysts from 1980 and 2004 Mount St. Helens dacites have been interpreted as evidence that shallow magma was fluxed by a Li-bearing vapor phase prior to eruption.     

Neoproterozoic events in the Tcholliré area: Pan-African crustal growth and geodynamics in central-northern Cameroon (Adamawa and North Provinces)

The Rei Bouba Group is a sedimentary and volcanic sequence (750–?650 Ma), regarded as a remnant of a Pan-African (back-arc?) orogenic basin that separated a remobilized Paleoproterozoic crust from an accretionary area (Poli Complex: 800-650 Ma). The latter was subjected to early deformation (D1) and intruded by calc-alkalic plutons (670 Ma). Transpressive tectonics and major thrusting, with emplacement of synkinematic granite, occurred at ca 630 Ma (D2-3) and a late compression (D4), with emplacement of calc-alkalic granite, occurred at ca 570 Ma. The Tcholliré Shear Zone is regarded as part of the major boundary between a recently accreted crust and the remobilized margin of the Congo Craton.     

A Practical Procedure for the Measurement of Fragmentation by Blasting by Image Analysis

Summary. The operation of a digital image analysis system in a limestone quarry is described. The calibration of the system, required in order to obtain moderately reliable fragmentation values, is done from muckpile sieving data by tuning the image analysis software settings so that the fragmentation curve obtained matches as close as possible the sieving. The sieving data have also been used to extend the fragment size distribution curves measured to sizes below the system’s optical resolution and to process the results in terms of fragmented rock, discounting the material coming from a loose overburden (natural fines) that is cast together with the fragmented rock. Automatic and manual operation modes of the image analysis are compared. The total fragmentation of a blast is obtained from the analysis of twenty photographs; a criterion for the elimination of outlier photographs has been adopted using a robust statistic. The limitations of the measurement system due to sampling, image processing and fines corrections are discussed and the errors estimated whenever possible. An analysis of consistency of the results based on the known amount of natural fines is made. Blasts with large differences in the amount of fines require a differentiated treatment, as the fine sizes tend to be the more underestimated in the image analysis as they become more abundant; this has been accomplished by means of a variable fines adjustment factor. Despite of the unavoidable errors and the large dispersion always associated with large-scale rock blasting data, the system is sensitive to relative changes in fragmentation.