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941.
Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process
with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al2O3 contents (60 and 70 mol%, respectively) and varying SiO2 plus B2O3 contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing
bulk B2O3 content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding
infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is
able to incorporate large amounts of boron into its structure (up to about 20 mol% B2O3 depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the
mullite structure in form of planar three-fold coordinated BO3 groups.
Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria 相似文献
942.
M. El Ghorfi F. Melcher T. Oberthür A. E. Boukhari L. Maacha A. Maddi M. Mhaili 《Mineralogy and Petrology》2008,92(1-2):59-80
Summary The Neoproterozoic Bou Azzer ophiolite complex hosts numerous, small lenticular bodies of massive and disseminated chromite.
Metallurgical-grade high-Mg and high-Cr spinels (cores with 48–62 wt% Cr2O3) reveal complex alteration patterns of successive Cr and Mn enrichment and loss of Al towards the rims, while the Mg# ratios
[(Mg/(Mg + Fe2+)] remain almost constant. Concentration patterns of platinum-group elements are typical for ophiolitic chromitite poor in
sulfides, with predominance of the IPGE, variable Rh, and low Pt and Pd. The most abundant platinum-group mineral is Rh-bearing
laurite that occurs either included in spinel or in silicate matrix, whereas Os-Ir-Ru alloy is always included in spinel.
Laurite inclusions reveal complex intergrowth textures with Rh-Ru-Pt rich alloy, and with Rh-rich sulfide. Most laurites display
trends to sulfur-poor compositions leading to local formation of very fine-grained Ru-Os-Ir alloy phases. Ni-Co-Fe sulfides,
arsenides and sulfarsenides devoid of PGE are associated with the alteration of chromite. Textural position and chemical composition
of the base metal inclusions, as well as comparison of alteration features between chromite and accessory chromian spinel
in the Co-Ni-As ores of the Bou Azzer ophiolite indicate a close connection. It is suggested that hydrothermal fluids percolated
through the marginal zones of the ophiolite belt during greenschist facies metamorphism and deposited Ni-Co-Fe arsenides,
sulfarsenides and minor sulfides as accessories within altered chromitites, and also in structurally favourable zones as Ni-Co-As
ores.
Author’s address: Dr. Frank Melcher, Federal Institute for Geosciences and Natural Resources, Stilleweg 2, 30655 Hannover, Germany 相似文献
943.
Summary The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of
the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined
ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral
(PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations
of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantle-normalised
chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined
ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic
origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved
in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in
the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite
losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic
hydrothermal fluids after the sulphide crystallisation.
Authors’ addresses: R. Pi?a, L. Ortega, R. Lunar, Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, ES-28040 Madrid,
Spain; F. Gervilla, Facultad de Ciencias, Instituto Andaluz de Ciencias de la Tierra, Universidad de Granada-CSIC, Avda. Fuentenueva, s/n, ES-18002
Granada, Spain 相似文献
944.
M. Mejías J. Garcia-Orellana J. L. Plata M. Marina E. Garcia-Solsona B. Ballesteros P. Masqué J. López C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536
A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic
aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a
previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated
combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics
and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural
analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and
groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were
applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium
isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (18O, 2H and 3H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system.
Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics
of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater
uses in the area of study. 相似文献
945.
Implementation of reconstructed geomorphologic units in landslide susceptibility mapping: the Melen Gorge (NW Turkey) 总被引:6,自引:2,他引:4
In the international literature, although considerable amount of publications on the landslide susceptibility mapping exist,
geomorphology as a conditioning factor is still used in limited number of studies. Considering this factor, the purpose of
this article paper is to implement the geomorphologic parameters derived by reconstructed topography in landslide susceptibility
mapping. According to the method employed in this study, terrain is generalized by the contours passed through the convex
slopes of the valleys that were formed by fluvial erosion. Therefore, slope conditions before landsliding can be obtained.
The reconstructed morphometric and geomorphologic units are taken into account as a conditioning parameter when assessing
landslide susceptibility. Two different data, one of which is obtained from the reconstructed DEM, have been employed to produce
two landslide susceptibility maps. The binary logistic regression is used to develop landslide susceptibility maps for the
Melen Gorge in the Northwestern part of Turkey. Due to the high correct classification percentages and spatial effectiveness
of the maps, the landslide susceptibility map comprised the reconstructed morphometric parameters exhibits a better performance
than the other. Five different datasets are selected randomly to apply proper sampling strategy for training. As a consequence
of the analyses, the most proper outcomes are obtained from the dataset of the reconstructed topographical parameters and
geomorphologic units, and lithological variables that are implemented together. Correct classification percentage and root
mean square error (RMSE) values of the validation dataset are calculated as 86.28% and 0.35, respectively. Prediction capacity
of the different datasets reveal that the landslide susceptibility map obtained from the reconstructed parameters has a higher
prediction capacity than the other. Moreover, the landslide susceptibility map obtained from the reconstructed parameters
produces logical results. 相似文献
946.
947.
Abstract The Taiwan orogen has been the focus of a number of models of mountain building processes, but little attention has been paid to high‐pressure (HP) metamorphic rocks that are found as exotic blocks intermingled within the deepest units of the mountain belt. In this study, we re‐appraise from updated petrological and thermodynamic databases the physical conditions of HP metamorphism in Taiwan, and we combine our findings with available geochronological data to estimate the thermal history of these rocks. Our results indicate that peak metamorphic conditions of ~550 °C and 10–12 kbar have been followed by a rapid isothermal decompression, with exhumation possibly as rapid as burial. These units have subsequently been stored at a pressure of ~3 kbar for ~4–5 Myr, before their final exhumation, probably facilitated by the accretion of passive margin sequences during the Late Cenozoic collision. Therefore, HP units in Taiwan maintain a record of processes at depth from the early stages of oceanic subduction to the present arc‐continent collision. 相似文献
948.
K. Vinod kumar R. C. Lakhera Tapas R. Martha R. S. Chatterjee A. Bhattacharya 《Environmental Geology》2008,55(4):789-799
Mass movements such as landslides in mountainous terrains are natural degradation processes and one of the most important
landscape-building factors. Varunawat Parbat overlooking Uttarkashi town witnessed a series of landslides on 23 September
2003 and the debris slides and rock falls continued for 2 weeks. This landslide complex was triggered due to the incessant
rainfall prior to the event, and its occurrence led to the blockage of the pilgrim route to Gangotri (source of the Ganges
river) and evacuation of thousands of people to safer places. Though there was no loss of lives due to timely evacuation,
heavy losses to the property were reported. High-resolution stereoscopic earth observation data were acquired after the incidence
to study the landslide in detail with emphasis on the cause of the landslide and mode of failure. Areas along the road and
below the Varunawat foothill region are mapped for landslide risk. It was found that the foothill region of the Varunawat
Parbat was highly disturbed by man-made activities and houses are dangerously located below steep slopes. The potential zones
for landslides along with the existing active and old landslides are mapped. These areas are critical and their treatment
with priority is required in order to minimise further landslide occurrences. 相似文献
949.
Bal Krishna Maheshwari Deepak A. Gunjagi 《Geotechnical and Geological Engineering》2008,26(1):101-107
Geotextile filters are rapidly replacing graded granular filters as the standard of practice in geotechnical design. The objective
of the present study is to predict the behavior of the geotextile filter for the locally (Roorkee—India) available soils using
three different geotextiles (two nonwoven and one woven). Nonwoven geotextiles are commonly used in filtration applications.
This paper evaluates the long-term performance of two needle-punched nonwoven geotextiles and one woven geotextile. Filtration
tests on soil–geotextile filter systems were conducted in the laboratory in order to evaluate the filtration and clogging
behavior. Laboratory test program, include evaluation of performance of two different nonwoven and one woven geotextile filters
in combination with locally available Solani River Sand and Clayey Soil. The paper describes the concept and details of the
Fine Fraction Filtration (F3) test and presents data on three different geotextiles, which were evaluated using three different soil types. It is deduced
that in all filtration applications, the non-woven geotextile would perform better than the woven geotextile. 相似文献
950.
Eduardo E. Alonso Sarah M. Springman Charles W. W. Ng 《Geotechnical and Geological Engineering》2008,26(6):817-826
Two large-scale “in situ” demonstration experiments and their instrumentation are described. The first test (FEBEX Experiment)
involves the hydration of a compacted bentonite barrier under the combined effect of an inner source of heat and an outer
water flow from the confining saturated granite rock. In the second case, the progressive de-saturation of Opalinus clay induced
by maintained ventilation of an unlined tunnel is analyzed. The paper shows the performance of different sensors (capacitive
cells, psychrometers, TDR’s) and a comparison of fill behaviour with modelling results. The long term performance of some
instruments could also be evaluated specially in the case of FEBEX test. Capacitive sensors provide relative humidity data
during long transient periods characterised by very large variations of suction within the bentonite. 相似文献