Detection of rovibrationally excited H2 formed through the heterogeneous recombination of H atoms on a cold HOPG surface

This paper reports results from an experiment designed to measure the nascent rovibrational population of H₂ molecules that have formed through the heterogeneous recombination of H atoms on the surface of cosmic dust analogues under conditions approaching those of the interstellar medium (ISM). H₂ that has formed on a highly oriented pyrolytic graphite (HOPG) surface has been detected, using laser induced resonance-enhanced multi-photon ionization (REMPI), in the v = 1 (J= 0–3) rovibrational states at surface temperatures of 30 K and 50 K. These excited product molecules display rotational temperatures significantly higher than the target surface temperature. These first results suggest that a considerable proportion of the binding energy released on formation of the H₂ is deposited in the surface, in addition to internal excitation of the product molecules. This revised version was published online in July 2006 with corrections to the Cover Date.     

Evaluation of the possible slip surface of a highly heterogeneous rock slope using dynamic reduction method

A new method, the dynamic reduction method (DRM) combined with the strain-softening method, was applied to evaluate the possible slip surface of a highly heterogeneous rock slope of the Dagangshan hydropower station in Southwest China. In DRM, only the strength of the failure elements is reduced and the softening reduction factor K is adopted to calculate the strength parameters. The simulation results calculated by DRM show that the further slip surface on the right slope of the Dagangshan hydropower station is limited in the middle part of the slope, while both SRM (strength reduction method) and LEM (limit equilibrium method) predict a failure surface which extends upper and longer. The observations and analysis from the three recorded sliding events indicate that the failure mode predicted by DRM is more likely the scenario. The results in this study illustrate that for highly heterogeneous slopes with geological discontinuities in different length scales, the proposed DRM can provide a reliable prediction of the location of the slip surface.     

Simulating the effect of hydrate dissociation on wellhead stability during oil and gas development in deepwater

It is well known that methane hydrate has been identified as an alternative resource due to its massive reserves and clean property. However, hydrate dissociation during oil and gas development (OGD) process in deep water can affect the stability of subsea equipment and formation. Currently, there is a serious lack of studies over quantitative assessment on the effects of hydrate dissociation on wellhead stability. In order to solve this problem, ABAQUS finite element software was used to develop a model and to evaluate the behavior of wellhead caused by hydrate dissociation. The factors that affect the wellhead stability include dissociation range, depth of hydrate formation and mechanical properties of dissociated hydrate region. Based on these, series of simulations were carried out to determine the wellhead displacement. The results revealed that, continuous dissociation of hydrate in homogeneous and isotropic formations can causes the non-linear increment in vertical displacement of wellhead. The displacement of wellhead showed good agreement with the settlement of overlying formations under the same conditions. In addition, the shallower and thicker hydrate formation can aggravate the influence of hydrate dissociation on the wellhead stability. Further, it was observed that with the declining elastic modulus and Poisson’s ratio, the wellhead displacement increases. Hence, these findings not only confirm the effect of hydrate dissociation on the wellhead stability, but also lend support to the actions, such as cooling the drilling fluid, which can reduce the hydrate dissociation range and further make deepwater operations safer and more efficient.     

Geography and Rural Household Income： A Village Level Study in Henan Province, China

This study uses the data from a sample survey conducted in April 2007 on 1 251 rural households in 11 villages of Henan Province, the largest less developed agricultural province in China, to examine how geography affects rural household income (RHI). The quantitative analysis indicates following results. 1) The significance of the traditional geographical factors reduces as RHI rank increases. 2) The landform does not affect the RHI significantly. The per capita income of rural household in a plain area is lower than that in a mountainous area. And 3) the capital endowment and status of non-farm economic activities contribute to the increase of RHI. But the probability and intensity of non-farm economic activities of rural households in urban outskirts villages are higher than that in non-urban outskirts villages. Based on the results, the paper further concludes that geography still plays a significant role in rural development, but it is changing over time. The agricultural resources (such as per capita arable land) significantly affect RHI with the relatively lower income level, while the geographical location shows a more significant impact on RHI with the relatively high income level. Along with economic development, the proximity replaces the traditional geographical factors such as landform and physical resources as the major determining factor in RHI.     

Radon volumetric activity and ion production in the undisturbed lower atmosphere: Ground-based observations and numerical modeling

The results of in situ ground-based observations of radon volumetric activity carried out at the Borok Geophysical Observatory of Schmidt Institute of Physics of the Earth of the Russian Academy of Sciences (58°04′ N; 38°14′ E) are presented. Modeling the characteristic diurnal variation in the ion production rate in the undisturbed midlatitude lower atmosphere above land is carried out. The Lagrangian stochastic model of turbulent transport is developed in application to determining the vertical profiles of radon activity for 222Rn and 220Rn isotopes and their radioactive decay products. The results calculated by the Lagrangian stochastic model are matched with the analytical solution for the free atmosphere. Based on the model, the estimate is obtained for the rate of radon outflow from the convective boundary layer to the free clear sky atmosphere. The implications of temperature stratification of the atmosphere for the vertical distribution of the ion production rate at the different radon emission rate are explored.     

Interannual variability of soil moisture in the European part of Russia in summer

Interannual and interdecadal variability of soil moisture in the European part of Russia in summer months is investigated using the data for 1948-2012. It is found that the two first empirical orthogonal functions (EOFs) describe about 50% of total variability of soil moisture. The spatial pattern of the first EOF is indicative of coherent changes in soil moisture in the whole European part of Russia. The second EOF is represented by the meridional dipole with the opposite signs of soil moisture variations in the northern and southern parts of the region. It is revealed that the spatiotemporal pattern of the principal EOFs of soil moisture variability in the European part of Russia almost does not vary during summer that is indicative of the uniform (for each EOF) mechanism of the formation of interan-nual variability of soil moisture.     

Exsolution in the mss-pentlandite system: Textural and genetic implications for Ni-sulfide ores

Experimentation in synthetic systems is essential for a correct interpretation of ore-mineral textures such as the pyrrhotite-pentlandite (po-pn) intergrowths of Ni-sulfide deposits. Within the Fe-Ni-S system, isothermal and cooling exsolution experiments were performed on monosulfide solid solution (mss) of various compositions using sealed, evacuated silica-glass tubes. The charges were annealed between 400° and 200°C for periods ranging from 20 minutes to 5 weeks; also, charges were cooled from 500° to 100°C at 1°C/h. Early-formed isothermal textures form by nucleation and growth, and depend on the initial degree of supersaturation and metal diffusivities; the final textures result from further growth and coarsening of the early forms and are particularly sensitive to the diffusivities, which are a function of temperature. The cooling-rate experiments indicate that massive pn develops by exsolution between 610° and about 250°C during slow cooling from temperatures above the mss-pn solvus; coarsened pn forms along basal planes in the mss matrix between about 250° and 150°C; pn "Flames" result at 150°C or slightly below. Crossing pn lamellae, obtained isothermally at high degrees of supersaturation and virtually unknown in ores, cannot form during slow cooling.     

Wind tunnel modeling of small-scale meteorological processes

After introductory remarks on similarity laws to be satisfied in wind tunnel experiments simulating small-scale meteorological processes, mean and turbulence characteristics of wind tunnel boundary layers are presented and compared with the characteristics of the atmospheric boundary layer. The results are used to evaluate the possibilities and limitations of physical modeling of pollutant dispersion in general. In the second part of the paper, the potential of wind tunnels to solve micro-meteorological problems of real practical interest will be demonstrated. The example involves the investigation of the effects of building downwash on ground-level concentrations for flue gases discharged from natural draft wet cooling towers.