Ophiolitic association of Cape Fiolent area,southwestern Crimea

An ophiolitic association consisting of serpentinized ultramafic rocks and serpentinite, layered mafic–ultramafic complex, gabbro and gabbrodolerite, fragments of parallel dike complex, pillow lava, black bedded chert, and jasper has been identified for the first time by authors in the Cape Fiolent area. The chemistry of pillow lavas and dolerites, including REE patterns and a wide set of other microelements, indicates suprasubduction nature of the ophiolites and their belonging to a backarc basin that has reached the stage of spreading in its evolution.     

Geodynamics and underlying bedrock of the magnetically active crust layer of the Lut block,Eastern Iran

The Curie point depth map of Eastern Iran was constituted from spectral analysis of the aeromagnetic data. The reduction to pole (RTP) was applied to the magnetic anomaly data. The Curie point depth values from 165 overlapping blocks, 100 × 100 km in size, have been estimated. The Curie point depth method provides a relationship between the 2-D FFT power spectrum of the magnetic anomalies and the depth of magnetic sources by transforming the spatial data into the frequency domain. The centroid and top depth of the magnetic sources (respectively Z₀ and Z_t) is calculated from radially averaged log power spectrum for each block. Finally, the Curie point depth of Eastern Iran is obtained by Z_b = 2Z₀–Z_t. The highest value of 24 km is located in eastern and western boundaries of the Lut block, and the lowest value of 12 km is located at north of study area. The shallow depths in the Curie-point depth map are well correlated with the young volcanic areas and geothermal potential fields. Geothermal gradient ranging from 24 to 45°C/km. The deduced thermal structure in eastern Iran has a relationship with orogenic collapse associated with delamination of thickened lithospheric root between the Lut and Afghan continental blocks.     

Tectonic setting discrimination diagrams for terrigenous rocks: a comparison

An attempt is made to compare discrimination diagrams of the first (mid-1980s) and second (early 2010s) generations compiled using data for sedimentary successions of different ages. Our results suggest that the diagrams of different generations allow more or less correct discrimination only between the platform, rift, passive margin, and island arc settings. The data for collision sediments do not form separate fields in these diagrams.     

The Latnenskoe refractory clay deposit (Central Russia)

This paper reports the results of our recent studies and generalizes previously known data on the geology, mineralogy, geochemistry, and genesis of the Russia’s largest Latnenskoe refractory clay deposit. It is shown that conditions of its localization were defined by regional and local factors. The regional factors controlled the distribution of the clay raw material in the region, while the local factors were responsible for the genesis and composition of refractory clays of the Latnenskoe deposit. Our studies showed that the formation of refractory clays is not only related to terrigenous but also to authigenic processes of sedimentation. The terrigenous component of clays was formed by the erosion of kaolin weathering crusts of the Voronezh anteclise crystalline basement and Paleozoic sedimentary hydromica–kaolinite rocks. Authigenic processes were significantly contributed by organic matter, which determined the environmental pH and Eh parameters. It is established that the mineral matter of clays of the deposit is represented by three morphological modifications (crystalline, amorphous, and biomorphic), which were formed subsequently and (or) simultaneously and could be transformed into each other. Application of a complex of modern precision methods allowed us to reveal a previously unknown biomorphic modification of kaolinite, the major rock-forming mineral, as well as mixed-layer kaolinite-smectite in the clays. It is shown that the distribution of major and trace elements and the sulfur isotope composition in different technological types of clay depend mainly on the facies conditions of their formation. Technological properties of clay raw material are considered.     

Chemical analysis of natural objects by ion chromatographic method in combination with a priori calculations using IONCHROM software

This paper briefly describes original developments in the theoretical and practical ion chromatography. It is demonstrated that new methods may be applied for the highly-selective analysis of complex natural objects. The determination of different species of sulfur and other ions in the condensates of fumarolic gases is considered in detail as an example.     

Separation of concentrated acid and salt solutions in nanoporous media as the basis for a new technology of processing of phosphorus-containing raw materials

The physical and mathematical models were used to study the method of acid retardation for separating acids from their salts in concentrated multicomponent solutions using nanoporous sorption materials. A combined mechanism of separation relies on the fact that in the sorption phase having a low dielectric permittivity, smaller-sized acid particles, namely, the molecules or strongly bound and weakly hydrated ion pairs, can penetrate the nanopores and are retained within these pores due to molecular sorption or competitive solvation forces. The dissolved salts presented by highly hydrated ions or weakly bound ion pairs can easily pass through the porous medium with a flow of concentrated solution, which is pumped through the column packed with the granulated bed of gel-type ion exchange resins or hypercrosslinked polymers. In conventional cyclic AR processes, purified acid is desorbed by water according to the mechanism of competitive solvation. However, such processes can be successfully used only when the salts separated from acids are highly soluble, as is the case with chloride and nitrate solutions free of components that may form compounds insoluble in neutral medium. At the separation in real sulfate and phosphate media, which normally contain alkaline earth metals and other components, conventional AR- based technologies proved to be unsuccessful. The new modified version of acid retardation is based on the previously discovered effect of stabilization of colloidal systems and supersaturated solutions in porous ion exchange media. A distinctive feature of the proposed technique is the use of weakly acidic aqueous solutions, instead of water, at the stages of acid displace in the cyclic AR processes. The proposed technique of WPA purification using strong-base gel-type ion exchangers in the phosphate form opens up the possibility of stable and feasible processes of acid separation and purification with simultaneous extraction of valuable components, e.g., REE concentrate.