High-pressure metallization and electronic-magnetic propertiesof hexagonal cubanite (CuFe2S3)

^?57Fe Mössbauer studies at room temperature and temperature-dependent resistance studies have been performed on a natural specimen of cubanite (CuFe₂S₃) in a diamond-anvil cell at pressures up to ～10 GPa. An insulator-metal phase transition occurs in the range 3.4–5.8 GPa coinciding with a previously observed structural transition from an orthorhombic to a hexagonal NiAs (B8) structure. The room temperature data shows that the metallization process concurs with a gradual transition from a magnetically ordered phase at low pressure to a nonmagnetic or paramagnetic phase at high-pressure. The change in magnetic behaviour at the structural transition may be attributed to a reduction of the Fe-S-Fe superexchange angle formed by edge-sharing octahedra occurring in the high-pressure phase. The non-magnetic or paramagnetic metallic phase at high pressure is retained upon decompression to ambient pressure-temperature conditions, indicative of substantial hysteresis associated with the pressure driven orthorhombic→hexagonal structural transition. The pressure evolution of both the ⁵⁷Fe Mössbauer hyperfine interaction parameters and resistance behaviour is consistent with the transition from mixed-valence character in the low pressure orthorhombic structure to that of extended-electron delocalization in the hexagonal phase at high-pressure.     

Deep-water geomorphology of the glaciated Irish margin from high-resolution marine geophysical data

The continental margin offshore of western Ireland offers an opportunity to study the effects of glacial forcing on the morphology and sediment architecture of a mid-latitude margin. High resolution multibeam bathymetry and backscatter data, combined with shallow seismic and TOBI deep-towed side-scan sonar profiles, provide the basis for this study and allow a detailed geomorphological interpretation of the northwest Irish continental margin. Several features, including submarine mass failures, canyon systems and escarpments, are identified in the Rockall Trough for the first time. A new physiographic classification of the Irish margin is proposed and linked to the impact of glaciations along the margin. Correlation of the position and dimensions of moraines on the continental shelf with the level of canyon evolution suggests that the sediment and meltwater delivered by the British–Irish Ice Sheet played a fundamental role in shaping the margin including the upslope development of some of the canyon systems. The glacial influence is also suggested by the variable extent and backscatter signal of sedimentary lobes associated with the canyons. These lobes provide an indirect measurement of the amount of glaciogenic sediment delivered by the ice sheet into the Rockall Trough during the last glacial maximum. None of the sedimentary lobes demonstrates notable relief, indicating that the amount of glaciogenic sediment delivered by the British–Irish Ice Sheet into the Rockall Trough was limited. Their southward disappearance suggests a more restricted BIIS, which did not reach the shelf edge south of 54°23′ N. The various slope styles observed on the Irish margin represent snapshots of the progressive stages of slope development for a glacially-influenced passive margin and may provide a predictive model for the evolution of other such margins.     

Fore‐arc evolution in the Tasman Geosyncline: The origin of the southeast Australian continental crust

A new general model describing the extended evolution of fore‐arc terrains is used to analyse the evolution of the southern Tasman Geosyncline and the concomitant growth and kratonisation of the continental crust of southeast Australia during the Palaeozoic. The southern Tasman Geosyncline comprises ten arc terrains (here defined), most of which are east‐facing, and several features formed by crustal extension. Each arc terrain consists of several strato‐tectonic units: a volcanic arc, subduction complex and fore‐arc sequence formed during subduction; and an overlying post‐arc sequence which post‐dates subduction and is composed of flysch, neritic sediments or subaerial volcanics.

When these materials attained a thickness of c. 20 km their internal heat‐balance caused partial melting of the subduction complex and the hydrated oceanic lithosphere trapped beneath it, to yield S‐ and I‐type granitic magma. The magma rose, inducing pervasive deformation of each arc terrain and emplacement of granitoid plutons at high levels in the evolving crust. Transitional basins then developed in many terrains on top of their volcanic arcs or the thinner parts of the buried accretionary prisms. After deformation of the transitional sequences, platform cover accumulated, marking the completion of kratonisation.

Analysis of each arc terrain in terms of the above units leads to a predicted ‘stratigraphy’ for the continental crust of southeast Australia. The crust is complexly layered, with lateral discontinuities reflecting the boundaries of arc terrains which were successively accreted, principally back‐arc to fore‐arc, during crustal development.     

Coalification in Carboniferous sediments from the Lötschberg base tunnel

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.     

The variability of ruthenium in chromite from chassignite and olivine‐phyric shergottite meteorites: New insights into the behavior of PGE and sulfur in Martian magmatic systems

The Martian meteorites comprise mantle‐derived mafic to ultramafic rocks that formed in shallow intrusions and/or lava flows. This study reports the first in situ platinum‐group element data on chromite and ulvöspinel from a series of dunitic chassignites and olivine‐phyric shergottites, determined using laser‐ablation ICP‐MS. As recent studies have shown that Ru has strongly contrasting affinities for coexisting sulfide and spinel phases, the precise in situ analysis of this element in spinel can provide important insights into the sulfide saturation history of Martian mantle‐derived melts. The new data reveal distinctive differences between the two meteorite groups. Chromite from the chassignites Northwest Africa 2737 (NWA 2737) and Chassigny contained detectable concentrations of Ru (up to ~160 ppb Ru) in solid solution, whereas chromite and ulvöspinel from the olivine‐phyric shergottites Yamato‐980459 (Y‐980459), Tissint, and Dhofar 019 displayed Ru concentrations consistently below detection limit (<42 ppb). The relatively elevated Ru signatures of chromite from the chassignites suggest a Ru‐rich (~1–4 ppb) parental melt for this meteorite group, which presumably did not experience segregation of immiscible sulfide liquids over the interval of mantle melting, melt ascent, and chromite crystallization. The relatively Ru‐depleted signature of chromite and ulvöspinel from the olivine‐phyric shergottites may be the consequence of relatively lower Ru contents (<1 ppb) in the parental melts, and/or the presence of sulfides during the crystallization of the spinel phases. The results of this study illustrate the significance of platinum‐group element in situ analysis on spinel phases to decipher the sulfide saturation history of magmatic systems.     

Stratigraphie und Fazies des Erzgebirgischen Kristallins im Rahmen des Mitteleuropäischen Varistikums

Zusammenfassung Es läßt sich zeigen, daß im erzgebirgischen Raum die jungalgonkische Serie des varistischen Sockels von der Petrofazies diskordant geschnitten wird. Im Bereich des erzgebirgischen Kristallins steigt die Amphibolitfazies beulenförmig bis an die Basis des varistischen Sedimenttroges auf. Mit diesem Aufstieg wird eine Granitbildung regionalen und lokalen Charakters als möglich in Verbindung gebracht.

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It can be demonstrated that the Upper Algonkian rocks of the Hercynian basement are disconformably cut by the petrofacies of the Erzgebirge. In the environment of crystallin rocks amphibolitic facies ascend to the bottom of the hercynian sedimentary trough. With this rise a granitisation of regional and locally restricted character might seem to be possible.

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Résumé On peut montrer que dans la région de l'Erzgebirge les couches de l'Algonkien supérieur du socle hercynien sont recoupées en discordance par le petrofacies. Dans le domaine du cristallin de l'Erzgebirge, le facies amphibolite a la forme d'un dûme atteignant la base de la fosse sédimentaire varisque. On croit pouvoir établir une relation entre la formation de granite à l'échelle régionale et locale et cette montée métamorphique.

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Herrn Prof. Dr. Dr. h. c.Erich Bederke zum 70. Geburtstag gewidmet.     

Cadmium absorption and accumulation in different parts of kidney beans, radishes and pumpkins

This study is done to measure the absorption and distribution of cadmium in different parts of kidney beans, radishes and pumpkins. Three parts of a field was chosen. In one part 65 ppm of cadmium nitrate was added to water and in the other part 130 ppm, the last part was irrigated with normal water. Samples were digested by EPA 3050 method. Cadmium concentration was measured by Unicam 919 absorption unit. Beans accumulate cadmium mostly in root (70 ppm) and a little amount is mobilized through upper parts (12–16ppm), but kidneys did not accumulate a significant amount. In radishes the roots did not accumulate a significant amount of cadmium but stems had 4 ppm and leaves had 25 ppm. Cadmium concentration in soil does not affect its concentration in different parts of pumpkins and beside the stems and leaves (4 ppm) the other parts' concentrations were insignificant. In regard to the results of this study the cadmium concentrations in edible parts of the samples (kidney beans, radish roots and pumpkin fruit) were less than the U.S. EPA standards for agriculture and human beings.     

Quaternary evolution of Cedar Creek alluvial fan, montana

Cedar Creek alluvial fan is a textbook example of an alluvial fan because of its fan shape with smooth, concentric contours and excellent symmetry. Similar planimetric shapes have been used to infer uniform fan deposition; however, Cedar Creek alluvial fan is composed of four fan deposits of Quaternary age, Qf1 (oldest) to Qf4 (youngest), indicating that fan deposition was nonuniform in both time and space. Field studies indicate that deposition of Cedar Creek alluvial fan is related to glaciofluvial outwash activity during the Pleistocene and upper-fan entrenchment and lower-fan deposition during the Holocene.Qf1 and Qf2 deposits are sub-horizontally bedded, clast-supported sandy gravels uniformly imbricated upfan. Comparison of soil profiles developed in these deposits to radiogenically-dated chronosequences within the region indicates that Qf1 and Qf2 are correlative with Bull Lake and Pinedale-age deposits, respectively. These relationships are substantiated by physical correlation of Qf1 and Qf2 with Bull Lake and Pinedale moraines, respectively, in the Cedar Creek drainage basin. The sedimentology and timing of Qf1 and Qf2 indicate deposition in high-energy, proglacial, braided streams. Furthermore, the present morphology of Cedar Creek alluvial fan was established largely during aggradation of Qf1 and Qf2 when sediment supply to the fan was sufficient to activate 60% to greater than 90% of the total fan area. During Bull Lake glaciation, the apex of Qf1 deposition formed the apex of Cedar Creek alluvial fan as Qf1 covered more than 90% of the present fan area. During Pinedale glaciation, Qf2 deposition shifted downfan; Qf2 is inset into Qf1 above the intersection point, but below the intersection point it eroded and/or buried Qf1 as it activated as much as 60% of the fan area.Qf3 and Qf4, comprising 21% of the fan area, are inset into Qf2 in the lower fan area. Soil development in Qf3 and Qf4 deposits indicate episodic deposition and entrenchment beginning in early Holocene and continuing to present. A post-glacial decrease in sediment supply to Cedar Creek alluvial fan is indicated by sediment storage within the Cedar Creek drainage basin. Decreased sediment supply to the fan resulted in upper-fan entrenchment of Qf2 and deposition of Qf3 and Qf4 in the lower-fan area.