Lithium isotopes in the system Qz-Ms-fluid:An experimental study

The fractionation of lithium isotopes among quartz, muscovite, and a chloride-bearing aqueous fluid has been investigated experimentally at 400°-500°C and 50-100 MPa. Experiments were performed for 15-60 days in cold seal vessels with natural mineral specimens. Lithium was introduced primarily through the fluid, which also contained KCl and HCl. In most runs, the fluid was prepared with the L-SVEC standard (δ⁷Li = 0) and was 1 M in total chloride with K/Li/H = 100/10/1. In two experiments, a ⁶Li spike was employed. The experiments demonstrate that quartz and muscovite are susceptible to pronounced, rapid shifts in Li isotopic composition by diffusion through interaction with a Li-bearing fluid, particularly at 500°C. At 500°C, fractionation factors were determined to be Δ_{quartz-aqueous} ≅ +8 to + 12‰ and Δ_{muscovite-aqueous} ≅ +18 to + 20‰. An intermineral fractionation factor is given by Δ_{muscovite-quartz} ≈ +9‰. At 400°C, the results suggest Δ_{quartz-aqueous} ≈ +4 to + 6‰. The study provides evidence of systematic fractionation in lithium isotopes at the temperatures of some magmatic processes, such as those associated with porphyry-type ore systems and pegmatites.     

Planetesimal sulfate and aqueous alteration in CM and CI carbonaceous chondrites

Water-soluble sulfate salts extracted from six CM chondrites have oxygen isotope compositions that are consistent with an extraterrestrial origin. The Δ¹⁷O of sulfate are correlated with previously reported whole rock δ¹⁸O and with an index of meteorite alteration, and may display a correlation with the date of the fall. The enrichments and depletions for Δ¹⁷O of water-soluble sulfate from the CM chondrites relative to the terrestrial mass dependent fractionation line are consistent with sulfate formation in a rock dominated asteroidal environment, and from aqueous fluids that had undergone relatively low amounts of oxygen isotope exchange and little reaction with anhydrous components of the meteorites. It is unresolved how the oxidation of sulfide to sulfate can be reconciled with the inferred low oxidation state during the extraterrestrial alteration process. Oxygen isotope data for two CI chondrites, Orgueil and Ivuna, as well as the ungrouped C2 chondrite Essebi are indistinguishable from sulfate of terrestrial origin and may be terrestrial weathering products, consistent with previous assertions. Our oxygen isotope data, however, can not rule out a preterrestrial origin either.     

The geological significance of a negative gravity anomaly in the South Wales Coalfield

Three gravity traverses across the eastern half of the South Wales Coalfield indicate a local, elongate, negative Bouguer anomaly of a few milligals amplitude bordering the southern rim. The anomaly has a maximum amplitude of 4 mgal near Maesteg and attenuates eastward, dying out in the vicinity of the East Crop. Two possible geological causes of the anomaly are examined, namely a local thick sequence of normal Upper Carboniferous strata and a discrete, low-density body of Carboniferous age with no apparent surface expression. The former, uncontroversial explanation requires rock densities at variance with measured values. In the case of the hypothetical low density body which can explain the anomaly, a variety of possible ages and configurations are discussed.     

The Pleistocene history of Wales and the borderland

The Pleistocene rock-stratigraphic record is accorded more or less traditional time-stratigraphic interpretation which was held widely before application of an Irish developmental model in 1960. The following sequence of events are recognised: (1) Complete glaciation, of indeterminate age, which antedated the raised beach interglacial. (2) The raised beach episode which is shown to be the last (Ipswichian) interglacial. (3) The last (Devensian/Weichselian) glaciation, followed by possible readvance in northwest and northeast Wales; prior and subsequent to glaciation periglacial conditions obtained. It is shown that the Irish model, relying heavily as it does on the equation of rock and time stratigraphy, is inapplicable in Wales.     

Caledonian metamorphism in part of northwest County Mayo,Ireland

Lewisian gneisses, Moinian and Dalradian sediments, and dolerites have been deformed and metamorphosed under Amphibolite Fades conditions. The metamorphic climax, with the growth of kyanite and staurolite, occurred after the cessation of the second deformational episode and before the onset of the third. Plagioclase growth ceased at or about the time of kyanite and staurolite nucleation. Metamorphic effects become less to the south and southeast while the most advanced stages occur around Inver. A single heat pulse appears to be not directly related to any structure.     

A resistivity section of Holy Island (Anglesey)

An account is given of the use of square array resistivity techniques to derive an apparent resistivity section down the length of Holy Island (Anglesey). Possible interpretations of this section in terms of the distribution of true resistivity with depth are given and discussed briefly in relation to proposed geological structure.