Integration of reflection seismic and sediment grain-size data from Lake Khubsugul (Northern Mongolia): a reply to Prokopenko and Kendall

Prokopenko and Kendall (J Paleolimnol doi:, 2008) criticise the work presented in Fedotov et al. (J Paleolimnol 39:335–348, 2008), and instead propose an alternative interpretation for the grain-size evolution recorded in the KDP-01 core, retrieved from the central part of Lake Khubsugul. Their interpretation is based (i) on a seismic-stratigraphic re-interpretation of sparker seismic profile khub012 (which they copied from Fedotov et al. (EOS Trans 87:246–250, 2006)), (ii) on the presupposition that changes in lake level are the dominant control on facies distribution in Lake Khubsugul, and (iii) on the invalidation of our age-depth model. In this reply to their comment, we demonstrate that they interpreted seismic artefacts and geometries caused by changes in profile orientation as true stratigraphic features and that the lake-level reconstruction they derive from this interpretation is therefore incorrect. We also demonstrate that their grain-size predictions, which they consider to be predominantly driven by changes in lake level, are inconsistent with the measured sulphate concentration, which is a demonstrated proxy of lake level in Lake Khubsugul, and with the measured grain-size record. Finally, we point out that even if there would be a problem with the age-depth model, this problem would not affect the part of the sedimentary sequence discussed in Fedotov et al. (J Paleolimnol 39:335–348, 2008).     

Thermal and exhumation history of the central Rwenzori Mountains, Western Rift of the East African Rift System, Uganda

The Rwenzori Mountains (Mtns) in west Uganda are the highest rift mountains on Earth and rise to more than 5,000 m. We apply low-temperature thermochronology (apatite fission-track (AFT) and apatite (U–Th–Sm)/He (AHe) analysis) for tracking the cooling history of the Rwenzori Mtns. Samples from the central and northern Rwenzoris reveal AFT ages between 195.0 (±8.4) Ma and 85.3 (±5.3) Ma, and AHe ages between 210.0 (±6.0) Ma to 24.9 (±0.5) Ma. Modelled time–temperature paths reflect a protracted cooling history with accelerated cooling in Permo-Triassic and Jurassic times, followed by a long period of constant and slow cooling, than succeeded by a renewed accelerated cooling in the Neogene. During the last 10 Ma, differentiated erosion and surface uplift affected the Rwenzori Mtns, with more pronounced uplift along the western flank. The final rock uplift of the Rwenzori Mtns that partly led to the formation of the recent topography must have been fast and in the near past (Pliocene to Pleistocene). Erosion could not compensate for the latest rock uplift, resulting in Oligocene to Miocene AHe ages.     

Paleoceanography of surface waters in the Gulf of Mexico during the late Quaternary

Late Quaternary paleotemperatures and paleosalinities of surface waters of the Gulf of Mexico were estimated using a multivariate statistical analysis of census data of planktonic foraminifera. Two climatic extremes were selected for detailed basinwide study, the climatic optimum 125,000 yr ago and the glacial maximum 18,000 yr ago. In addition, patterns of climatic change were examined in seven piston cores from 127,000 yr ago to the present day. During the climatic optimum 125,000 yr ago temperature distributions in surface waters were similar to those of the present. The 22°C winter isotherm trended northeastward across the central basin and paleotemperatures decreased northward. Summer distributions were nearly homogeneous and ranged between 28° and 29°C. Winter salinities were 1‰ fresher than present values in the northmost Gulf and 0.4‰ fresher in the central basin. Summer salinities were similar during both times. In contrast, during the last glacial maximum temperatures were 1° to 2°C cooler in winter and 1°C cooler in summer, and isotherms formed a circular pattern in the Gulf during both seasons. Salinity was 0.3‰ fresher in winter than at present but 0.6‰ saltier in summer. Conditions deteriorated from the climatic optimum to the glacial maximum. In the Mexico Basin, winter temperatures were 2°C cooler from 75,000 to 45,000 yr ago (Y6 to Y3 Subzones), summer temperatures reached a minimum (3°C cooler) 32,000 yr ago (Y2–Y3 boundary), and seasonality reached minimal values (5°C) from 45,000 to 15,000 yr ago. All three parameters became similar in value to those in the Straits of Florida from 45,000 to 15,000 yr ago, suggesting that the exchange of surface waters was enhanced at this time between the two regions. Summer salinities remained similar to present conditions in the Mexico Basin, whereas, winter salinities increased 2‰ by 32,000 yr ago and then fell 0.5‰ until the glacial maximum ended. The Westerlies may have migrated southward over the Mexico Basin in winter from 32,000 to 15,000 yr ago.     

Facies Structure and Quantitative Parameters of Pleistocene Sediments of the Bering Sea

Lithofacies zoning is described for the first time for the Neo- and Eopleistocene of the Bering Sea. Four lithofacies sedimentation zones are distinguished: (I) terrigenous; (II) siliceous–terrigenous; (III) siliceous, and (IV) volcanoterrigenous ones. Corresponding maps were treated using Ronov volumetric method to quantify sedimentation parameters for distinguished lithofacies zones (subzones) and types of Pleistocene sediments. It was revealed that terrigenous sediments predominate over other sediments. Accumulation of the terrigenous sediments was more intense (by 1.4 times) in the Neopleistocene than in the Eopleistocene. The sedimentation rate of siliceous sediments of the Bowers Ridge in the Eopleistocene was two times higher than in the Neopleistocene.     

The relation between typical concentrations of chemical constituents in potable water and their injurious limits

 There is an obvious similarity between the values of the typical concentrations of the inorganic and synthetic organic constituents in potable water and their injurious limits to human health. This similarity is attributed to the adaptation of man to his environment, i.e. it has resulted from natural selection. Received: 6 August 1999 · Accepted: 30 November 1999     

Geochemical signatures of two different coastal depositional environments within the same catchment

The geochemistry of lake (Renstradträsket) and estuarine (Pieni Pernajanlahti Bay) sediment was investigated in a medium sized watershed draining to the Gulf of Finland, Baltic Sea. Catchment land-use types were compared and found similar. Sediment cores were dated using ²¹⁰Pb- and ¹³⁷Cs-chronologies and analyzed for Al, K, Cu, Zn, Fe, Mn, phosphorus fractions, TN, TC and biogenic silica (BSi). Differences between the sediment cores were studied by using linear regression analysis and principal components analysis (PCA). Despite similarities in catchment land-use and history, the sediment geochemical profiles of the sites varied significantly. Some of the differences could be related to differences in chemical sedimentation environment (lacustrine versus estuarine). TP concentration was found to be positively correlated with sediment iron content in estuarine sediment but negatively correlated with Fe in lake sediment. In the estuarine core sedimentary iron was not correlated to lithogenic potassium and aluminum but in the lake core the iron seemed to be lithogenic in origin, as suggested by the strong positive correlations (r ² = 0.95–0.96) between these three variables. Most similarities among the cores were found in Al concentrations. Estuarine nutrient profiles appeared relatively monotonous compared to the lake core. This is probably due to more vigorous mixing of the sediments that may ensure more rapid and complete consumption of the organic matter deposited on the bottom of the estuary. Therefore the lake sediment appeared to preserve the historical record of eutrophication better. Biologically less active and more particle-bound materials like the trace metals Cu and Zn seemed to retain good records of anthropogenic impact also in the estuarine core. The study highlights the need to take the sedimentation environment into account when interpreting geochemical record.     

A numerical model of the partitioning of trace chemical solutes during drop freezing

Partitioning of volatile chemicals among the gas, liquid, and solid phases during freezing of liquid water in clouds can impact trace chemical distributions in the troposphere and in precipitation. We describe here a numerical model of this partitioning during the freezing of a supercooled liquid drop. Our model includes the time-dependent calculation of the coupled processes of crystallization kinetics, heat transport, and solute mass transport, for a freezing hydrometeor particle. We demonstrate the model for tracer partitioning during the freezing of a 1000 μm radius drop on a 100 μm ice substrate, under a few ambient condition scenarios. The model effectively simulates particle freezing and solute transport, yielding results that are qualitatively and quantitatively consistent with previous experimental and theoretical work. Results suggest that the ice shell formation time is governed by heat loss to air and not by dendrite propagation, and that the location of ice nucleation is not important to freezing times or the effective partitioning of chemical solutes. Even for the case of nucleation at the center of the drop, we found that dendrites propagated rapidly to form surface ice. Freezing then proceeded from the outside in. Results also indicate that the solid-liquid interfacial surface area is not important to freezing times or the effective partitioning of chemical solutes, and that the rate aspects of trapping are more important than equilibrium solid-liquid partitioning to the effective partitioning resulting from freezing.     

Assessment of Nitrate—Nitrogen Distribution in Kansas Groundwater, 1990–1998

Nitrate-nitrogen (nitrate-N) in groundwater is a potential problem in many parts of Kansas.From 1990 to 1998, 747 water samples were collected from domestic, irrigation, monitoring,and public water supply wells primarily from the western two-thirds of the state, and analyzedfor nitrate-N by the Kansas Geological Survey. Nitrate-N concentrations of the 747 samplesanalyzed range from 29% with less than or equal to 3 mg/L, 51% between 3 and 10 mg/L,and 20% greater than or equal to 10 mg/L. Factors that show a statistically significantrelationship with the occurrence of nitrate-N in Kansas groundwater in this assessment includegeographic area of the state, depth of well, and age of well. Nitrate-N levels of wells screenedin the High Plains aquifer in south-central Kansas showed a statistically higher concentrationthan samples collected from the High Plains aquifer in the western portion of the state.Comparison of nitrate-N with depth of well indicated that shallower wells throughout the stategenerally have higher nitrate-N values than deeper wells. Irrigation wells older than 1975showed statistically higher nitrate-N concentration than wells installed during and since 1975,possibly related to changes in well-construction practices and regulations that occurred in 1975.     

Geoinformational Mapping of Landscapes in the Northwestern Part of Western Siberia Using the Hansen Mosaic Dataset

Presented are the technique and results of studying the landscape structure of the north-west of Western Siberia on the basis of the Hansen mosaic dataset consisting of elements covering the entire territory of the Earth. To study this area used a synthesis of classical methods of thematic system mapping as described in the doctrine of geosystems of V. B. Sochava, and automated interpretation of remote sensing data and mapping using GIS technologies. The method of geoinformational mapping of the landscape structure with the use of MultiSpec and Quantum GIS software programs for the purpose of drawing up real-time raster landscape maps is shown. In drawing up the map and the legend, the principle of geomic system-hierarchical representation of the territory as a complex multi-level “bottom-up” structure from topological-level geosystems (groups and classes of landscape facies) to regional-level geosystems (geoms, groups and classes of geoms) was used. Compilation of operational raster landscape maps of the north-west of Western Siberia involved multilevel automated interpretation of the Hansen mosaic dataset and mapping of areas (clusters) on images with different brightness characteristics, with the landscape structure of key areas and stationary physical and geographical profiles. A characteristic of this approach also implies using a dynamic classification of geosystems based on the study of their variable states. Such an approach permits a monitoring of changes in landscape structure and its areas and the intensity of anthropogenic impacts on forest and marsh landscapes, and determination of permissible pressure on geosystems in areas with high technogenic pressure of the oil and gas complex represented by the north-west of Siberia. An automated processing of data based on a supervised classification of territorial objects allows for the elimination of inaccuracies arising in visual image interpretation. Raster landscape maps can be used both for a further generation of vector maps and as a real-time information base for purposes of environmental management and protection.