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611.
Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The 176Hf/177Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic 176Hf/177Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system. 相似文献
612.
Paul R. Craddock Olivier J. Rouxel Lary A. Ball Wolfgang Bach 《Chemical Geology》2008,253(3-4):102-113
We have developed a technique for the accurate and precise determination of 34S/32S isotope ratios (δ34S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O2+. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical. 相似文献
613.
Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis 总被引:1,自引:0,他引:1
Konstadinos N. Moutsopoulos Alexandra Gemitzi Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090
The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection
zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the
present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying
a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a
wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield
delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem. 相似文献
614.
The Ras Al-Subiyah area is considered one of the most promising areas in Kuwait for future development. This development will
include a new town called Subiyah and its associated infrastructure. This area is also being considered as the location for
connection between Boubyan Island, which is now undergoing major development and the Kuwait mainland. The present study investigates
the geomorphology of the Ras Al-Sabiyah area in the northern sector of Kuwait. The study area is generally flat, and it is
located west of the Jal Az-Zor escarpment. It is bordered on the east by the Khor Al-Sabiyah tidal channel and on the south
by Kuwait Bay. The area receives sediments from several sources; currently the most important are aeolian sediments and the
deposition of mud delivered through the Khor Al-Sabiyah from the Iraqi marshes. The study area has been subjected to severe
environmental changes due to the Gulf wars and the drainage of Iraqi marshes and the associated artificial changes in fluvial
system. Twenty-two surface sediments were collected from the Ras Al-Subiyah area. Samples were collected to include the main
geomorphologic characteristic features of the study area. Field observations and remote sensing images from 1990 and 2001
were used to produce an updated geomorphologic map for the Ras Al-Subiyah and a map showing geomorphic changes between 1990
and 2001. Grain size of the surface sediment ranges from gravel to medium sand. In general, grain size statistical analysis
indicates that most of the areas are composed of two or more classes of sands transported and deposited from different sources
including aeolian, sabkhas, river and the bays. The variability in the grain size statistical parameters may be attributed
to the complexity of surface morphology as well as the diversity in the type of depositional environment in the Ras Al-Subiyah
area. The total area subjected to change during the 12-year period (1990–2001) is about 32 km2 as calculated using GIS techniques. 相似文献
615.
L. Moreno J. J. Durán M. A. Casermeiro J. R. Quintana Ma A. Fernández 《Environmental Geology》2008,54(3):465-477
Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored
to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the
best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate
is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is
almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil
and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass
discharged was relatively large (COD 14,656 g/m2, NO3 85 g/m2, NO2 4 g/m2, NH4 2,425 g/m2, PO4 1,143 g/m2, K 1,531 g/m2, B 63 g/m2). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO4 94.4%, K 59.17%, N
total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was
eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts
of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of
the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water,
and are proposed as the best indicators. 相似文献
616.
Doline probability map using logistic regression and GIS technology in the central Ebro Basin (Spain) 总被引:3,自引:0,他引:3
In the surroundings of Zaragoza, karstification processes are especially intense in covered karst areas where fluvial terraces
lie directly on Tertiary evaporites. Since the beginning of Quaternary, these processes have lead to the development of collapse
and subsidence dolines with a wide range of sizes, which have significant economic impacts. To reduce economic impact and
increase safety, a regional analysis of this phenomenon is needed for spatial management. Therefore, a probability map of
dolines was developed using logistic regression and geographic information system (GIS) techniques. This paper covers the
selection of input data, manipulation of data using the GIS technology, and the use of logistic regression to generate a doline
probability map. The primary variable in the doline development in this area is geomorphology, represented by the location
of endorheic areas and different terrace levels. Secondary variables are the presence of irrigation and the water table gradient. 相似文献
617.
We propose a simple pressure test that can be used in the field to determine the effective permeability of existing wellbores.
Such tests are motivated by the need to understand and quantify leakage risks associated with geological storage of CO2 in mature sedimentary basins. If CO2 is injected into a deep geological formation, and the resulting CO2 plume encounters a wellbore, leakage may occur through various pathways in the “disturbed zone” surrounding the well casing.
The effective permeability of this composite zone, on the outside of the well casing, is an important parameter for models
of leakage. However, the data that exist on this key parameter do not exist in the open literature, and therefore specific
field tests need to be done in order to reduce the uncertainty inherent in the leakage estimates. The test designed and analyzed
herein is designed to measure effective wellbore permeability within a low-permeability caprock, bounded above and below by
permeable reservoirs, by pressurizing the reservoir below and measuring the response in the reservoir above. Alternatively,
a modified test can be performed within the caprock without directly contacting the reservoirs above and below. We use numerical
simulation to relate pressure response to effective well permeability and then evaluate the range of detection of the effective
permeability based on instrument measurement error and limits on fracture pressure. These results can guide field experiments
associated with site characterization and leakage analysis. 相似文献
618.
J. L. Simón M. A. Soriano L. E. Arlegui J. Gracia C. L. Liesa A. Pocoví 《Environmental Geology》2008,53(5):1057-1065
Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines),
aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as
well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines
computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times.
According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations
in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast,
rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries
through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not
have an equivalent in observed paleodolines. 相似文献
619.
Zaragoza city is located in the central Ebro Basin, in the Iberian Peninsula. The fluvial terraces formed by the Ebro River
present a valuable resource of sand and gravel deposits. However, taking advantage of these available resources implies conflicts
with other land use interests like urban and industrial development as well as agricultural use, which has also traditionally
occupied the alluvial terraces. These deposits represent a substantial groundwater resource that should be preserved for future
generations. The development of spatial decision support systems (SDSS) has greatly assisted efforts for solving land-use
conflicts. These systems combine the benefits of geographic information systems (GIS) and decision support methodologies and
are therefore suitable to manage sustainable development of urban areas. In this contribution, an extraction suitability map
taking into consideration a variety of environmental criteria is created with the help of a SDSS. The method used is the analytical
hierarchy process which is integrated in ArcGIS. Areas most suitable to sand and gravel extraction are located in the high
terraces, and in those terraces covered by pediments where the thickness of resource is relatively high. These areas are far
from valuable natural areas, outside areas most vulnerable to groundwater contamination, and beneath soils with poor irrigation
characteristics. 相似文献
620.
Quick-look assessments to identify optimal CO2 EOR storage sites 总被引:1,自引:0,他引:1
Vanessa Núñez-López Mark H. Holtz Derek J. Wood William A. Ambrose Susan D. Hovorka 《Environmental Geology》2008,54(8):1695-1706
A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of
reservoirs to generate a workable set of sites that closely match the requirements for optimal CO2 enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO2 EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities
of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that
the CO2 EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO2 sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of
technical and practical feasibility for miscible CO2 EOR. The second stage provides quick estimates of CO2 EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set
of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties,
disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow
in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves
time and allows more resources to be applied to the best candidate sites. 相似文献