1nm锰矿相的金属阳离子交换能力的研究

人工合成的1nm锰矿相和铜、钴、镍等二价金属阳离子的交换实验表明,1nm锰矿相具有强烈的金属阳离子交换能力.正是这种金属阳离子的交换能力,使得大洋多金属结核大量地富集了铜、钴、镍等有价金属元素.1nm锰矿相对几种金属阳离子的交换的优先顺序为:Cu>Co>Zn≥Ni>Ca>Mg.多金属结核中镍的含量往往高于铜、钴、锌等元素,但在交换顺序中它却低于铜、钴、锌等,这种不一致性说明结核成矿后期的金属离子交换并非是有价金属结合进结核的唯一途径.多金属结核富含铜、钴、镍等有价金属可能是结核初始成矿和成矿后期金属离子交换等多种因素共同作用的结果.     

阿拉伯海的扩张历史：某些新的控制条件

根据海台、无震海岭．活动洋中脊以及几条破碎带，可把阿拉伯海划分成几个深海盆地．这些盆地的进化历史已从地球物理的研究中推演出来．东阿拉伯海盆(EAB)位于Laxmi-Laceadive海岭及印度的西部大陆坡之间，被认为其下伏是由裂谷和相关过程形成的过渡地壳，     

Oxidative stress in Laeonereis acuta (Polychaeta, Nereididae): environmental and seasonal effects

Laeonereis acuta was seasonally collected in an industrially polluted site (P) and in an unpolluted site (UP) at the Patos Lagoon estuary (southern Brazil). Glutathione S-transferase (GST), superoxide dismutase (SOD) and catalase (CAT) activity (U/mg protein) was determined in five groups of worms from each site. Metallothionein (MT - mol GSH/g ww) and lipid peroxides content (LPO - nmoles of cumene hydroperoxide/g ww) were also measured. Annual mean values for CAT (UP=3.7+/-0.3; P=5.7+/-0.6), GST (UP=0.034+/-0.003; P=0.045+/-0.004) and MT (UP=0.15+/-0.02; P=0.23+/-0.03) were higher (p<0.05) in worms from the P site. In autumn, CAT activity was higher (p<0.05) in worms from the P site (7.6 +/- 1.3) than in those from the UP site (3.6 +/- 0.4). In summer, MT concentration was higher in worms from the P site (0.37 +/- 0.03) than in those from the UP site (0.19 +/- 0.01). No significant difference (p>0.05) in the LPO content was observed in worms from the different sites or collected in different seasons. These results indicate that worms from the polluted site showed higher antioxidant responses than those from the unpolluted site, sufficient to prevent oxidative damage in terms of LPO.     

Correlative changes in metabolism and DNA damage in turbot (Scophthalmus maximus) exposed to benzo[a]pyrene

Juvenile turbot (Scophthalmus maximus) were injected intraperitoneally with either corn oil or 5 mg/kg benzo[a]pyrene (BaP) dissolved in corn oil and sampled I and 3 days after injection. After 1 day, no elevation of 7-ethoxyresorufin O-deethylase (EROD) activity was observed, however bile metabolites (BaP-7,8 dihydrodiol representing 70% of the total metabolites) and a single hepatic DNA adduct spot (0.47 adducts/10(8) nucleotides) identified by 32P-postlabelling were formed. No BaP metabolites or DNA adducts were observed in either control or carrier control fish. Fish sampled after 3 days reported 5-fold higher (P < 0.05) levels of EROD activity, a shift in the bile metabolite profile towards BaP phenol formation (1OH and 30H BaP comprising up to 60% of total metabolites detected) and the formation of two adduct spots (0.86 and 0.71 adducts/10(8) nucleotides). These results show that BaP can be metabolised and form hydrophobic DNA adducts in turbot without EROD elevation. Following EROD elevation, a shift in the profile of both BaP metabolites and BaP metabolite-DNA interactions occurs indicative of other oxidative processes.     

Oxidative stress responses in two populations of Laeonereis acuta (Polychaeta, Nereididae) after acute and chronic exposure to copper

Acute (4 days) and chronic (14 days) effects of copper were evaluated on the antioxidant defenses of Laeonereis acuta (Polychaeta) collected in unpolluted (UP) and polluted (P) sites. In the acute assay (125 and 250 micro g Cu/l) superoxide dismutase (SOD) and glutathione S-transferase (GST) activities did not change, whereas catalase (CAT) increased in worms from both the sites. Lipid peroxidation was higher in copper exposed worms from the P site. In the chronic assay (62.5 micro g Cu/l) polychaetes from the P site showed enhanced activities of SOD, GST and CAT and higher contents of metallothionein-like proteins and sulfhydrils compared to worms from UP. Differences in responses between polychaetes from UP and P sites suggest that organisms from the polluted site, P, are more susceptible to oxidative stress conditions.     

Irish on the move

Trends in emigration from Ireland over time are reviewed. "During the eighteenth and nineteenth centuries overseas migration to the United States and seasonal harvest migration to Britain were the main types of movement, but over the past 100 years the Irish have developed a special affinity for settling in British towns. Although the outflow was halted for a time during the 1970s, when return migration took over, the 1980s have seen a renewal of the exodus. This time, however, the character of the flow has changed from predominantly low-skill construction and factory workers to embrace better-educated emigrants, including many graduates. This shift reflects Ireland's changing position in the international market for labour."     

个旧“花岗岩凹陷带”、“花岗岩凹陷带构造”的提法是概念性错误

编者的话:这封来信对本刊2007年第三期刊载的一篇稿件中某些专业术语的使用提出了自己的看法,同时也提醒广大地质工作者要重视专业术语使用要注意准确性和规范化.本刊欢迎读者、作者就一些专业领域的学术问题展开交流或争呜,以活跃学界的学术气氛、促进地质科学的不断发展.     

贝加尔裂谷系及邻区断裂现今活动变化及成因(英文)

已有的地质和地球物理方法无法对年、月、旬等现今时间尺度上的断层活动变化进行有效预测。运用基于地震活动定量指数运算程序的地理信息技术可以解决这个问题。这种方法被应用于贝加尔裂谷系(BRS)及邻区的研究当中。研究发现,断层活动变化发生在以几年为周期的时间尺度上,这无法用区域应力场的变化进行合理解释。沿着穿越贝加尔裂谷系的剖面编制了活动断层图以及地震活动定量指数曲线。提出的这种方法可以根据地震活动定量指数对活动断层进行仔细的分类,从而为解决地震中期预报相关问题开辟了重要途径。这种方法还被用来研究断层现今活动的时空变化和形成机制。研究发现,在实时尺度上断层活动具有高频发生的特征,这种现象可能是由于脆性岩石圈板内和块体内部运动产生的慢变形波的干扰导致的。利用变形波的通过速度可以对活动断层进行分组,各组具有不同的地质和地球物理特征参数,同时还可以对变形波波前的方向以及某一区域内主要断层在实时间隔内(地质上的瞬间)的活动情况进行预测。     

西天山喇嘛苏成矿斑岩年代学、地球化学特征与成因初探

近东西走向的天山造山带位于中亚造山带或阿尔泰构造拼贴体的最南端,是哈萨克斯坦和塔里木板块的汇聚地带,也是一个重要的铜一金等多金属成矿带[1].天山造山带是在古生代由塔里木和西伯利亚板块之间的古亚洲洋的消减闭合,塔里木、准噶尔、哈萨克斯坦等板块的俯冲-碰撞-增生所形成[2].     

磷处理粉煤灰可作农业土壤磷源

粉煤灰(简称CCP或ash)具有改良土壤,增加植物产量的功能。此外,由于它特殊的多孔结构,也可用作吸纳并承载植物养分的载体。用NaH2PO4配制成含磷0.10mol/L浓度的溶液,对采自加拿大西安大略省Sarnia地区Lambton电厂的底灰(bottomash)进行振荡浸渍处理。结果表明,振荡浸渍66h后的粉煤灰中磷含量可达784×10-6。以磷处理粉煤灰、未进行磷处理的粉煤灰和石英砂按比例混合,作为基本生长介质进行玉米种植实验,其中实验配方设计为生长介质中含磷量分别为标准含磷浓度(50×10-6)的10%、25%、50%、75%和100%。生长26、34和46d后分别与不含磷的空白配方、施加含氮-磷-钾为0-20-0标准磷肥并控制磷含量为标准浓度(50×10-6)配方进行生物产量对比。生长实验结果表明,以磷处理粉煤灰供磷的生长介质,当含磷量为标准浓度的25%至100%时,其植物生长量就比添加标准浓度磷肥的配方好。种植46d后的生物生长量统计结果显示,含磷分别为标准浓度50%、75%和100%的实验介质中,玉米杆的鲜重较施标准磷肥介质中玉米分别增长39.46%、42.73%和46.13%;玉米杆干重依次增加29.71%、13.39%和28.87%;根鲜重平均增加16.62%;根干重平均增加14.03%。上述实验结果启示,粉煤灰可以很好地吸纳承载磷养分,并持续供给植物吸收生长,如果采用吸纳磷(或其他养分)的粉煤灰改良砂质土壤将有重要意义。