Surface drag and turbulence over an inhomogeneous land surface

Data collected over an inhomogeneous semi-rural area are presented. The data are compared with previous surface-layer data to determine how representative the fixed-point flux measurements are of area averages. Departures from the standard surface-layer results are found to be relatively small (~10–20%), which supports the concept of a blending height above which the flow ceases to respond to variations in the underlying surface and becomes horizontally homogeneous.Effective roughness lengths are derived for different wind directions and the relationship between the effective roughness length and upwind surface is examined in the light of recent ideas on averaging surface roughness lengths. It is found that by averaging drag coefficients, realistic values of the effective roughness length can be calculated which are not very sensitive to the precise choice of the component roughness lengths.     

Diffuse radiation,twilight, and photochemistry — I

A photochemical scheme which includes a detailed treatment of multiple scattering up to solar zenith angles of 96° (developed for use in a GCM) has been used to study partitioning within chemical families. Attention is drawn to the different zenith angle dependence of diffuse radiation for the two spectral regions <310 nm and >310 nm. The effect that this has on the so-called 40 km ozone problem is discussed. The importance of correctly including multiple scattering for polar ozone studies is emphasised.     

Subaqueous pyroclastic flows and ignimbrites: an assessment

An assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary, hot gas-rich pyroclastic flows, mass-flows which resulted from the transformation of gassupported flows into water-supported ones, and secondary mass-flows carrying redeposited pyroclastic debris. Based on subaerial pyroclastic flows, the term pyroclastic flow should be restricted to demonstrably hot, gas-rich mass-flows of pyroclastic debris. Using this definition, very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described. In the majority of these cases, the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate. The only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the Ordovician nearshore, shallow marine ignimbrites of Ireland and Wales, and Miocene ignimbrites of southwest Japan, resulting from the passage of subaerially erupted pyroclastic flows into shallow water. Other possible examples are near-vent dense clast deposits in the Donzurobo Formation of Japan, possible submarine intra-caldera ponded ignimbrite successions in California and Wales, and near-vent pumiceous deposits of Ramsay Island, Wales. All other purported cases are either clearly the result of water-supported mass-flow transportation and deposition (debris avalanches, debris flows, turbidity currents), or lack adequate supporting evidence regarding the heat state or the palaeoenvironment. Only the shallow marine ignimbrites of Ireland and Wales show adequate evidence of welding, but even these could have been nearly wholly exposed above sea-level when welding occurred. We conclude that when pyroclastic flows enter water they are generally disrupted explosively and/or ingest water and transform into water-supported mass-flows, and we suggest the various scenarios in which this occurs. There is no evidence to suggest that welding in wholly subaqueous environments is common.     

Predicting ground-motion variations at the Turkey-flat test site,California

Results of a single group participating in an international experiment are analyzed. The experiment served to verify computational predictions of the ground-motion variations due to near-surface geological effects at a site established for that purpose by the California Department of Conservation. Based on an acceleration record at a rock location, and geotechnical model of medium, records at the other locations of a nearby sedimentary deposit were predicted. A 2-D finite-difference sensitivity analysis suggested that the lateral wave-propagation effects are negligibly small, and locally 1-D computations are sufficient for the present site. Those computations are compared with observations not available to the authors during the blind prediction. Peak accelerations, peak velocities and RMS accelerations were predicted with errors less than 159%, 114% and 62%, respectively. Maxima of the response spectra were fitted within a factor of 2. The predicted and observed Husid's plots (i.e., the normalized cumulative plots of the acceleration squared) have the correlation coefficients 0.98. The detected misfits do not show any simple relation to the instrument location, component, frequency, or time.     

Magma sources for Mesozoic anorogenic granites of the White Mountain magma series,New England,USA

The magma sources for granitic intrusions related to the Mesozoic White Mountain magma series in northern New England, USA, are addressed relying principally upon Nd isotopes. Many of these anorogenic complexes lack significant volumes of exposed mafic lithologies and have been suspected of representing crustal melts. Sm–Nd and Rb–Sr isotope systematics are used to evaluate magma sources for 18 felsic plutons with ages ranging from about 120 to 230 Ma. The possibility of crustal sources is further examined with analyses of representative older crust including Paleozoic granitoids which serve as probes of the lower crust in the region. Multiple samples from two representative intrusions are used to address intrapluton initial isotopic heterogeneities and document significant yet restricted variations (<1 in _Nd). Overall, Mesozoic granite plutons range in _Nd [T] from +4.2 to -2.3, with most +2 to 0, and in initial ⁸⁷Sr/⁸⁶Sr from 0.7031 to 0.709. The isotopic variations are roughly inversely correlated but are not obviously related to geologic, geographic, or age differences. Older igneous and metamorphic crust of the region has much lower Nd isotope ratios with the most radiogenic Paleozoic granitoid at _Nd [180 Ma] of -2.8. These data suggest mid-Proterozoic separation of the crust in central northern New England. Moreover, the bulk of the Mesozoic granites cannot be explained as crustal melts but must have large mantle components. The ranges of Nd and Sr isotopes are attributed to incorporation of crust by magmas derived from midly depleted mantle sources. Crustal input may reflect either magma mixing of crustal and mantle melts or crustal assimilation which is the favored interpretation. The results indicate production of anorogenic granites from mantle-derived mafic magmas.     

Na-rich carbonate inclusions in perovskite and calzirtite from the Guli intrusive Ca-carbonatite,polar Siberia

Carbonate phases, some rich in Na₂O and comparatively rich in SrO and BaO, occur as inclusions in perovskite and calzirtite (Ca₂Zr₅Ti₂O₁₆) in the carbonatite of the Guli complex, Siberia. This is the first record of alkali carbonates, akin to nyerereite [Na₂Ca(CO₃)₂], in plutonic igneous rocks. The inclusion populations suggest that the parental magma of the complex was Ca-rich but developed Na-rich differentiates during the latest stages. This points to the dominant calcic carbonatites of the complex not being derivatives of alkali-rich parental carbonatites. These alkali-rich carbonate inclusions (and rare inclusions of djerfisherite) have been preserved due to the resistance of perovskite and calzirtite to processes of leaching, hydrothermal alteration and weathering.     

Geochemical specialization of the tin-bearing granitoid massifs of NW Bohemia

The geochemistry of Hercynian tin-bearing granitoid massifs of the Krune hory Mts. (Erzgebirge), Slavkovský les Forest (Kaiserwald) and Smriny (eastern Fichtelgebirge) is compared by statistical processing of 270 analyses including a wide spectrum of major and trace elements. Seven different types of granites are distinguished. Out of these, five types represent the successive differentiation of the largest massif of NW Bohemia: the Karlovy Vary (Karlsbad) massif. This comprises strongly differentiated peraluminous granites evolving towards extreme Li-Rb-Cs-F-and Sn-enrichment in the youngest members, which are albite-topaz-zinwaldite lithium granites. The sixth and seventh types are different from the former by their location in the eastern Krune hory and tectonic setting, and they display geochemical features of anorogenic granites: they are metaluminous albite-zinwaldite granites with marked enrichment of Nb, Y, and HREE in addition to Li, Rb, Cs, F and Sn, indicating contamination by sub-crustal material. Sn-W mineralizations, including flat peri-contact greisen bodies, steep greisen veins and tourmalinized phyllites, are all intimately associated with the most strongly differentiated granites — the Li-granite and the Cinovec-granite respectively.     

Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Littoral '92

Reports

Littoral '92