微量磷的萃取新光度法

本文研究了在0.5—0.65N硫酸介质中,以氟化钾为掩蔽剂,抗坏血酸～盐酸羟胺为还原剂,用锑盐在室温催化磷显色,使磷锑钼三元配合物与阳离子表面活性剂形成多元离子缔合物,该离子缔合物在正丁醇—醋酸丁酯混合有机溶剂中经萃取后产生“析相”,此兰色胶团,经增溶后,其灵敏度大大提高,表观摩尔吸收系数为2.55×10~5l·mol·cm~(-1)。配合物组成比为P:Sb:Mo:CTMAB=1:2:12:2。稳定时间达1O小时以上。应用在天然水、地下水及一些废水中微量磷的测定中结果满意。     

量化地图图形符号动态化的展示

 图形符号是地图的语言,在量化地图中,图形符号侧重于表示地理事物的数量特征,以揭示事物的量变过程与发展规律。图形符号的设计除注重内容的表达之外,还应强化形式的表达。图形符号动态化就是从符号的表现形式上来增强地图的趣味性和可视性。本文从视角感受的角度,阐述了图形符号动态化的含义及其在量化地图中的表现形式,以丰富地图的展示方法,提高量化地图的展现力     

南大港湿地旅游信息系统的功能模块与应用

南大港湿地旅游信息系统 (简称 NWTIS)是适应南大港湿地生态旅游需要而精心设计与开发的。系统采用 Visual Basic的语言编辑及可视化数据库管理和 Map Info的图元输出功能进行系统集成 ,开发了基于 Windows风格的 NWTIS,实现了大量属性和空间数据的查询、分析和图文显示。     

世界10大“半岛”集景

说到“半岛”为三面被海洋,湖泊或河流所包围仅一面与陆地相连者。全球有半岛22个,最大的要算阿拉伯半岛面积为322万平方千米;最小的如约克半岛苏厄德半岛只有几万平方千米,现摘录如下趣闻。     

Research and application of mineral resources assessment by weights of evidence model based on SIG

Geological data are usually of the characteristics of multi-source, large amount and multi-scale. The construction of Spatial Information Grid overcomes the shortages of personal computers when dealing with geological data. The authors introduce the definition, architecture and flow of mineral resources assessment by weights of evidence model based on Spatial Information Grid （SIG）. Meanwhile, a case study on the prediction of copper mineral occurrence in the Middle-Lower Yangtze metallogenic belt is given. The results show that mineral resources assessement based on SIG is an effective new method which provides a way of sharing and integrating distributed geospatial information and improves the efficiency greatly.     

准噶尔盆地西北缘沸石发育特征及成储机理初探：以玛南地区二叠系乌尔禾组为例

沸石类胶结物是准噶尔盆地西北缘玛南地区二叠系乌尔禾组发育的一种特殊胶结物类型。通过岩心观察、薄片鉴定、扫描电镜分析与岩石组分统计,明确了玛南地区乌尔禾组沸石胶结物的矿物特征、空间分布、成因机理与成储机制。研究区乌尔禾组主要发育浊沸石与片沸石,其中片沸石分为两期,早期富铁,晚期贫铁。研究区沸石胶结物的空间分布规律并不明显,仅在垂向上,从乌尔禾组到百口泉组,浊沸石与片沸石含量具有逐渐降低的趋势。沸石类胶结物的形成主要受控于母岩中凝灰岩砾石组分,中酸性火山岩砾石不利于浊沸石的形成,其他火山岩砾石与沸石的形成无明显关系,浊沸石大量发育的次生溶蚀孔隙是研究区油气赋存的主要储集空间类型。沸石类胶结物的沉淀与溶蚀可以简化为两阶段成岩作用过程,早期正常成岩胶结形成各类沸石胶结物,晚期深部成岩流体上涌,对储层进行溶蚀与改造,深部流体改造是成储的关键阶段。     

Effects of Coal Rank and High Organic Sulfur on the Structure and Optical Properties of Coal-based Graphene Quantum Dots

Coal‐based graphene quantum dots (GQDs) were successfully produced via a one‐step chemical synthesis from six different coal ranks, from which two superhigh organic sulfur (SHOS) coals were selected as natural S‐doped carbon sources for the preparation of S‐doped GQDs. The effects of coal properties on coal‐based GQDs were analyzed by means of high‐resolution transmission electron microscopy (HRTEM), X‐ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X‐ray photoelectron spectroscopy (XPS), ultraviolet‐visible (UV‐Vis) absorption spectroscopy, and fluorescence emission spectra. It was shown that all coal samples can be used to prepare GQDs, which emit blue‐green and blue fluorescence under ultraviolet light. Anthracite‐based GQDs have a hexagonal crystal structure without defects, the largest size, and densely arranged carbon rings in their lamellae; the high‐rank bituminous coal‐based GQDs are relatively reduced in size, with their hexagonal crystal structure being only faintly visible; the low‐rank bituminous coal‐based GQDs are the smallest, with sparse lattice fringes and visible internal defects. As the metamorphism of raw coals increases, the yield decreases and the fluorescence quantum yield (QY) initially increases and then decreases. Additionally, the surface of GQDs that were prepared using high‐rank SHOS coal (high‐rank bituminous coal) preserves rich sulfur content even after strong oxidation, which effectively adjusts the bandgap and improves the fluorescence QY. Thus, high‐rank bituminous coal with SHOS content can be used as a natural S‐doped carbon source to prepare S‐doped GQDs, extending the clean utilization of low‐grade coal.     

西藏甲玛斑岩-矽卡岩型铜多金属矿床原位Pb同位素组成研究

西藏甲玛斑岩-矽卡岩型铜多金属矿床的成矿期次可划分为成矿前斯和矽卡岩成矿期(铜钼阶段、铜铋阶段、铁铜阶段和铜铅锌阶段)。应用飞秒激光剥蚀多接收等离子体质谱(fsLA-MC-ICP-MS)对甲玛矿床主要矿石中的硫化物和斑岩中的长石斑晶进行原位微区Pb同位素组成分析,测定结果与前人运用化学溶样法获得的Pb同位素组成基本一致,表明原位Pb同位素分析技术具有很高的可靠性,不同成矿阶段的硫化物的Pb同位素组成总体一致表明成矿物质来自同一岩浆源区。斜长石和钾长石的Pb同位素组成对比研究显示,花岗斑岩与甲玛矿床的形成有直接成因联系,而花岗闪长斑岩很可能与成矿作用无关。通过对甲玛成矿物质来源的研究表明,有较多幔源物质加入的新生加厚下地壳部分熔融形成的岩浆为甲玛超大型矿床的形成提供了充足的Cu、Au等成矿物质。     

ArcGIS在莲花县地籍区地籍子区划分中的应用

ArcGIS是土地调查数据库建设中常用的软件之一,研究和探讨利用该软件在土地调查、数据库建设中数据(属性)获取和组成及建库流程等相关技术,对同类项目的实施具有一定的指导意义。阐述了ArcGIS制作地籍区地籍子区划分原则、步骤、拓扑检查、地籍区地籍子区编码规则及其属性录入。