本研究以南海东北部MD18-3569孔(22°09.30'N,119°49.24'E;水深1320m)上部10.09m的沉积物为研究材料,利用浮游有孔虫Globigerinoides ruber壳体的氧同位素(δ18Oc)、Mg/Ca比值计算了表层海水剩余氧同位素(δ18Oresidual),重建了过去两万年以来(19.88~0.78 ka B.P.,时间分辨率约152a)的表层海水盐度演变历史,结合南海其他站位降水重建记录,分析了研究区的水文气候变化特征。研究表明:1)南海南部和北部δ18Oresidual记录的长期趋势呈反相变化关系,即南海北部δ18Oresidual在末次冰消期逐渐偏负、全新世以来逐渐偏正,指示海表盐度先减小后增大,而南海南部δ18Oresidual则呈现先偏正、后偏负的变化特征。这种南、北反相变化关系表明末次冰消期过程中,随着北半球夏季辐射量逐渐增加,热带海洋上方的大气对流活动增强,包括南海南部在内的暖池区水汽蒸发及相关δ18O分馏增强,同时东亚夏季风增强、把更多蒸发水汽传输至东亚大陆,途中在南海北部产生更多δ18O偏轻的季风降水,导致研究区海表盐度降低、δ18Oresidual逐渐偏负。2)在千年尺度上,全新世东亚夏季风于1.4 ka B.P.、2.7 ka B.P.、4.4 ka B.P.、6.2 ka B.P.、7.2 ka B.P.和8.9 ka B.P.共出现6次降水减少事件,平均间隔约1500年,与中国东部石笋δ18O记录的全新世千年尺度事件一致,可能受太阳辐照度变化影响。因此,末次冰盛期以来,研究区的δ18Oresidual主要受夏季风降水影响。
Pulleniatina obliquiloculata shells from 16 core-top samples from the tropical Indo-Pacific Oceans are analyzed for the ratios of boron and cadmium to calcium(B/Ca and Cd/Ca). The B/Ca ratios show a very weak positive relationship with [B(OH)_4~-] and the dissolved carbonate species at the apparent calcification depth of P.obliquiloculata. The boron partition coefficients(K_D) between P. obliquiloculata B/Ca and seawater[B(OH)_4~-]/[HCO_3~-] distribute around 1.1×10~(-3)-1.3×10~(-3) with a mean value of(1.19±0.12)×10~(-3),and are significantly related to the nutrient concentration, especially phosphate. The lack of any clear correlation between the P. obliquiloculata B/Ca and seawater carbonate chemical parameters suggests that the physiochemical controls on boron incorporation are masked by the complexity of natural seawater condition. But the significant dependence of Ku on nutrient may likely be explained by a nutrient related growth-rate effect. Cd/Ca of P.obliquiloculata shows significant correlation with seawater phosphate concentration, and its partition coefficients(D_(cd)) are significantly related to temperature. A first-principle methodology of P. obliquiloculata B/Ca is applied;with the aid of Cd/Ca as a phosphate proxy and a constraint on K_D, to estimating sea water carbonate chemistry(e.g., pH). The results are fairly promising and allow us to propose the possibility to apply the combination of B/Ca and Cd/Ca proxies(and also Mg/Ca and δ~(18)O for estimating temperature and salinity) for the paleoreconstruction of seawater carbonate chemistry. 相似文献