钛同位素标准溶液研制

钛同位素组成可用于地球化学和宇宙化学研究中,但目前国内外缺乏钛同位素标准物质.为了满足地质样品钛同位素分析的需要,本文研制了钛同位素标准溶液,报道了钛同位素标准溶液的研制过程和定值结果,包括标准溶液的选择、均匀性和稳定性检验、定值分析及测定数据的统计性检验等.通过初步测定,确定美国Alfa公司生产的Ti单元素溶液作为备选Ti同位素标准溶液.将备选标准溶液分装成150瓶,随机抽取15瓶进行均匀性检验,测试结果的F值均小于临界值,表明备选标准溶液的Ti同位素组成均匀.通过30个月的稳定性检验,标准溶液的特征量值变化在不确定度范围内.采用独家和多家实验室相结合的方法进行定值,标准溶液的特征量值及不确定度推荐为:δ50Ti=-2.23‰±0.14‰,δ49Ti=-1.67‰±0.09‰,δ48Ti=-1.13‰±0.06‰,δ47Ti=-0.57‰±0.05‰.研制的标准溶液可用于钛同位素分析时校正仪器和验证质谱分析过程,有利于不同实验室的测试数据之间的对比和应用.     

Geochronology and geochemistry of the Heihe mafic pillow lavas in the Qinling Mountains, China

The Qinling Mountains in central China are the joint orogenic zone between the Sino-Korean (or North China) and the Yangtze craton blocks. The age and genesis of the Danfeng mafic volcanics in the north of the Shangzhou-Danfeng fault zone, i.e. the main suture zone in the Qinling orogenic belt, have been controverted for a long time because their age is closely related to the converged time of two blocks. The ages and the geochemical data of the Heihe pillow lavas for the Danfeng mafic volcanics in the Heihe River area in the Qinling orogen are reported in this paper. The obtained isochron age by the Sm-Nd isotopic data of the 13 whole-rock samples for the mafic pillow lavas is 963±130 (2σ) Ma, corresponding to I_Nd = 0.51173±16 (2σ),ɛ _Nd(T)= +6.6, MSWD0.57. However, the Rb-Sr isotopic analytical results for the same samples as the Sm-Nd whole-rock ones are disperse. For the Sm-Nd isotopic systems were interfered during the later geological functions, the Sm-Nd isochron age for the whole-rock sample (Q9511WR) and the mineral phenocrystal samples: amphiboles (Hb) and plagioclases (Plag) presents the better uncertainty, whereas isochron ages of 930 Ma and 437 Ma are given if the WR-Plag and WR-Hb are calculated respectively, and their Rb-Sr isochron age is 268±47(2σ) Ma, I_sr = 0.70475±11 (2σ), MSWD0.96. The major and trace elements for the lavas show that they were formed in the quasi-N-MORB setting.     

安徽铜陵新桥铜金矿床黄铁矿Rb／Sr同位素年龄数据——燕山晚期成矿作用的证据

本文采用亚样品取样和Rb/Sr同位素方法对安徽铜陵新桥铜-硫铁-金矿床层状矿体矿石矿物--黄铁矿直接进行Rb-Sr等时线法测定,获得了112.6±7.8Ma的Rb-Sr等时线年龄,它代表了主成矿期成矿作用的时代.结合已有地质资料认为燕山晚期成矿作用在新桥铜-硫铁-金矿床的形成中居重要作用.     

勉县—略阳蛇绿混杂岩带镁铁质—安山质火山岩块年龄和该带构造演化的复杂性

位于南秦岭略阳—勉县—镇巴高川一线的勉略蛇绿混杂岩带一般认为形成于印支期,但笔者研究表明,除存在印支期的岩块外,也存在大量晋宁期的变质镁铁质火山岩块和岛弧火山岩块:1略阳三岔具岛弧火山岩性质的变质安山质火山岩的Sm-Nd等时年龄为873±71(2σ)Ma,INd=0.511796±67(2σ),MSWD0.73;2勉县安子山类似N-MORB洋壳碎片的变质镁铁质火山岩块的Sm-Nd等时年龄为877±78(2σ)Ma,INd=0.51190±10(2σ),MSWD0.93;3出露于略阳庄科轻稀土强烈亏损蛇绿岩块,虽然其Nd同位素组成分散,不形成等时线,但是其高场强大离子不相容微量元素与勉县安子山变质镁铁质火山岩具有十分类似地球化学特征,它们可能是大致同时,由类似源区形成的。这些事实表明,勉略蛇绿构造混杂岩带是复杂的,可能是多期构造事件叠加复合构造活动带。