安庆夕卡岩型铁铜矿成矿流体特征

通过对安庆夕卡岩型铁铜矿床中各成矿阶段的夕卡岩矿物、石英和方解石中流体包裹体的岩相学、显微测温及显微激光喇曼光谱成分分析等研究,认为矿床早期成矿流体可能为深部岩浆熔-流作用形成的岩浆热液,具高温高盐度和富CH4等还原性挥发分的特征;在燕山期复杂构造活动影响下,成矿流体在温度为220℃左右,压力为75 MPa左右的条件下发生减压沸腾去气作用,CH4等气体大量逃逸,由于大气降水的不断混入,最终演化为低温、低盐度的混和流体.     

闽西晚中生代基性岩脉稀土元素地球化学特征

幔源基性脉岩是源于地幔的基性岩浆充填先存破裂或区域性节理形成的,为岩石圈伸展和地壳拉张的产物,对研究深部地幔性质和大陆动力学演化具有重要的指示意义[1～4].研究区位于政和-大浦断裂带的西部,断裂带以西地区主要为早、中侏罗世的壳源型S花岗岩类,晚侏罗世以来的岩浆活动比较弱,岩浆侵入和火山活动有局限性.因此,闽西基性脉岩的研究对探讨内陆地区岩浆活动规律和构造演化有重要的意义.本文以闽西基性脉岩(半村辉绿岩脉、拔里角闪辉长岩脉、曹坊辉绿岩脉)为研究对象,利用稀土元素对基性脉岩的形成机制做了初步的讨论.     

Geochemistry of sedimentary rocks and its relation to crustal evolution and mineralization in Southwest Yangtze Massif, China

Through a systematic study on trace elements and REE geochemistry of mudstone deposited in the basin and lower slope environments during Upper Proterozoic to Triassic in the Southwest Yangtze Mssif,three geochemical abnormal horizons of which the geochemical characteristics are quite different from those of other horizons have been established for the first time.They are the Lower Cambrian,the Upper Devonian and the Upper Permian,As compared with the crustal evolution in this area.these three geochemical abnormal horizons are corresponding to the pulling-apart periods of geotectonic cycles.which illustrates that uncommon depositional sources puring into the basin from the earth‘s interior may be one of the most important causes to originate the geochemical anomalies in these lhrizons.Thus it can be realized that the geochemistry of post-Archean sedimentary rocks has a great deal to do with the crustal evolution and it can be used as a tracer to analyze the crustal evolution.The elements in this area are mainly concentrated in these geochemical abnormal horizons,and the degree of enrichment and deficiency of trace elements in other horizons is very limited.A series of research on mineralization indicates that the main strata-bound ore deposits discovered in the Southwest Yangtze Massif occur in the Cambrian,Devonian and Permian-Trassic strata.The results of isotope tracer resarch have also proved that most of the metallogenic elements in these ore deposits came from the host strata.which illustrates that the geochemical abnormal horizons may have made great contributions to these ore-forming processes.Thus it can be concluded that it is only the particular horizons corresponding to the particular periode of earth‘s evolution that can they be the significant source beds because only in these uncommon horizons there can be highly enriched metallogeinc elements.which may be one of the most important reasons for explaining the time-bound nature of mineralization.     

含金硫化物矿床的表生富集型金矿

虎圩金矿位于湿热多雨的江西省东部，赋存在东乡火山岩盆地北部，江南地体与赣中地体的拼接带上，因此，矿区断裂构造发育，岩浆活动频繁。金矿化产于燕山中期侵入的花岗闪长玢岩的内外接触带上。矿化以充填交代张性断裂构造带的脉状形式产出。矿体为不规则脉状和透镜状，具明显的垂直分带现象。上部为氧化矿石、具黑色土状、蜂窝状构造，Ａｕ含量达工业品位以上，形成金矿体、此外，氧化矿石还富Ｃｏ，相对贫Ｃｕ、Ｚｎ、Ａｇ和Ｐｂ     

白云鄂博独居石SHRIMP定年的思考

对主矿条带状矿石、主矿下盘白云岩和接触带白云岩中的3个独居石精矿进行了SHRIMP定年。结果表明矿区存在着无古宙和古生代两期成矿作用。推断对两期成矿等强度样品的分析，可望获得两条非谐和线（回归混合线）和两个下交点年龄。     

拉尔玛硒-金矿床元素有机／无机结合态及硒的赋存状态研究

以金属矿床中有机质的重要组成部分———干酪根为研究对象 ,对干酪根中的Se及其他微量元素进行了分离测定 ,对矿床中元素的有机 /无机结合态进行了定量研究 .认为矿床中Se主要以有机结合态方式存在 ,根据生物化学证据 ,不同成矿演化阶段Se的有机结合态比率以及理论计算和红外光谱分析 ,推断Se可能与有机质中的某些元素键合 ,较为牢固地吸附在有机质中 ,并可能形成Se的有机矿物 .同时 ,也给出了无机结合态硒的可能形式     

镉同位素在古环境重建中的应用:以晚泥盆世弗拉期-法门期生物灭绝事件为例北大核心CSCD

磷(P)是海洋初级生物不可或缺的营养元素,现代海水中溶解态镉与磷的含量线性关系极好,表明镉可能作为海洋初级生物的营养元素而被利用。浮游生物优先摄取轻的镉同位素,使得海水中的镉同位素变化与海洋初级生产力的变化紧密相关。目前镉同位素已成功应用于二叠纪-三叠纪之交古海洋初级生产力的重建。广西桂林晚泥盆世弗拉期-法门期(Frasnian-Famennian,F-F)之交杨堤剖面的镉同位素数据显示,在F-F灭绝事件前,δ114Cd总体偏重(0.03‰~0.49‰),指示当时海洋具有较强的初级生产力;F-F之交,δ114Cd呈现负偏(-0.44‰^-0.01‰),表明这一时期海洋初级生产力显著下降;F-F灭绝事件后,δ114Cd又逐渐增大(-0.04‰~0.13‰),反映灭绝事件后海洋初级生产力的恢复。海洋初级生产力的下降,导致了海洋生态系统中的食物链受到破坏,从而引发了F-F之交的生物灭绝事件。     

Geochemistry of Late Mesozoic mafic dykes in western Fujian Province of China： Sr-Nd isotope and trace element constraints

The Bancun diabase dyke and the Bali hornblende gabbro dyke in western Fujian Province were emplaced in the Early and Late Cretaceous periods, respectively; the former is designated to calc-alkaline series and the latter to K-high-calc-alkaline rock series. Both the dykes are characterized by such geochemical characteristics as high Al and Na2O>K2O. As for the Bancun dyke, Al2O3=16.32%–17.54% and K2O/Na2O=0.65–0.77; as for the Bali dyke, Al2O3=16.89%–17.81% and K2O/Na2O=0.93–0.99. Both the Bancun and Bali mafic dykes are relatively enriched in LILE and LREE, but depleted in HSFE, displaying the geochemical characteristics of continental marginal arc, with high initial Sr isotopic ratios and low εNd (t) values. The (87Sr/86Sr)i ratios of the Bancun diabase dyke are within the range of 0.708556–0.70903 and their εNd (t) values vary between -6.8 and -6.3; those of the Bali hornblende dyke are within the range of 0.710726–0.710746 and their εNd (t) values are -4.7– -4.9, showing the characteristics of enriched mantle EM II. The isotope and trace element data showed that the mafic dykes have not experienced obvious crustal contamination, and metasomatism caused by subduction fluids is the main factor leading to LILE and LREE enrichments. The enriched mantle is the source region for the mafic dykes, and mixing of subduction fluid metasomatized enriched mantle and EM II-type mantle constituted the mantle source region of both the Bancun and Bali mafic dykes. Upwelling of the asthenosphere mantle provided sufficient heat energy for the generation of magmas. In accordance with the discrimination diagram of their tectonic settings as well as their trace element geochemical characteristics, it is considered that the dykes both at Bancun and Bali possess the characteristics of continental marginal arc, revealing the tectonic environment of formation of the mafic dykes, the continental dynamic background as an intraplate tensional belt in which the mafic dykes were emplaced. Meanwhile, it is also indicated that the tensional tectonic stress mechanism is responsible for the formation of the mafic dykes in western Fujian Province.     

桂北沙子江铀矿床稀土元素地球化学特征

针对沙子江矿床的区域地层、赋矿围岩、成矿各阶段方解石及铀矿石进行稀土元素地球化学研究发现:各类样品具大体类似的LREE富集及Eu负异常的稀土配分模式,表明它们之间稀土元素特征具有继承性,赋矿花岗岩与区域地层稀土元素特征指示两者具有共同的陆壳沉积物源区;方解石及矿石中稀土元素主要继承了赋矿花岗岩的特征。成矿各阶段方解石Y/Ho值范围狭窄,在28.86~38.22之间,显示它们具共同的源区,且从成矿早阶段经主成矿阶段到成矿晚阶段,Eu负异常趋于强烈,δEu均值由0.34→0.26→0.25,表明成矿流体向相对还原环境演化。铀矿石具最高的稀土元素总量(ΣREE=259.88×10-6~869.31×10-6),且与铀矿石的品位存在正相关关系,暗示稀土元素与铀的迁移具同步性。铀矿石(以原生铀矿物为主)中Ce负异常的形成可能与铀源岩中分散的U(Ⅳ)被活化为在成矿流体中易迁移的U(Ⅵ)的氧化过程相伴;而铀黑的Ce正异常则是由表生作用过程所导致。