Collisional excitation of interstellar cyclopropenylidene

Theoretical rotational excitation rates were computed for C3H2 in collisions with He atoms at temperatures from 30 to 120 K. The intermolecular forces were obtained from accurate self-consistent field and perturbation theory calculations, and collision dynamics were treated within the infinite-order sudden approximation. The accuracy of the latter was examined by comparing with the more exact coupled states approximation.     

Indians in England: why did they emigrate?

The period of highest migration from India to England was 1955-1975. In 1981, the Bradford metropolitan district had about 13,000 Indians. 46% were Punjabis and 43.3% were from Gujarat. Using a 10% sample of Indian households in the Bradford district in 1984 and secondary information, this study examines the impact of the following reasons on decision to migrate: 1) push factors in the area of origin, 2) the 1947 partition of India, 3) strong economic attraction of the destination, and 4) "cultural ethos" and "status competition" among the migrant communities in the areas of emigration. Findings show that 1) Punjab and Gujarat do not have high poverty levels nor very high population densities; 2) the partition of India did not influence migration decisions; 3) the economic well-being of returning migrants and the high conversion rate of English currency did attract migrants to England (39% of surveyed migrants emigrated to England for purely economic reasons); and 4) 60% of the Punjabis and over 50% of the Gujaratis state that local status competition had a significant influence on their decisions to migrate. Thus, the economic attraction of England and the status competition among local families and the community were the dominant factors in migration decision making.     

Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.     

A spatial perspective on the distribution of the Indians in the United Kingdom, 1981

The author analyzes the spatial distribution of Indians living in Great Britain in 1981. The impact of factors such as demand for labor, location of manufacturing industries, and the attraction of urban areas is examined.     

Determinants and characteristics of female migration: a case study of Salem City in Tamil Nadu,India

A random sample of 521 male and 481 female migrants surveyed in Salem city in Tamil Nadu, India, during 1980-1981 was analyzed on the basis of a classification related to reasons (association, marriage, distress, and voluntary) for migration. Women were found to outnumber males in associational migration, both in rural to urban and urban to urban streams. They also formed almost all the marriage migrants. They were more numerous in distress migration as well. There were, however, comparatively few women among voluntary migrants. The incidence of illiteracy among migrant women was generally high, except for voluntary migrants who had completed high school. The share of working women was not negligible, but in most cases present work status was achieved after migrating.     

贵州遵义牛蹄塘组黑色岩系的硒同位素变化及其环境指示初探

西南早寒武世牛蹄塘组是分布在中国南方扬子地台的一套黑色岩系,区域上发育有典型富集多金属元素的硫化物矿化层.选取遵义松林小竹牛蹄塘组下部富硒、钼、镍等元素的黑色岩系剖面,利用Se同位素初步探讨了该剖面岩石的沉积环境和硒的可能来源.结果表明,小竹牛蹄塘组下部剖面黑色岩系的δ82/76SeSRM3149比值变化较大,下部底层含碳斑脱岩与磷块岩的变化范围在-4.35‰～ 4.11‰之间;中间镍钼层及碳质页岩、碳质碳酸盐岩的δ82/76SeSRM3149变化范围窄,平均值为0.9‰±0.23‰(n=4);上层碳质页岩为-1.24‰.结合已发表的钼同位素数据,认为中间岩石沉积于缺氧/无氧环境,但存在盆地海水与热液或充氧水团的混合;下层的岩石曾一度位于充氧与贫氧环境的边界面,局部岩石曾暴露地表经历了较强的风化和蚀变作用,海水中硒有可能来自底部富硒斑脱岩的氧化淋滤或海底热液.据此推测遵义松林小竹牛蹄塘组下部岩石的沉积环境极可能处在局限盆地靠近陆地的边缘部分,经历了充氧→贫氧→缺氧/无氧→贫氧的演化阶段.     

铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

Total content and chemical speciation of arsenic in the polychaete Sabella spallanzanii

An unusual feature has been observed in polychaetes regarding their capacity to accumulate high levels of relatively toxic forms of arsenic in specific tissues. Basal levels of arsenic and distribution of its compounds were investigated in tissues of the Mediterranean polychaete Sabella spallanzanii. Particularly high concentrations were measured in the branchial crown (1036+/-136 microg/g d.w.) and chemical speciation revealed that the predominant form was the relatively toxic dimethylarsinate (DMA). These data suggest a potential role of As as anti-predatory strategy in polychaetes.     

长江入海沉积物的输送及其入海后的运移

前言 长江和黄河是世界著名的多沙河流，每年入海泥沙分别为5亿吨和11亿吨，分别占世界的第四位和第二位。千万年来由她们发育了广大的冲积平原，浩浩荡荡东流入海，形成东中国海大陆架沉积物的主要来源。研究长江和黄河沉积物搬运入海的沉积动力过程，不仅对东海大陆架的了解和开发有重要意义，也给陆上经济发展提供科学依据。     

Analysis of medaka cytochrome P450 3A homotropic and heterotropic cooperativity

We have previously demonstrated that medaka CYP3A is associated with metabolism of several endobiotics including steroids and bile acids. In this study, we demonstrate that medaka CYP3A catalysis exhibits unusual kinetic behaviors consistent with allosteric interaction which cannot be described by hyperbolic kinetic models. Using 7-benzyloxy-4-(trifluoromethyl)-coumarin (BFC) and nonylphenol as CYP3A substrates, we describe both homotropic and heterotropic cooperative interactions. Given the role of CYP3A in maintaining the homeostatic balance for numerous endobiotics, enzymatic activation/inhibition by endocrine disruptors (EDCs) represents a putative (non-genomic) mechanism for endocrine disruption.