钠辉石的出溶机理

对于具有限混溶或原子有序分布的简单二元固溶体来说,已结合其自由能曲线来预测一种体系的相关系和出溶机理。有序过程的特征影响着出溶机理的适用性.如果有序化作用是二步(较高)有序时,则整个过程以连续机理占优势,而所描述的一种“条件旋节分解”(“Conditional spinodal”)(Allen 和 Cahni 1976)只有对序与无序端员组分之间起着决定作用.对于一步有序来说,有序相仅能经成核与生长来沉淀无序相.用透射电子显微镜所观察到的绿辉石徼细结构包括出溶页片和反相晶畴,并且在所选择的样品中它们之间的关系已用于解释地质条件下起控制作用的出溶机理。绝大多数绿辉石几乎都经历了阳离子的有序过程,然后保持均一体,或通过旋节分解作用出溶一种无序辉石。连续出溶机理占优势已用来说明 C2/c→P2/n 转换可以是二步(较高)有序的.现已提供了一种硬玉——普通辉石的可能相图,它是以这种理论为基础的,即在低温下无序端员组分之间应该是有限混溶的,而中间成分(绿辉石)的阳离子是有序的,两者迭加在一条溶相线上。这就完全解释了观察到的许多微细结构,并与在含杂质硬玉和绿辉石之间、绿辉石和钠辉石之间存在宽阔二相区的岩相学证据相符合。加入锥辉石所产生的影响类似于增温效应,所以,也就能够预测硬玉——锥辉石——普通辉石的相关系。     

地中海盐沉积的成因——兼论邻近地区晚第三纪盐沉积

地中海海底盐沉积,不可能是整个海盆多次干化的结果,特别是沉积当时,盆地底部的地形条件如果类似现代地中海,干化成盐更属子虚之词。相反,大西洋的盐-水补给,使其含盐量不断提高,最终导致盐矿物的沉淀——这种假说看来不仅合理,也为当时地质上的时空特点所印证。一次异常的突发的成盐高潮,绝不能形成地中海地区众多的盐矿床。它们的形成,也许要和当时的地质环境联系起来;晚第三纪时,地中海周围广大地区遍布着陆缘海和内盆地(众所周知,这儿是大小型盐类矿床的潜在产地)。盐矿沉积,是和这些盆地沉积环境的普遍特点相适应的。     

Modeling of two-phase flow in membranes and porous media in microgravity as applied to plant irrigation in space

In traditional applications in soil physics it is convention to scale porous media properties, such as hydraulic conductivity, soil water diffusivity, and capillary head, with the gravitational acceleration. In addition, the Richards equation for water flux in partially saturated porous media also contains a gravity term. With the plans to develop plant habitats in space, such as in the International Space Station, it becomes necessary to evaluate these properties and this equation under conditions of microgravitational acceleration. This article develops models for microgravity steady state two-phase flow, as found in irrigation systems, that addresses critical design issues. Conventional dimensionless groups in two-phase mathematical models are scaled with gravity, which must be assigned a value of zero for microgravity modeling. The use of these conventional solutions in microgravity, therefore, is not possible. This article therefore introduces new dimensionless groups for two-phase models. The microgravity models introduced here determined that in addition to porous media properties, important design factors for microgravity systems include applied water potential and the ratio of inner to outer radii for cylindrical and spherical porous media systems.     

ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions

Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies.     

Sources of salinity in ground water from Jericho area, Jordan Valley

One of the major problems in the lower Jordan Valley is the increasing salinization (i.e., chloride content) of local ground water. The high levels of salinity limit the utilization of ground water for both domestic and agriculture applications. This joint collaborative study evaluates the sources and mechanisms for salinization in the Jericho area. We employ diagnostic geochemical fingerprinting methods to trace the potential sources of the salinity in (1) the deep confined subaquifer system (K2) of Lower Cenomanian age; (2) the upper subaquifer system (K1) of Upper Cenomanian and Turonian ages; and (3) the shallow aquifer system (Q) of Plio-Pleistocene ages. The chemical composition of the saline ground water from the two Cenomanian subaquifers (K1 and K2) point to a single saline source with Na/Cl approximately 0.5 and Br/Cl approximately 7 x 10(-3). This composition is similar to that of thermal hypersaline spring that are found along the western shore of the Dead Sea (e.g., En Gedi thermal spring). We suggest that the increasing salinity in both K1 and K2 subaquifers is derived from mixing with deep-seated brines that flow through the Rift fault system. The salinization rate depends on the discharge volume of the fresh meteoric water in the Cenomanian Aquifer. In contrast, the chemical composition of ground water from the Plio-Pleistocene Aquifer shows a wide range of Cl- (100-2000 mg/L), Na/Cl (0.4-1.0), Br/Cl (2-6 x 10(-3)), and SO4/Cl (0.01-0.4) ratios. These variations, together with the high SO4(2-), K+, and NO3- concentrations, suggest that the salinity in the shallow aquifer is derived from the combination of (1) upconing of deep brines as reflected by low Na/Cl and high Br/Cl ratios; (2) leaching of salts from the Lisan Formation within the Plio-Pleistocene Aquifer, as suggested by the high SO4(2-) concentrations; and (3) anthropogenic contamination of agriculture return flow and sewage effluents with distinctive high K+ (80 mg/L) and NO3- (80 mg/l) contents and low Br/Cl ratios (2 x 10(-3)). Our data demonstrates that the chemical composition of salinized ground water can be used to delineate the sources of salinity and hence to establish the conceptual model for explaining salinization processes.     

Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea

Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g⁻¹ and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g⁻¹, while fossil PAH concentrations ranged from 42 to 187 ng g⁻¹. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution.     

Marine risk assessment: linear alkylbenzenesulponates (LAS) in the North Sea

The fate of linear alkylbenzenesulponates (LAS) in estuaries and coastal areas of the North Sea has been characterized with simple environmental models. The predicted concentration range in the estuaries around the North Sea (0.9-9 microg LAS l(-1)) was validated by monitoring data (1-9 microg LAS l(-1)). In offshore sites of the North Sea, it is estimated--and experimentally verified for a few sites--that the LAS concentration is below analytical detection limit (i.e., 0.5 microg LAS l(-1)). The effects of LAS on marine organisms have been reviewed. For short-term acute tests, there was no significant difference (p = 0.83) between the mean LC50 values of freshwater and marine organisms (mainly pelagic species tested, 4.1 and 4.3 mg LAS l(-1), respectively). For longer-term chronic tests, it appeared that the sensitivity (mean no-observed effect concentration (NOEC) value) of marine and freshwater organisms (0.3 and 2.3 mg LAS l(-1), respectively) was significantly different pt-test = 0.007). The predicted no-effect-concentrations (PNEC) were 360 and 31 microg LAS l(-1), for freshwater and marine pelagic communities, respectively. Given that the maximum expected estuarine and marine concentrations are 3 to > 30 times lower than the PNEC, the risk of LAS to pelagic organisms in these environments is judged to be low.     

The mean value concept in mono-linear regression of multi-variables and its application to trace studies in geosciences

The "mean value concept" in a mono-linear regression of multi-variables is clarified.Its applications to reconstruction of the past 90-year salinity of the sea surface water in Xisha Islands and to tracing the past 80 ka paleo-geomagnetic events from the Luochuan loess 10Be record are introduced in detail,which show the significance and the potential of the "mean value concept" in geoscience research.     

对重力势二阶垂直偏导数的一种新的取样方法

从目前的研究来看，二阶垂直导数（X和Y两个方向）的求解方法较简单，它采用的五个因子的数字滤波的最小二乘法来优化数据。但是在较小区域面积时（对工程和环境应用中的重力数据），重力异常很容易放大和被区域重力场掩盖，我们认为产生的缘由是表示重力场的x和y方向上的二次多项式引起的。因此，为了逼近重力水平方向的偏导可以设计一个好的滤波器来拟合在xy平面的重力场值，再得出想要的重力垂直方向偏导，文中最后对提出的方法在前人经典模型上和野外实践进行了验证。     

埃及东部沙漠南部埃尔贝达地区晚元古代岩中剪切带金的成矿作用

埃及东部沙漠地区由多种晚元古代岩石组成.它们以蛇绿岩、变辉长岩、变枕状玄武岩、岛弧变沉积岩与变火山岩组合体以及同构造期花岗岩等形式产出.蛇绿岩呈小规模、沿碳酸盐化剪切带逆冲于变火山岩之上的北北西向拉伸岩片.逆冲的岩石以发育滑石-碳酸盐、菱镁矿囊状体和石英-碳酸盐细脉为特征.埃尔贝达地区被另一条穿过变枕状玄武岩和变火山岩滑动的北西向逆冲断层所切割.石英脉与深成蚀变作用(即硅化和绿泥石化)广泛发育于逆冲构造面,构成了一条多样化的剪切带. 埃尔贝克金矿位于限定在蛇绿岩和变枕状玄武岩中的两条剪切带内(北西-南东向).金矿化主要与该区早期变形事件(D1)相伴.在晚元古代岩石板块消减期间,两期热液流体的注入影响着剪切带.在矿物方面,剪切带含有绿泥石、磁铁矿、赤铁矿、钛铁矿、黄铁矿、黄铜矿、针铁矿、褐铁矿、铜兰、斑铜矿和金.产于逆冲区蛇绿岩内的碳酸盐化剪切带(SiO2＜50%),金含量很低(0.24～0.45ppm),而变枕状玄武岩中的硅化剪切带富含SiO2(＞80%)且含金达45 ppm.观察到金以与石英连生的细颗粒金(约0.3 mm)、微细粒包裹体金(20～0.5 μm),或以与赤铁矿和孔雀石共生的细小不规则状斑点的形式产出.也发现从蚀变赤铁矿中活化形成的金呈微细粒、不规则状斑点(约10 μm).分析硅化剪切带内的石英脉和赤铁矿中的微粒金,含金量分别为92%和94%.