咸水层二氧化碳封存试验的水文和地球化学监测

水文和地球化学监测是典型试验场地特征描述和二氧化碳利流监测的主要组成部分。本次试验把二氧化碳注入德克萨斯州北部海湾地区河成三角洲Frio地层的含咸水砂层。注入的二氧化碳在原地形成超临界相,与周围咸水相比超临界相二氧化碳具有气体特征（低密度和粘度）,而一些二氧化碳溶解于咸水。典型试验通过1个注入井和1个监测井完成。在两个水井均开展了压力和流速监测;在监测井持续采集地表流体样品和定期采集井下液体样品。在二氧化碳注入之前开展的场地特征描述包括：在抽水试验的同时进行压力瞬变分析,来评估单相流动特征;确定注入井和监测井之间的水力连通性;确定对应的边界条件以及分析地层范围内的环境条件。此外,在注入二氧化碳前开展的示踪剂试验,有助于评估在单相条件下注入井和监测井之间的动态孔隙率和流径的几何形状。在注入二氧化碳前开展的地球化学采样,能为随后开展的地球化学监测提供基准,并有助于确定注入二氧化碳时使用的最佳示踪剂。在二氧化碳注入期间,开展水文监测来评估两相流动特征,并协助监测注入的二氧化碳羽流的运动;而通过地球化学采样能够提供二氧化碳和示踪剂到达监测井的直接证据。而且,含有二氧化碳的水能起到弱酸的作用,可与含水层内多种矿物发生反应,在监测井采集水样时可提供明显的化学信号。单相示踪剂试验和二氧化碳（以及与二氧化碳同时注入的示踪剂）的临界点曲线对比结果显示：超临界二氧化碳与固有咸水之间存在两相流动过程：为了有效地把二氧化碳封存于咸水含水层,必须充分了解二氧化碳封存场地当前存在的不确定性因素。     

Geology and rare-earth element geochemistry of highly evolved, molybdenite-bearing granitic plutons, Southeastern Desert, Egypt

The field relations, mineralogy, and major and trace elements (including REE analyses of whole-rock samples and minerals) of granites and their associated molybdenite uranium mineralized aplites in Southeastern Desert, Egypt, have been studied. The granites are leucocratic and mostly peraluminous in nature with muscovite increasing at the expense of biotite. The chemical and mineralogical characteristics of the granitic rocks indicate that their melts originated from the LILE-enriched mantle wedge by partial melting and are contaminated by crustal melts, followed by thermogravitational processes. Leucogranites with higher Na2O/K2O ratios from Um Dargag and Um Maiat crystallized under H2O-saturated equilibrium conditions in which the exsolved vapor continuously migrated away. The REE patterns of the granites studied are characterized by LREE enrichments and negative Eu anomalies. In comparison, the potassic aplites and the more sodic leucogranites are depleted in LREE, enriched in HREE and show more remarkable negative Eu anomalies. Allanite and monazite are the most important REE carriers in the granites. These minerals are strongly enriched in LREE, whereas fluorite and xenotime, which are more abundant in the aplites, are enriched in HREE. The average Lu/Ce ratio represents the fractionation trend with respect to HREE. It is 0.71 for radioactive fluorite, and it increases to 1.22 for non-radioactive fluorite. The high REE contents of molybdenite represent re-deposition of the mobilized Mo and REE. Due to the strong control of accessory minerals, the REEs are of limited use in petrogenetic modelling of highly evolved granitic systems.     

过去千年气候变化重建研究新进展

20世纪气候变暖的归因是当前全球共同关注的焦点之一,而解决这一问题的途径之一是对过去千年的气候变化历史进行精确重建。简要回顾过去千年气候重建的研究进展,重点关注古气候空间重建方法方面的最新进展,并将目前古气候空间重建方法划分为3类,即综合-比例法（Composite Plus Scale, CPS）、气候场重建法（Climate Field Reconstruction, CFR）以及状态空间模型（State-space Model）法,同时指出了这些方法的优缺点以及可能的解决途径。     

2011年3月日本福岛核电站核泄漏在海洋中的传输

使用全球版本的迈阿密等密度海洋环流模式对2011年3月日本福岛核电站泄漏在海洋中的传输以及扩散进行了数值模拟。数值模式中核废料(示踪物)排放情景采取等通量连续排放,排放时间从3月25日开始,分别持续20 d以及1 a,两种情形分别积分20 a。为了减少海洋环流年际变化带来的数值模拟的的不确定性,20 a的模式积分分别用2010年、1991-2011年、1971-1991年以及1951-1971年4个不同时段的NCEP/NCAR逐日再分析资料作为大气强迫场,因此每种排放情形包含4个数值试验。模拟结果的分析表明,不同核废料排放情景及其在不同时段大气资料对海洋模式的驱动下,模拟的示踪物总体的传输扩散路径(包括表层以及次表层)、传输速率以及垂直扩展的范围没有显著的差异。集合平均数值模拟的结果显示:在两种排放情景下,日本福岛核泄漏在海洋的传输路径受北太平洋副热带涡旋洋流系统主导,其传输路径首先主要向东,到达东太平洋后,再向南向西扩散至西太平洋,可能在10~15 a左右影响到我国东部沿海海域,且海洋次表层的传输信号比表层信号早5 a左右。通过进一步分析模式积分过程中最大示踪物浓度随时间变化发现,在积分第20 a(2031年3月),海洋表层和次表层浓度的最高值分别只有模式积分第一年浓度的0.1%和1%。在积分的20 a里,排放的核废料主要滞留在北太平洋海域(超过86%±1.5%的核废料在积分结束时,滞留在北太平洋),而在积分的前10 a(2021年之前),几乎所有的核废料滞留在北太平洋;在核废料的垂直分布上,主要集中在海洋表层至600 m的深度,在积分的20 a时间里,没有核废料信号扩散至1 000 m以下的深度。数值模拟的结果也表明核废料浓度减弱的强度以及演变的时间特征主要受洋流系统的影响,与排放源的排放时间长短关系不大。值得指出的是,更加准确地评估一个真实的核泄漏事故对海洋环境所造成的可能影响,还需要考虑大气中的放射性物质的沉降以及海洋生态对核物质的响应。     

西北婆罗州深水区：活动褶皱冲断带中的烃类聚集

在西北婆罗州深水区，一个活动的海上褶皱冲断带内拥有大量已经证实的烃类聚集，相信继续的勘探活动还会发现相当可观的油气。在新近纪大规模褶皱冲断带中发现典型的圈闭几何形态是上盘背斜、前陆褶皱及隆起和逆断层下盘错动断开处。商业性钻井目标位于变形的中新统和上新统沉积地层中，其中充满的油气来自现今仍然活跃的含油气系统。此处主要面临的问题是避免钻探活动变形和近期隆起期间烃类已经排出的圈闭。构造变形阶段研究列出了控制圈闭形成史和烃类保存史的一些关键要素。本文目的是提供一个有关西北婆罗州深水区褶皱冲断带的总体看法，为今后这一地区的油气勘探介绍一些重要结果。     

Biogeochemical processes and nutrient cycling within an artificial reef off Southern Portugal

This study (2002/2004) examines the effect of artificial reef (AR) structures off the southern coast of Portugal on biogeochemical process and nutrient cycling. Organic and inorganic carbon, nitrogen, phosphorus and chlorophyll a were determined monthly in sediment cores and settled particles for a two-year period. Ammonium, nitrates, phosphates, silicates, total organic nitrogen and phosphorus, chlorophyll a and phaeopigments were also determined monthly in water samples within AR and control sites. Results of the two-year study showed that: (i) there was a significant exponential fit between organic carbon and chlorophyll a (r2=0.91; p<0.01) in reef sediment suggesting an increase of benthic productivity; (ii) organic carbon and nitrogen content in settled particles within AR environment was about four times higher two years after reef deployment; (iii) nutrients and chlorophyll a in the water column were higher at AR than control site. Two years after AR deployment, dissolved organic and inorganic compounds in near bottom water were 30-60% higher, emphasizing benthic remineralization processes at AR's organically rich sediment. Marked chemical changes in the ecosystem were observed during the two-year study period, reinforcing the importance of these structures for sandy coastal areas rehabilitation through trophic chain pull-out.     

Harmful algal blooms and eutrophication: ��strategies�� for nutrient uptake and growth outside the Redfield comfort zone

While many harmful algal blooms have been associated with increasing eutrophication, not all species respond similarly and the increasing challenge, especially for resource managers, is to determine which blooms are related to eutrophication and to understand why particular species proliferate under specific nutrient conditions. The overall goal of this brief review is to describe why nutrient loads are not changing in stoichiometric proportion to the "Redfield ratio", and why this has important consequences for algal growth. Many types of harmful algae appear to be able to thrive, and/or increase their production of toxins, when nutrient loads are not in proportion classically identified as Redfield ratios. Here we also describe some of the physiological mechanisms of different species to take up nutrients and to thrive under conditions of nutrient imbalance.     

Estimation of Hourly and Daily Global Solar Radiation at Clear Days Using an Approach Based on Modified Version of Gaussian Distribution

The performance of two models,Jam and Baig,based on the modified version of Gaussian distribution function in estimating the daily total of global solar radiation and its distribution through the hours of the day from sunrise to sunset al any clear day is evaluated with our own measured data in the period from June 1992 to May 1993 in Qena Egypt The results show a high relative deviation of calculated values from measured ones,especially for Jain model,in the most hours of the day,except for those near to local noon.This misfit behavior is quite obvious in the early morning and late afternoon A new approach has been proposed in this paper to estimate the daily and hourly global solar radiation This model performs with very high accuracy on the recorded data in our region.The validity of this approach was verified with new measurements in some clear days in June and August 1994.The resultant very low relative deviation of the calculated values of global solar radiation from the measured ones confirms the     

含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。     

Where do periodic variations in the discharge of a well become negligible?

A rule of thumb is presented to determine where variations in the discharge of a pumping well have a significant influence on the flow in an aquifer. The rule of thumb relates the period of the variation of the discharge to the distance from the well beyond which the transient effect on the flow in the aquifer is insignificant. For example, when an irrigation well pumps intermittently during the growing season, the rule may be applied to determine the distance from the well beyond which flow in the aquifer can be simulated with an average discharge during the growing season; the distance from the well beyond which flow can be simulated with a steady, yearly averaged discharge can also be computed.