Temperature paleogradient estimations in the central Bohemian basin

Summary The coalification data of 12 boreholes in the Central Bohemian Basin are used to evaluate the paleotemperature gradients for the Upper Carboniferous period of the basin's development. Two versions of the burial history considered are supposed to yield an upper and a lower estimate. According to the more probable lower version, the average values of the paleogradient suggest an increasing tendency from west to east in the interval of 45–53K/km. The current geothermal gradients vary in the range of 28–35K/km. By combining the present thermal conductivity and the paleogradients, we have tried to estimate the Upper Carboniferous heat flow. Its values range from 96mW/m ² to 117mW/m ² .The results obtained can be compared with the paleogradient estimates in the Saar-Nahe Basin (F. R. of Germany). This region, which is similar with respect to the time of origin and tectonic pattern to the Central Bohemian Basin, displays on the average a slightly higher Permo-Carboniferous geothermal gradient of 60K/km.     

Mass balance of mercury in the Mediterranean Sea

The Mediterranean Basin is rich in mercury from natural and anthropogenic sources. During an extensive research from 2002–2005, measurements of different mercury forms were carried out in the Mediterranean Sea by the Italian research vessel Urania as a part of the Med Oceanor and MERCYMS projects funded by the EU Framework programme. Further on, transport and fate of mercury forms was simulated in water and air compartments by two different models, and an approximate coupling of both models was performed. The new 3-dimensional model PCFLOW3D was completed with the first version of a biogeochemical module which deals with various mercury species in dissolved and particulate forms. Exchange with the bottom and the atmosphere, methylation, demethylation, reduction and oxidation were taken into account. Based on the integrated hydrodynamic-atmospheric model and results of field measurements the mass balance of total mercury in the Mediterranean Sea was determined in order to estimate main sources and sinks and simulate future trends of mercury contamination in the Mediterranean. The following terms were taken into account: sources of mercury from major rivers and from point sources, exchange with the Atlantic Ocean and the Black Sea, estimated natural sources from geotectonic active areas in the sea, exchange with bottom sediments, and evasion to and deposition from the atmosphere.     

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Abscherungserscheinungen in der Trias der Iberischen Ketten (Nordspanien)

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Coal taxes as supply-side climate policy: a rationale for major exporters?

The shift away from coal is at the heart of the global low-carbon transition. Can governments of coal-producing countries help facilitate this transition and benefit from it? This paper analyses the case for coal taxes as supply-side climate policy implemented by large coal exporting countries. Coal taxes can reduce global carbon dioxide emissions and benefit coal-rich countries through improved terms-of-trade and tax revenue. We employ a multi-period equilibrium model of the international steam coal market to study a tax on steam coal levied by Australia alone, by a coalition of major exporting countries, by all exporters, and by all producers. A unilateral export tax has little impact on global emissions and global coal prices as other countries compensate for reduced export volumes from the taxing country. By contrast, a tax jointly levied by a coalition of major coal exporters would significantly reduce global emissions from steam coal and leave them with a net sector level welfare gain, approximated by the sum of producer surplus, consumer surplus, and tax revenue. Production taxes consistently yield higher tax revenues and have greater effects on global coal consumption with smaller rates of carbon leakages. Questions remain whether coal taxes by major suppliers would be politically feasible, even if they could yield economic benefits.     

Modification of the degree-day formula for diurnal meltwater generation and refreezing

Theoretical and Applied Climatology - The standard degree-day, temperature-index approach to calculating snowmelt generation and refreezing (the SDD method) is convenient and popularly used but...     

Oxygen isotope ratios in fossil wood cellulose: Isotopic composition of Eocene- to Holocene-aged cellulose

We measured the δ¹⁸O of cellulose (δ¹⁸O_cel) extracted from fossil wood collected at 9 sites in the northern and southern hemispheres as a potential source of information about precipitation δ¹⁸O (δ¹⁸O_ppt) in the past and paleotemperatures. The samples had been buried in fluvial sediments for periods of time ranging from ca. 45 million to 250 years. At the oldest localities (high latitude, Eocene- through Pliocene-age sites in Canada and Russia), mean annual temperature (MAT) estimates derived from the modern relationship between MAT and δ¹⁸O_cel are 6-16 °C lower than the MAT estimates derived from other biological proxies. Estimates of Pleistocene and Holocene mean annual temperatures are close to the modern values at those sites. These results are consistent with other recent findings that the MAT/δ¹⁸O_ppt relationship across North America was not constant throughout the Cenozoic. Paleo-δ¹⁸O_ppt estimates derived from fossil cellulose and the modern North American relationship between δ¹⁸O_cel and δ¹⁸O_ppt are within the current annual range of δ¹⁸O_ppt values at all locations. The middle Eocene δ¹⁸O_ppt we determined from arctic cellulose samples (−21.9‰) is consistent with river water δ¹⁸O determined in two other studies (−19.1‰ to −22‰). These findings provide some evidence that a precipitation δ¹⁸O signal may be retained in wood cellulose during millions of years of burial, and that latitudinal patterns in δ¹⁸O_ppt may not have changed much during the past 45 Ma. These interpretations depend, of course, on the assumption that the isotopic composition of the cellulose has not changed during burial, an assumption for which it is difficult to gather direct evidence. XRD analysis shows that the crystalline form of the fossil cellulose we used to estimate paleoprecipitation δ¹⁸O and paleo-MAT is the same as that of modern cellulose, and that the samples are free of quartz and iron oxide contaminants that result in negative errors in measured δ¹⁸O_cel.