In vitro simulation of oxic/suboxic diagenesis in an estuarine fluid mud subjected to redox oscillations

Estuarine turbidity maxima (ETMs) are sites of intense mineralisation of land-derived particulate organic matter (OM), which occurs under oxic/suboxic oscillating conditions owing to repetitive sedimentation and resuspension cycles at tidal and neap-spring time scales. To investigate the biogeochemical processes involved in OM mineralisation in ETMs, an experimental set up was developed to simulate in vitro oxic/anoxic oscillations in turbid waters and to follow the short timescale changes in oxygen, carbon, nitrogen, and manganese concentration and speciation. We present here the results of a 27-day experiment (three oxic periods and two anoxic periods) with an estuarine fluid mud from the Gironde estuary. Time courses of chemical species throughout the experiment evidenced the occurrence of four distinct characteristic periods with very different properties. Steady oxic conditions were characterised by oxygen consumption rates between 10 and 40 μmol L⁻¹ h⁻¹, dissolved inorganic carbon (DIC) production of 9–12 μmol L⁻¹ h⁻¹, very low NH₄⁺ and Mn²⁺ concentrations, and constant NO₃⁻ production rates (0.4 - 0.7 μmol L⁻¹ h⁻¹) due to coupled ammonification and nitrification. The beginning of anoxic periods (24 h following oxic to anoxic switches) showed DIC production rates of 2.5–8.6 μmol L⁻¹ h⁻¹ and very fast NO₃⁻ consumption (5.6–6.3 μmol L⁻¹ h⁻¹) and NH₄⁺ production (1.4–1.5 μmol L⁻¹ h⁻¹). The latter rates were positively correlated to NO₃⁻ concentration and were apparently caused by the predominance of denitrification and dissimilatory nitrate reduction to ammonia. Steady anoxic periods were characterised by constant and low NO₃⁻ concentrations and DIC and NH₄⁺ productions of less than 1.3 and 0.1 μmol L⁻¹ h⁻¹, respectively. Mn²⁺ and CH₄ were produced at constant rates (respectively 0.3 and 0.015 μmol L⁻¹ h⁻¹) throughout the whole anoxic periods and in the presence of nitrate. Finally, reoxidation periods (24–36 h following anoxic to oxic switches) showed rapid NH₄⁺ and Mn²⁺ decreases to zero (1.6 and 0.8–2 μmol L⁻¹ h⁻¹, respectively) and very fast NO₃⁻ production (3 μmol L⁻¹ h⁻¹). This NO₃⁻ production, together with marked transient peaks of dissolved organic carbon a few hours after anoxic to oxic switches, suggested that particulate OM mineralisation was enhanced during these transient reoxidation periods. An analysis based on C and N mass balance suggested that redox oscillation on short time scales (day to week) enhanced OM mineralisation relative to both steady oxic and steady anoxic conditions, making ETMs efficient biogeochemical reactors for the mineralisation of refractory terrestrial OM at the land-sea interface.     

Luminosity Profiles of 6 Dwarf Galaxies in the M 81/82 Group

Für 6 Zwerggalaxien sehr geringer Flächenhelligkeit aus der M81-Gruppe werden die wichtigsten photometrischen Parameter ermittelt. Zum ersten Mal werden Helligkeitsprofile extremer Zwerggalaxien außerhalb der lokalen Gruppe angegeben. Die Profile werden sehr viel besser durch ein Exponentialgesetz als durch das r1/4-Gesetz wiedergegeben. Zwischen irregulären und sphärischen Zwerggalaxien konnten keine signifikanten Unterschiede im Profil gefunden werden.     

Transformation of amplitudes and frequencies of precession and nutation of the earth’s rotation vector to amplitudes and frequencies of diurnal polar motion

The temporal change of the rotation vector of a rotating body is, in the first order, identical in a space-fixed system and in a body-fixed system. Therefore, if the motion of the rotation axis of the earth relative to a space-fixed system is given as a function of time, it should be possible to compute its motion relative to an earth-fixed system, and vice versa. This paper presents such a transformation. Two models of motion of the rotation axis in the space-fixed system are considered: one consisting only of a regular (i.e., strictly conical) precession and one extended by circular nutation components, which are superimposed upon the regular precession. The Euler angles describing the orientation of the earth-fixed system with respect to the space-fixed system are derived by an analytical solution of the kinematical Eulerian differential equations. In the first case (precession only), this is directly possible, and in the second case (precession and nutation), a solution is achieved by a perturbation approach, where the result of the first case serves as an approximation and nutation is regarded as a small perturbation, which is treated in a linearized form. The transformation by means of these Euler angles shows that the rotation axis performs in the earth-fixed system retrograde conical revolutions with small amplitudes, namely one revolution with a period of one sidereal day corresponding to precession and one revolution with a period which is slightly smaller or larger than one sidereal day corresponding to each (prograde or retrograde) circular nutation component. The peculiar feature of the derivation presented here is the analytical solution of the Eulerian differential equations.     

Spectroscopic analysis of the nuclear and circumnuclear regions of the Seyfert 2 galaxy NGC 7130

We discuss here the spectroscopic properties of the Seyfert 2 galaxy NGC 7130 (= IC 5135). Emission line regions were isolated and line ratios were measured and fitted with photoionization models; this allowed to discriminate between thermal and non thermal ionization in the circumnuclear regions. Massive star formation is likely to occur at projected distances from the nucleus ≫ 2 kpc: line profiles in these regions suggest the presence of outflows of gas due to stellar winds from hot massive stars.     

Die Feldspate des Granites von Eisenkappel (Kärnten) und seines Randporphyres

Zusammenfassung Der Eisenkappeler Granit und sein Randporphyr wurden mineralogisch und petrographisch untersucht. Der Randporphyr und auch Übergangszonen zum Kerngranit zeigen eine Ummantelung der Alkalifeldspate mit Plagioklas-Rapakivi Textur. Genaue analytische Untersuchungen an, Alkalifeldspateinkristallen und den dazugehörigen Plagioklashüllen (bzw. den in unmittelbarer Nachbarschaft befindlichen Plagioklasen bei Proben des Kerngranits) ergaben folgende Einzelheiten: Die Alkalifeldspate sind Mikroklinperthite mit einer durchschnittlichen Triklinität von =0,50. Der Ab-Gehalt ist hoch (Kerngranit um Ab=31%, Randporphyr um Ab=38%), ebenso der An-Gehalt (durchschnittlich 3,5%). Die Plagioklase sind Oligoklase (Kerngranit um An=28%, Randporphyr um An=22%) mit einem extrem hohen Or-Gehalt (Or=4,2% bis 7,0%) und teilweise antiperthitisch entmischt. Die Zusammensetzung der Feldspate läßt auf relativ hohe Bildungstemperaturen und entsprechend niedrige Wasserdampfdrucke schließen. Die Untersuchungsergebnisse und die Entstehung der Rapakivi Textur werden diskutiert.

---

Summary The granite of Eisenkappel and its marginal porphyry (Carinthia) have been investigated. The latter as well as gradations toward the central granite have alkalifeldspars manteled with plagioclase (rapakivi texture). The phenocrysts of the alkalifeldspars and their plagioclase rims and the phenocrysts of alkalifeldspar and neighbouring plagioclases in case of the central granite show the following attitudes: The alkalifeldspar are microcline perthites with an abliquity =0,50; From the central granite to the marginal porphyry the Abcontent of the alkalifeldspar increases from Ab=31–38 wight percent. The An-content is 3,5%. The An-content of the plagioclase drops in the same direction (An=28–22%). They exhibit a high Or-content (Or=4,2–7%) which is partly unmixed to antiperthite. The composition of the feldspars reflects a rather high temperature of formation and corresponding low water vapor pressure. The results and the origin of the rapakivi texture are discussed.

---

---

Mit 6 Textabbildungen

---

Herrn Prof. Dr.H. Leitmeier zum 80. Geburistag gewidmet.     

Wave-trains in the solar wind

Applying an Alfvén-Wave-Extended-QRH-approximation and the method of characteristics, we solve the equations of motion for outwardly propagating Alfvén waves analytically for three different cases of an azimuthal dependence of the background solar wind, (a) for a pure fast-slow stream configuration, (b) for the situation where the high-speed stream originates from a diverging magnetic field region, and (c) for the case of (b) and an initially decreasing density configuration (‘coronal hole’). The reaction of these waves on the background state as well as mode-mode coupling effects are neglected. These three solar wind models are discussed shortly. For the superimposed Alfvén waves we find, on an average, that there is a strong azimuthal dependence of all relevant wave parameters which, correlated with the azimuthal distributions of the solar wind variables, leads to good agreements with observations. The signature of high-speed streams and these correlations could clearly indicate solar wind streams originating from ‘coronal holes’. Contrary to the purely radial dependent solar wind, where outwardly propagating Alfvén waves are exclusively refracted towards the radial direction, we now find a refraction nearly perpendicular to the direction of the interplanetary magnetic field in the compression region and closely towards the magnetic field direction down the trailing edge and in the low-speed regime.     

The space spectrum of convective instability

Growth rates are obtained for convective disturbances propagating in an atmosphere with a linear variation of entropy. The dispersion equation for small-scale disturbances in the parabolic entropy diagram case is considered by means of the WKB-approximation. It is shown for that case that the small-scale disturbances are reflected inside the convective zone and so cannot be observed at the Sun's surface. If the atmosphere is polytropic, it is shown that the small-scale disturbances can easily reach the sun's surface.     

What controls equatorial Atlantic winds in boreal spring?

The factors controlling equatorial Atlantic winds in boreal spring are examined using both observations and general circulation model (GCM) simulations from the coupled model intercomparison phase 5. The results show that the prevailing surface easterlies flow against the attendant pressure gradient and must therefore be maintained by other terms in the momentum budget. An important contribution comes from meridional advection of zonal momentum but the dominant contribution is the vertical transport of zonal momentum from the free troposphere to the surface. This implies that surface winds are strongly influenced by conditions in the free troposphere, chiefly pressure gradients and, to a lesser extent, meridional advection. Both factors are linked to the patterns of deep convection. Applying these findings to GCM errors indicates, that, consistent with the results of previous studies, the persistent westerly surface wind bias found in most GCMs is due mostly to precipitation errors, in particular excessive precipitation south of the equator over the ocean and deficient precipitation over equatorial South America. Free tropospheric influences also dominate the interannual variability of surface winds in boreal spring. GCM experiments with prescribed climatological sea-surface temperatures (SSTs) indicate that the free tropospheric influences are mostly associated with internal atmospheric variability. Since the surface wind anomalies in boreal spring are crucial to the development of warm SST events (Atlantic Niños), the results imply that interannual variability in the region may rely far less on coupled air–sea feedbacks than is the case in the tropical Pacific.     

Equatorial Atlantic variability and its relation to mean state biases in CMIP5

Coupled general circulation model (GCM) simulations participating in the Coupled Model Intercomparison Project Phase 5 (CMIP5) are analyzed with respect to their performance in the equatorial Atlantic. In terms of the mean state, 29 out of 33 models examined continue to suffer from serious biases including an annual mean zonal equatorial SST gradient whose sign is opposite to observations. Westerly surface wind biases in boreal spring play an important role in the reversed SST gradient by deepening the thermocline in the eastern equatorial Atlantic and thus reducing upwelling efficiency and SST cooling in the following months. Both magnitude and seasonal evolution of the biases are very similar to what was found previously for CMIP3 models, indicating that improvements have only been modest. The weaker than observed equatorial easterlies are also simulated by atmospheric GCMs forced with observed SST. They are related to both continental convection and the latitudinal position of the intertropical convergence zone (ITCZ). Particularly the latter has a strong influence on equatorial zonal winds in both the seasonal cycle and interannual variability. The dependence of equatorial easterlies on ITCZ latitude shows a marked asymmetry. From the equator to 15°N, the equatorial easterlies intensify approximately linearly with ITCZ latitude. When the ITCZ is south of the equator, on the other hand, the equatorial easterlies are uniformly weak. Despite serious mean state biases, several models are able to capture some aspects of the equatorial mode of interannual SST variability, including amplitude, pattern, phase locking to boreal summer, and duration of events. The latitudinal position of the boreal spring ITCZ, through its influence on equatorial surface winds, appears to play an important role in initiating warm events.     

Mercury contents in the vertical profiles through alluvial sediments as a reflection of mining in Idrija (Slovenia)

The influence of geomorphological factors to Hg contamination of the Idrijca River alluvial sediments because of the historical mining and ore roasting activities has been studied. Main source of Hg in alluvial sediments was dumping of ore roasting residues and mining waste into the river channel and its erosion downstream. The position of the material in relation to the geomorphological properties is highly related with its Hg content. Floodplains were found to be the most contaminated geomorphological units (mean Hg content 335 mg/kg), with Hg concentration rapidly dropping in the first terrace (155 mg/kg). The least contaminated material was found in the higher terraces (3.8 mg/kg). Sampling upstream Idrija (average Hg content is 22.1 mg/kg) shows that not only mine and ore roasting plant increased Hg levels in alluvial deposits but also contaminated sites upstream Idrija contribute to Hg contamination. Geochemical background for alluvial sediments for this area is estimated to be 0.75 mg/kg. Downstream Idrija, 9 hotspots were determined where highly contaminated material is actively eroded and carries a high risk of further contamination of the So?a River and northern Adriatic Sea ecosystems.