Thermodynamic properties and phase stability of wadsleyite II

The thermodynamical stability of a newly observed wadsleyite II phase in the Mg₂SiO₄ system is studied by the density functional theory. The wadsleyite II equation of state has been derived. The phase boundaries of Mg₂SiO₄ polymorphs: wadsleyite, wadsleyite II and ringwoodite are studied using the quasi-harmonic approximation at high external pressures. Clapeyron slopes determined for wadsleyite II–ringwoodite and wadsleyite–wadsleyite II boundaries are 0.0047 and 0.0058 GPa/K, respectively. It is shown that the wadsleyite II phase is not thermodynamically preferred in the pure Mg₂SiO₄ system and will probably not occur between wadsleyite and ringwoodite phases.     

Floods at the northern foothills of the Tatra Mountains — A Polish-Swiss research project

The present paper introduces the topical area of the Polish-Swiss research project FLORIST (Flood risk on the northern foothills of the Tatra Mountains), informs on its objectives, and reports on initial results. The Tatra Mountains are the area of the highest precipitation in Poland and largely contribute to flood generation. The project is focused around four competence clusters: observation-based climatology, model-based climate change projections and impact assessment, dendrogeomorphology, and impact of large wood debris on fluvial processes. The knowledge generated in the FLORIST project is likely to have impact on understanding and interpretation of flood risk on the northern foothills of the Tatra Mountains, in the past, present, and future. It can help solving important practical problems related to flood risk reduction strategies and flood preparedness.     

The influence of atmospheric circulation on the type of precipitation (Krak��w, southern Poland)

The paper discusses the impact of atmospheric circulation on the occurrence of various types of precipitation. A 146-year-long precipitation record from Kraków spanning the period 1863?C2008 was used alongside a calendar prepared by Nied?wied? (1981, 2009) describing circulation types covering the period 1873?C2008 and air masses and atmospheric fronts covering the period 1951?C2008 in southern Poland. The influence of atmospheric circulation on precipitation was measured using the frequency, conditional probability and average daily totals of precipitation. Circulation types, air masses and atmospheric fronts exerted influences on precipitation as a result of the seasonal variations of the thermal and moisture properties of air masses. The impact is best expressed by circulation types as these combine the aspect of cyclonicity/anticyclonicity with that of the direction of air advection, the two elements which determine the physical properties of the air. On average, liquid precipitation prevailed in all circulation types, except the Ea type in which snowfall dominated over liquid precipitation. Depending on the season, one of the three types of circulation, Wa, Wc and Bc, were shown to coincide with the greatest amount of liquid and thunderstorm precipitation. There was no single dominant circulation type for mixed precipitation or snowfall. In summer, the circulation types Nc, NEc, Cc and Bc were the most favourable to liquid and thunderstorm precipitation in terms of both probability and totals. In winter, snowfall was the most favoured by the Ec type. Frontal precipitation was twice as likely to occur as air mass precipitation, with the exception of snowfall which was predominantly an air mass type of precipitation in terms of probability, but its greatest totals were recorded on atmospheric fronts.     

Analysis of Vertical Turbulent Heat Flux Limit in Stable Conditions with a Local Equilibrium, Turbulence Closure Model

Assuming that the vertical turbulent heat flux vanishes at extremely stable conditions, one should expect its maximal absolute value to occur somewhere at moderate stability, between a neutral and extremely stable equilibrium. Consequently, in some situations duality of solutions may be encountered (e.g. two different values of temperature difference associated with the same values of heat flux and wind speed). A quantitative analysis of this feature with a local equilibrium Reynolds-stress model is presented. The fixed-wind / fixed-shear maximum has been identified both in the bulk and in single-point flux–gradient relationships (that is, in the vertical temperature gradient and wind-shear parameter domain). The value of the Richardson number corresponding to this maximum is derived from the model equations. To study the possible feedback in strongly stable conditions, weak and intense cooling scenarios have been simulated with a one-dimensional numerical, high-resolution atmospheric boundary-layer model. Despite the rapid cooling, flow decoupling at the surface has not been observed; instead, a stability-limited heat flux is maintained, with a gradual increase of the Richardson number towards the top of the turbulent layer, with some signs of oscillatory behaviour at intermediate heights. Vertical changes of wind shear and the Brunt–Väisälä frequency display a remarkably non-monotonic character, with some signs of a gradually developing instability.     

Surface-Layer Flux–Gradient Relationships over Inclined Terrain Derived from a Local Equilibrium,Turbulence Closure Model

Derivation of surface-layer flux–gradient relationships from a local-equilibrium, turbulence-closure model for a forced flow over inclined terrain is presented. Results are shown as a generalization of Monin–Obukhov universal functions respesenting non-dimensional wind and temperature gradients.     

Toxicity Assessment by Microtox® in Sediments,Pore Waters and Sediment Saline Elutriates in the Gulf of Gdansk (Baltic Sea)

The toxicity of sediments in the Gulf of Gdansk is analyzed in relation to the chemical composition of interstitial and near‐bottom waters, and sediment properties. The toxicity of sediments, pore waters and saline elutriates is determined by using the Microtox® test based on changes in light production of the luminescent bacteria Vibrio fischeri. The results indicate considerable toxicity in the majority of examined sediments. Since the sediment elutriates and pore waters are toxic in some cases, the total toxicity of the sediments is likely to be due to both sediment‐bound and water soluble substances. The sediment toxicity is related to the percentage contribution of the fine fraction of sediments. A significant correlation between the toxicity of the sediments and the black carbon content implies anthropogenic contamination. The toxicity of the sediments is seen to increase with the increase of hydrogen sulfide concentration in pore waters. The ammonia in pore waters was found not to be responsible for the toxicity of the sediments.     

Long-term variability of occurrence of precipitation forms in winter in Kraków, Poland

The paper discusses long-term change in snowfall, rainfall and mixed precipitation viewed in conjunction with air temperature and North Atlantic Oscillation (NAO) in winter (December–February). In the study of contemporary climate change and its effect on the hydrological cycle it is useful to focus on winter precipitation forms. A 146-year secular observation series from Kraków, spanning the period 1863–2008, was used to extract data on the number of days with precipitation and on precipitation amount broken down by form. Statistically significant trends were found in total and mixed precipitation, but not in snowfall and rainfall. The climate warming effect has contributed to a material decrease in the snowfall to total winter precipitation ratio during the second half of the 20th c. The highest impact of air temperature was found in the wintertime variation in number of days with snowfall while the NAO had a significant influence on the frequency and amount of both rainfall and snowfall.     

Spatial distribution of phosphorus forms in sediments in the Gulf of Gdańsk (southern Baltic Sea)

The paper analyses the concentrations of total phosphorus and its forms in sediments from the Gulf of Gdańsk on the basis of studies conducted at 25 sampling sites in 2001–05. The phosphorus speciation analysis was performed by sequential extraction. The extensive spatial variability of P_tot concentrations and speciation was found to be dependent on the physicochemical properties of the sediments, the oxygen conditions in the water and sediments, and the depth of the water column above the sediment surface. In the coastal zone, the sedimentation of riverine suspended matter and the sorption and chemisorption processes exert a considerable influence on P speciation. Over 70% of variation of total phosphorus concentration in sediments in the Gulf of Gdańsk could be explained by changes of proportion of fine fraction of sediments (grain size <0.0625 mm). Maximum P_tot concentrations were recorded in clays and silts in the deep water, stratified part of the Gulf of Gdańsk. In the coastal zone, where sandy sediments are dominant, phosphorus concentrations were much lower; this was due to the considerable dynamics of the bottom water and intensive sea floor transport. P_tot concentrations in the Gulf of Gdańsk sediments ranged from 1.75 to 957.17 μmol g⁻¹ d.w. Of all the forms of phosphorus, the highest concentrations were found for organic phosphorus (Org-P). Of its inorganic forms, the highest concentrations were of phosphorus bound to clay minerals and aluminium oxides (NaOH-P), the lowest ones were of loosely bound phosphorus (NaCl-P). On the basis of determinations of total phosphorus concentrations in sediments of a given type and the available data on the seabed areas covered by particular sediment types in the Gulf of Gdańsk, the mass of total phosphorus in the surficial sediment layer (0–2 cm) was estimated at ca. 15.6×10³ tonnes.