Effect of organic solvent type on the removal of nitrate ion using liquid membrane technique

In this study, the removal of nitrate ions from aqueous solutions with liquid membrane technique has been investigated for different organic solvent types in which solubilized tetradecyl trimethyl ammonium bromide (TDTMABr) as carrier. n-butyl alcohol, chloroform, and mixture of chloroform + n-hexane (n-hexane 85% + chloroform 15%) were used as organic solvent. Kinetic parameters (k _1d, k _2m, k _2a, t _max, R _m^max, J _m^max, J _a^max) were calculated from obtained data. time R _a values of mixture, butyl alcohol, and chloroform are 0.81, 0.78, and 0.55, respectively. Similarly R _d, R _m, and t _max values of the mixture equal to 0.14, 0.04, and 87.92 min, respectively. This behavior of the system shows the organic solvent type is an effective parameter on separation yield. It can be concluded that the mixture is the most effective organic solvent type among the investigated ones, because liquid membrane systems should be operated within the range of having the R _m, R _d, and t _max values are minimum while R _a values are maximum.     

Observations of aδ Scuti-like pulsator: HR 7222

Visual and blue band photometric observations of the Scuti-type variable have been carried out. It has been found that LT Vul pulsates in the radial fundamental mode. Higher overtones such as third andn > 3 overtones have also been detected.     

Barrier holes and trench application to reduce blast induced vibration in Seyitomer coal mine

In this research, experimental applications have been performed to reduce blast induced vibrations in open pit mines. For this purpose, artificial discontinuity zones such as barrier holes and trench were opened in a dragline panel of Seyitomer Lignite Enterprise, Kutahya, Turkey. Peak particle velocities in front of and behind them were measured by seismographs. In this way, their effect against vibration was observed and compared. Barrier holes were opened 24 m deep through 3 parallel lines and aligned at 1 m spacing. On the other hand, the trench had 8 m depth and 4 m width. During the research, 209 measurements were taken belonging to 105 explosions. Twenty-eight explosions were carried out in the barrier holes experiments and 77 explosions were carried out in the trench experiments. A decrease in vibration of 14.3–18.5% was obtained behind the barrier holes while a decrease of 24.8–58.1% was provided by the trench.     

Application of Chebyshev theorem to data preparation in landslide susceptibility mapping studies:an example from Yenice(Karabük,Turkey) region

Landslide database construction is one of the most crucial stages of the landslide susceptibility mapping studies. Although there are many techniques for preparing landslide database in the literature, representative data selection from huge data sets is a challenging, and, to some extent, a subjective task. Thus, in order to produce reliable landslide susceptibility maps, data-driven, objective and representative database construction is a very important stage for these maps. This study mainly focuses on a landslide database construction task. In this study, it was aimed at building a representative landslide database extraction approach by using Chebyshev theorem to evaluate landslide susceptibility in a landslide prone area in the Western Black Sea region of Turkey. The study area was divided into two different parts such as training (Basin 1) and testing areas (Basin 2). A total of nine parameters such as topographical elevation, slope, aspect, planar and profile curvatures, stream power index, distance to drainage, normalized difference vegetation index and topographical wetness index were used in the study. Next, frequency distributions of the considered parameters in both landslide and nonlandslide areas were extracted using different sampling strategies, and a total of nine different landslide databases were obtained. Of these, eight databases were gathered by the methodology proposed by this study based on different standard deviations and algebraic multiplication of raster parameter maps. To evaluate landslide susceptibility, Artificial Neural Network method was used in the study area considering the different landslide and nonlandslide data. Finally, to assess the performances of the so-produced landslide susceptibility maps based on nine data sets, Area Under Curve (AUC) approach was implemented both in Basin 1 and Basin 2. The best performances (the greatest AUC values) were gathered by the landslide susceptibility map produced by two standard deviation database extracted by the Chebyshev theorem, as 0.873 and 0.761, respectively. Results revealed that the methodology proposed by this study is a powerful and objective approach in landslide susceptibility mapping.     

Geochemical characteristics of Kırka (Sarıkaya) borate deposit,northwestern Anatolia,Turkey

The K?rka borate deposit was deposited in a Miocene lacustrine basin which is closely associated with volcanic activity which lasted from Paleogene to the beginning of Quaternary. Borate mineralization alternates with claystone, mudstone, tuff and fine-layered limestone and mostly shows a lenticular structure. The mineral paragenesis is composed of borax, tincalconite, ulexite, kurnakovite, probertite, tunellite, colemanite, dolomite, smectite group minerals, illite and some firstly reported minerals for the K?rka deposit including hydrochloroborite, brianroulstonite, hilgardite-4M and searlesite minerals. In comparison to average values of earth crust, concentrations of Cs, Sr, Li, As and Se were significantly enriched with respective rates of 21, 15, 14, 3 and 188 folds. Regarding KY, KS1 and KS2 locations, there are differences in both element abundances and their geochemical tendencies which are attributed to variations in discharge regime and physico-chemical conditions of the depositional environment. Independent behaviour of B₂O₃ might indicate that boron is not associated with clays and carbonates and, therefore, most part of boron must be derived from volcanic activity (hydrothermal solutions, gases). REE data indicate that the K?rka borate deposit was formed in a sedimentary environment where highly alkaline (high pH) hydrothermal solutions also took part in borate precipitation process.     

Synthesis of Calix(aza)crown and its Oligomeric Analogue for the Extraction of Selected Metal Cations and Dichromate Anions

The present study reports the synthesis of a novel ionophore, calix[4]azacrown ( 5 ) bearing two amino groups at the lower rim along with its oligomeric analogue ( 6 ). The liquid‐liquid extraction properties of these compounds towards selected metal cations and dichromate anions have been evaluated. It is observed that ( 5 ) and ( 6 ) are good extractants for the selected metal cations. However, in the case of dichromate anion, only species ( 5 ) shows remarkable extraction properties at low pH, whereas species ( 6 ) shows poor extraction behavior. The results have importance especially in wastewater treatment to obtain environmentally safe industrial effluent and they should also assist supramolecular chemists in designing and synthesizing more sophisticated host molecules for the removal of toxic pollutants.     

The Effect of Oxygen on Anaerobic Color Removal of Azo Dye in a Sequencing Batch Reactor

In this study, various amounts of oxygen were added to the anaerobic phase of an anaerobic‐aerobic sequencing batch reactor (SBR) receiving azo dye remazol brilliant violet 5R to mimic the input of oxygen into the anaerobic zones of biological textile wastewater treatment plants. The effect of oxygen on the anaerobic biodegradative capability of the mixed microbial culture for remazol brilliant violet 5R was investigated. To investigate the effect of oxygen on anaerobic azo dye biodegradation, the anaerobic phase of the SBR cultures were exposed to a very low limited amount of oxygen for various air flow rates. Initially, an air flow rate of 20 mL/min was applied, further on the air flow rate in the anaerobic phase was increased up to 40 mL/min. System performance was determined by monitoring chemical oxygen demand, color removal rate, activities of anaerobic (azo reductase) and aerobic enzymes (catechol 2,3‐dioxygenase, catechol 1,2‐dioxygenase). The results of percentage COD reduction at each stage were similar for all runs, giving an overall reduction of 96%. Anaerobic color removal efficiency and azo reductase activity of anaerobic microorganisms were adversely affected by the addition of oxygen. Color removal efficiencies of the anaerobic phases decreased from 80% down to 42 and 38% for the limited oxygen conditions of 20 mL/min and 40 mL/min, respectively. It was observed that the activity of catechol 2,3‐dioxygenase and catechol 1,2‐dioxygenase, involved in breakage of aromatic rings, increased after they are exposed to oxygen limited conditions compared to fully anaerobic conditions. It was also observed that catechol 1,2‐dioxygenase enzyme activity increased by increasing the oxygen level on oxygen limited conditions in the anaerobic zone.     

Implications of 2007’s Earthquake Activity in Eğirdir Lake (SW Anatolia) Based on Moment Tensor Solutions and Inversion of Stress State

We analyzed the waveforms of the small- to moderate-sized earthquakes that took place in the northern part of the inner Isparta Angle (IA) to retrieve their source parameters and combine these results with the focal mechanism solutions of the larger events that occurred in 2007 in E?irdir Lake at the apex of IA. In total, source mechanisms of 20 earthquakes within the magnitude range 3.5 < M < 5.0 were calculated using a regional moment tensor inversion technique. The inversion of the focal mechanisms yields an extensional regime with a NNE–SSW (N38°E) trending σ ₃ axis. Inversion results are related to a mainly WNW–ESE oriented normal fault beneath E?irdir Lake. The R value of a NNE–SSW extensional regime is 0.562 showing a triaxial stress state in the region. The current stress regime results from complex subduction processes such as slab pull, slab break-off, roll-back and/or retreating mechanism along the Hellenic and Cyprus arcs and the southwestward extrusion of the Anatolian block since the early Pliocene.     

Simulation of the earthquake-induced collapse of a school building in Turkey in 2011 Van Earthquake

Collapses of school or dormitory buildings experienced in recent earthquakes raise the issue of safety as a major challenge for decision makers. A school building is ‘just another structure’ technically speaking, however, the consequences of a collapse in an earthquake could lead to social reactions in the complex aftermath of a seismic tremor more than any other type of structure may possibly cause. In this paper a school building that collapsed during 2011 Tabanli, Van Earthquake in eastern Turkey, is analysed in order to identify the possible reasons that led to collapse. Apart from the inherent deficiencies of RC buildings built in Turkey in the 80's and 90's, its structural design exhibits a strikingly high asymmetry. In the analyses conducted, much attention has been given to the direction of the earthquake load and its coincidence with the bi-axial structural response parameters. The failure of the structure to comply with the 1975 Code, in vigor at the time of construction, has also been evaluated with respect to the structure’s collapse. Among the parameters that controlled the collapse, the high plan asymmetry and the coincidence of the vulnerable directions with the dominant shaking direction were critical, as well as the underestimation of the seismic hazard and the lateral design force level, specified by the then Turkish Earthquake Code.