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841.
This paper documents the timing, geochemistry and possible origin of sodium enrichment associated with Proterozoic iron formation-hosted copper-gold ore lenses at the Starra deposit, Australia. The ore lenses are immediately underlain by variably sheared albitemagnetite-hematite-pyrite-bearing rocks, and overlain by mainly unaltered, less-sheared, meta-sediments. Evidence indicating that albite was abundant prior to deformation, and also prior to the main hydrothermal addition of Fe, S, Cu and Au, includes (1) regional albite development at this stratigraphic level; (2) alteration of albite by ore-related sericite; and (3) inclusion of unfoliated inclusions of albite and hematite in ore-related pyrite. Nevertheless, albite also developed around dolerites and within hangingwall shears during metamorphism and deformation. Least altered albite footwall rocks have SiO2 (67.31–73.13 wt.%), Al2O3(9.89–12.51 wt.%), total alkali elements (6.40–9.43 wt.%) and HFS elements (e.g., Zr = 179–275 ppm; Ti/Zr = 7.6–14.1) comparable with felsic volcanics, but have high relative Na2O contents (5.08–5.81 wt. %), and variable to high Na2O/K2O ratios (0.05–68.37). An episode of alkali alteration by high-Na fluids prior to the ore-related alteration is postulated to account for sodic compositions, after chemical consideration of the alternatives (1) arkosic sediments; (2) trondhjemitic volcaniclastics; and (3) Na-metasomatism of Staveley Formation sediments. During the most intense ore-alteration, isocon analysis indicates a density increase of 23% compared to the least altered albitised hostrocks. Cu, Fe, Au, Sn, W, Zn, K, Ba and Rb were enriched during the mineralising process, whereas Mn, Ca, Si, Nb and Zr were lost, and Al, Ti and Y were not changed (and were used to define the isocon). The loss of some high field strength elements during this alteration indicates that igneous rock classification diagrams based on immobile element ratios should be used with caution for albitemuscovite magnetite-pyrite assemblages associated with iron formation-hosted copper-gold deposits. Zircon was partially soluble, whereas titanium oxides were probably stable in the saline, high temperature (260°–380 °C), acid (pH = 3.9–6.0) fluids envisaged for ore-related alteration.  相似文献   
842.
The thick, richly fossiliferous succession of the upper Windermere Supergroup, Mackenzie Mountains, northwestern Canada, provides a test of integrated biostratigraphic and chemostratigraphic frameworks in terminal Proterozoic correlation. The C- and Sr-isotopic abundances of lower Keele Formation carbonates approximate those for other pre-Varanger samples, confirming that the simple disc-like fossils of the underlying Twitya Formation predate all known diverse Ediacaran faunas. "Tepee" and Sheepbed carbonates record strong post-glacial isotopic excursions; in contrast, delta13C values for Gametrail through Risky carbonates vary only within the narrow range of about +l% to +2%. A second negative excursion occurs in Ingta Formation carbonates that immediately underlie the paleontologically determined Precambrian-Cambrian boundary. The upper Windermere profile as a whole compares closely with curves determined for other terminal Proterozoic successions. The lowermost diverse Ediacaran assemblages in the Sheepbed Formation correlate chemostratigraphically with the oldest fauna in Namibia, but the two assemblages differ in taxonomic composition. Blueflower assemblages correlate both chemostratigraphically and taxonomically with faunas from Australia, China, Siberia, and elsewhere. Increasing data support the hypothesis that paleontological and geochemical data together provide a reliable means of correlating terminal Proterozoic sedimentary rocks throughout the world.  相似文献   
843.
Summary The Goonumbla porphyry copper-gold deposit in N.S.W., Australia, is hosted by late Ordovician (439.2 ± 1.2 Ma)shoshonitic igneous rocks. In terms of their petrography, the rocks vary from andesitic to dacitic lavas and tuffs which are partly intruded by monzonite stocks; they are characterized by high and variable Al2O3 (13.4–19.9 wt%), very high K2O values (up to 6.8 wt%), and high K2O/Na2O ratios (0.58–1.48), which are typical for the shoshonite association. The rocks also have enriched LILE concentrations (Ba up to 1200 ppm, Sr up to 1350 ppm), low HFSE (TiO2 < 0.67 wt%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm), and very low LREE (La < 22.4 ppm, Ce < 31 ppm), which are typical for potassic volcanic rocks formed in alate oceanic-arc setting.Mineral chemistry of selected magmatic mica and apatite phenocrysts from host rocks reveals relatively high SrO and BaO contents (micas: 0.15 wt% and up to 0.28 wt%, respectively; apatites: up to 0.28 wt% and 0.19 wt%, respectively) and very high halogen concentrations. Micas are characterized by up to 3.9 wt% F and 0.14 wt% Cl, whereas apatites have up to 3.6 wt% F and 0.68 wt% Cl. These very high halogen contents compared to those from barren intrusions imply that the shoshonitic magmatism was the source of mineralization.Copper-gold mineralization consists mainly of bornite, chalcopyrite, chalcocite and minor pyrite and tetrahedrite. Native gold occurs mainly as minute grains within silicates of the host rocks, and more rarely as fine inclusions in the sulphides. Mineralization is accompanied by wallrock alteration comprising a spatially restricted potassic type and a regional propylitic alteration type.Thus, the porphyry copper-gold deposit in the Goonumbla district can be viewed as an additional example of a worldwide association between potassic/shoshonitic magmatism and base- and precious-metal mineralization. More specifically, it appears to be the oldest recorded example of a shoshontie-associated porphyry Cu-Au deposit from a late oceanic-arc setting, a possible modern analogue being Ladolam at Lihir Island, Papua New Guinea
Die Shoshonit Porphyry Cu-Au Assoziation im Goonumbla Distrikt, N.S.W., Australien
Zusammenfassung Die Porphyry Cu-Au Vererzung im Goonumbla Distrikt in New South Wales, Australien, sitzt in oberordovizischen (ca. 439.2 ± 1.2 Ma) Shoshoniten auf. Das petrographische Spektrum dieser Gesteine reicht von andesitischen bis dazitischen Laven und Tuffen, die lokal von Monzonit-Stöcken intrudiert werden; die Gesteine besitzen hohe, aber variable Al2O3 Gehalte (13.4–19.9 Gew%), sehr hohe K2O Gehalte (bis zu 6.8 Gew%) und hohe K2O/Na2O Verhältnisse (0.58–1.48), die typisch sind für Shoshonite. Außerdem weisen sie hohe Konzentrationen an LILE Elementen (Ba bis 1200 ppm, Sr bis 1350 ppm) auf und geringe Konzentrationen an HFSE (TiO2 < 0.67 Gew%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm) sowie an LREE (La < 22.4 ppm, Ce < 31 ppm), die als typisch gelten für potassische Vulkanite von ozeanischen Plattengrenzen.Die Mineralchemie von repräsentativen Glimmer- und Apatit-Phänokristallen ist charakterisiert durch hohe SrO und BaO Gehalte (Glimmer: 0.15 Gew%, bzw. bis 0.28 Gew%; Apatite: bis 0.28 Gew%, bzw. 0.19 Gew%). Sie enthalten ferner sehr hohe Halogen-Konzentrationen. Die Glimmer enthalten beispielsweise bis zu 3.9 Gew% F und 0.14 Gew% Cl, während Apatite bis zu 3.6 Gew% F und 0.68 Gew% Ci aufweisen. Dies erscheint nicht ungewöhnlich, weil Glimmer und Apatite von vererzten Mag matiten zumeist deutlich höhere Halogengehalte besitzen, als solche von unvererzten Magmatiten. Die hohen Halogen-Gehalte in Phänokristallen aus den Shoshoniten legen nahe, die Vulkanite als den Ursprung der Vererzung zu interpretieren.Die Cu-Au Vererzung besteht überwiegend aus den Sulfiden Bornit, Kupferkies, Kupferglanz und vereinzelt auftretendem Pyrit und Tetrahedrit. Gediegen Gold wird in der Regel nur als kleine Partikel innerhalb von Silikaten der shoshonitischen Wirtsgesteine und seltener als feine Einschlüsse in Sulfiden gefunden.Die Vererzung wird von hydrothermaler Alteration der Wirtsgesteine begleitet und zwei Alterationsarten lassen sich unterscheiden: eine potassische sowie eine regional zu beobachtende propylitische Alteration.Die Porphyry Cu-Au Lagerstätte im Goonumbla Gebiet ist ein Beispiel für die weltweit beobachtete Assoziation von Bunt- und Edelmetallvererzungen und potassisch/shoshonitischem Magmatismus. Der Goonumbla Distrikt stellt die älteste bisher bekannte Porphyry Cu-Au Lagerstätte aus einerspätgenetischen ozeanischen Plattengrenze dar. Einmodernes Beispiel für eine Cu-Au Lagerstätte vergleichbaren Typs ist Ladolam auf Lihir Island, Papua New Guinea.
  相似文献   
844.
Analysis of 153 residential air radon (Rn-222) screening measurements from southeast Michigan indicates that basements host Rn levels two to three times higher than upper-level rooms. Compared to unfinished basements, finished (e.g., paneled walls, tiled floors) basements apparently reduce indoor air Rn levels while partially finished basements may not. Factor analysis of residence questionnaire data explains 59 percent of the Rn data variance. The volume of pathways (e.g., foundation cracks/holes, uncapped sumps) allowing Rn seepage into the dwelling controls the largest portion, 23 percent, of the explained data variance. The residence water source explains 11 percent of the Rn data variance. Groundwater Rn levels contribute to the air Rn data variability, but the study data cannot quantitatively assess this contribution. Seven percent of the Rn data variance is likely controlled by house depressurization facilitated by residence structural properties. Residences with foundation cracks or poorly sealed joints and low-volume indoor-outdoor air exchange are more prone to this effect. Eighteen percent of the explained Rn data variance correlates with the residence's primary heat source. Evidently, operating combustion sources also induce house depressurization and allow Rn to be drawn into the house through entry paths. Twenty-four percent of the analyses equal or exceed 4 pCi/1 Rn. In residences occupied 5 years by the same individuals, 17 percent of the Rn data are 4 pCi/l; here the arithmetic mean air Rn level is 8.3 pCi/l and the average occupancy period 17.4 years.  相似文献   
845.
The geological setting, ages, petrography and geochemistry of late Pan-African ( 580 Ma) calc-alkaline and tholeiitic dike rocks in the Bir Safsaf igneous complex of south-west Egypt are discussed. These basaltic to rhyolitic dikes intruded contemporaneously and shortly after the intrusion of granitoids. The major and trace element data, Sr and Nd isotope relations, in combination with textural observations, confirm complex interactions between most of the intermediate calcalkaline dike melts and plutonic melts, with different degrees of mixing, assimilation, replenishment and tapping of magma chambers. Trachytic and rhyolitic dikes are strongly differentiated melts from the granitic pluton. The tholeiitic dikes evolved dominantly by fractional crystallization processes. It is inferred that open system and closed system processes operated in calc-alkaline magma chambers, and that the calc-alkaline melts came from a garnet-and amphibole-bearing mantle, modified by a subduction component. Tholeiitic rocks were formed later by fractional crystallization and assimilation processes. Magma ascent of both dike types took place in an extensional environment and the presumed subduction zone has to be seen in connection with the Atmur-Delgo suture zone.  相似文献   
846.
The inner regions of the circumstellar disk around Pictoris might be dust-free due to a possible planet which may have cleared up dust particles. We present a new observational technique based on the use of an anti-blooming CCD in order to directly image this zone. The structure of the disk is revealed down to 2 arcsec from the star (30 AU). We show that the Pic disk brightness is neutral inV, R, andI C , but drops down when going inward inB, possibly related to a change in the dust composition. Also, a slight disk asymmetry is present but inverted from the outer to the inner zones.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.  相似文献   
847.
In an earlier paper Arp, Bi, Chu and Zhu investigated various quasar samples and recognized a periodicity of remarkable degree in them. Their conclusion was that the existence of such a periodicity is a counterevidence against the cosmological origin of quasar redshifts. Since this question is of great importance in a cosmological context, here we reanalyze some of the samples together with a galaxy sample of the pencil-beam survey of Broadhurstet al. Our result is that on the plane of cosmological parameters (0, 0) there is a non-negligible region where two quasar samples and the galaxy sample are simultaneously fairly periodic. Pure periodicity is still compatible with cosmological principles, at least on length scales much longer than the period length. So the regularities can fit into a cosmological context.  相似文献   
848.
Proposed to both the French and the European Space Agency as one possible small mission, SPICE is a project for a dedicated small satellite for a near-IR spectroscopic all-sky survey. The instrument would cover the spectral range 1.8 - 3.6µm, possibly extended to 1.8 - 7µm, at a resolution of 100, with pixels of 1 arc-min. The excellent sensitivity (0.02 MJy sr-1) results from: i) the quasi-zero level of background due to the efficient passive cooling of the whole experiment; ii) the use of large format arrays; iii) the non-stop observing mode (drift-scanning). The spectral domain, complementing the one of ISO, partially opaque from the ground, is specially rich in spectral features tracing stars and all components of the Interstellar Medium (molecular, atomic and ionized gas, dust). With a cooling below 80 K of the focal instrument, then it becomes possible to consider doubling the spectral domain and to cover the whole 1.8 - 7µm range.  相似文献   
849.
An insight into the geomorphic evolution of any area can be obtained by detailed landform mapping. In the present study, an area in the Middle Ganga Plain has been selected for the study using mainly remote sensing data. Various fluvial landforms have been mapped and the changes in planform of rivers over approximately 50 years have been evaluated. Both fluvial processes and tectonic activities are considered to have collectively influenced the migration of the rivers in this region. Digital enhancements of Landsat MSS and TM data are found to be quite useful in identification and mapping of subtle fluvial palaeofeatures. The present study demonstrates the utility of remote sensing in examining the geomorphic evolution of the area.  相似文献   
850.
Early Cretaceous sandstones and shales from the Thakkhola region (Chukh and Tangbe Formations) were deposited on the subsiding northern (Tethyan) margin of Gondwana; current directions indicate a source area to the south. Whereas the Berriasian Chukh Formation is dominated by quartz arenites, volcaniclastic sandstones and minor conglomerates dominate the Tangbe Formation of Valanginian to Aptian age. Upsection, the composition of the volcaniclastic components changes from mainly basaltic to dominantly dacitic/rhyolitic. Magmatism was preceded and accompanied by strong uplift in the source area of the Chukh and Tangbe clastics, resulting in the erosion of probably more than several hundred meters of pre-Cretaceous sedimentary, metamorphic and plutonic rocks. A geochemical whole rock analysis of basaltic pebble fragments shows their alkaline character and suggests a within-plate geotectonic setting for the volcanic source. This volcanotectonic event is probably related to rifting between Australia and Greater India, where seafloor spreading began in late Valanginian/Hauterivian times.  相似文献   
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