Ilmenite composition in the Tellnes Fe–Ti deposit,SW Norway: fractional crystallization,postcumulus evolution and ilmenite–zircon relation

Major and trace element XRF and in situ LA-ICP-MS analyses of ilmenite in the Tellnes ilmenite deposit, Rogaland Anorthosite Province, SW Norway, constrains a two stage fractional crystallization model of a ferrodioritic Fe-Ti-P rich melt. Stage 1 is characterized by ilmenite-plagioclase cumulates, partly stored in the lower part of the ore body (Lower Central Zone, LCZ), and stage 2 by ilmenite-plagioclase-orthopyroxene-olivine cumulates (Upper Central Zone, UCZ). The concentration of V and Cr in ilmenite, corrected for the trapped liquid effect, (1) defines the cotectic proportion of ilmenite to be 17.5 wt% during stage 1, and (2) implies an increase of D _V^Ilm during stage 2, most likely related to a shift in fO₂. The proportion of 17.5 wt% is lower than the modal proportion of ilmenite (ca. 50 wt%) in the ore body, implying accumulation of ilmenite and flotation of plagioclase. The fraction of residual liquid left after crystallization of Tellnes cumulates is estimated at 0.6 and the flotation of plagioclase at 26 wt% of the initial melt mass. The increasing content of intercumulus magnetite with stratigraphic height, from 0 to ca. 3 wt%, results from differentiation of the trapped liquid towards magnetite saturation. The MgO content of ilmenite (1.4–4.4 wt%) is much lower than the expected cumulus composition. It shows extensive postcumulus re-equilibration with trapped liquid and ferromagnesian silicates, correlated with distance to the host anorthosite. The Zr content of ilmenite, provided by in situ analyses, is low (<114 ppm) and uncorrelated with stratigraphy or Cr content. The data demonstrate that zircon coronas observed around ilmenite formed by subsolidus exsolution of ZrO₂ from ilmenite. The U-Pb zircon age of 920 ± 3 Ma probably records this exsolution process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

Possibilities of GPS Kinematic Measurements for Geological Survey in East Slovakia

This paper deals with transformation procedures for observed GPS data from the world geodetic system WGS-84 into the national geodetic grid datum S-UTCN(system of united trigonometric cadaster network) and Baa(the Baltic Sea after adjustment).Transformation from WGS-84 into SUTCN is performed most frequently by means of the 7-element Helmert transformation with three identical points.Geodetic network was adjusted by two ways.     

Atmospheric concentrations of nonmethane hydrocarbons at a North European coastal site

Two years of individual nonmethane hydrocarbon (NMHC) measurements at a rural site close to the south coast of Norway show that there was a distinct annual cycle with a late winter maximum and late summer minimum in the slowly reacting NMHCs acetylene, ethane, propane and i- and n-butane. The average January—March concentrations were a factor 2–4 higher than the July-September concentrations. Also ethene, propene and the pentanes show a similar annual cycle, but the individual scatter in the measurements in particular of propene, is large. The highest concentrations of NMHC were found in winter for easterly transport on a regional scale (out to 1500 km from the site), and for southeasterly transport in the summer.     

Improved indirect phase reflection height measurement at panská ves — method,equipment, evaluation

Summary Indirect phase reflection height measurements have been performed at the Panská Ves Observatory, Czechoslovakia, for 30 years to monitor solar flare effects (SFA). Only after introducing the new receiver in May 1985, could the indirect phase height analysis (IPHA) method be applied to measurements along the Allouis — Panská Ves 162 kHJ measuring path. The IPHA method allows the electron density and pressure variability in the lower ionosphere to be studied, particularly near the 80 km altitude. This paper describes the theoretical background of the IPHA method, the measuring equipment used at Panská Ves, the method of evaluating records and checking of data, and the program package developed by us both for graphic and numerical processing, as well as our efforts to develop a homogeneous East European IPHA network. The IPHA method has been introduced succesfully at the Panská Ves Observatory.     

Direct measurement of U-238 and disequilibrium state in geological samples by low energy scintillation gamma spectroscopy

A method has been developed to determine the state of disequilibrium and uranium content in geological samples using low energy gamma scintillation spectrometry. Ore standards in radioactive equilibrium were prepared in different concentrations and their low energy spectra were compared with those of chemical uranium standards of the same concentrations. The standards were analysed carefully for their U contents using X-ray fluorescence and high resolution gamma spectrometers. Counts of the complex peak under which 63 keV and 93 keV photopeaks take place in ore spectra were compared with the counts in corresponding channels of chemical uranium spectra. For standards in equilibrium it was found that (26 ± 2)% of the counts under complex peak came from Th-234 and also there was a constant relation between Th-234 (63 keV and 93 keV) and Pb-210 (47 keV) counts. The technique was applied to the geological samples for which eU concentrations had been measured previously by means of high energy gamma spectroscopy in the same laboratory.     

Deep seismic reflection experiments at Kiruna

Summary In August 1955 a series of specially arranged quarry blasts in the Kiruna iron ore mines was recorded with a refraction apparatus at approx. 10 km distance. The experiments are the first seismic investigations of the deeper crustal structure in Fennoscandia and were mainly undertaken in order to study near-vertical reflections from crustal discontinuities. The records show clear directP waves with sharp onsets and a velocity of 5.65±0.13 km/sec (in porphyry), furthermoreS waves of less definite onsets and sound waves through the atmosphere.P waves reflected from crustal discontinuities are weak and of erratic occurrence, in agreement with theoretical expectation for near-vertical reflections. Approx. depths to the Conrad and the Mohorovii'c discontinuities are calculated as 19 km and 33–34 km. There is general agreement with the explosion records written by the Grenet seismograph at Kiruna, and the differences which exist can be explained by the different frequency response of the two instruments.

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Zusammenfassung Im August 1955 wurde eine Reihe speziell angeordneten Steinbruchsprengungen in den Eisenerzgruben bei Kiruna mittels einer Refraktionsapparatur in rund 10 km Entfernung registriert. Diese Versuche sind die ersten seismischen Untersuchungen der tieferen Krustenstruktur in Fennoskandien und wurden hauptsächlich wegen eines Studiums von Reflexionen an krustalen Diskontinuitäten bei nahe vertikalem Einfall der Wellen vorgenommen. Deutliche, direkteP-Wellen mit scharfen Einsätzen und einer Geschwindigkeit von 5.65±0.13 km/sec (Porphyr) wurden registriert, ausserdemS-Wellen mit weniger scharfen Einsätzen und Schallwellen durch die Atmosphäre. An krustalen Diskontinuitäten reflektierteP-Wellen sind schwach und unregelmässig, im Einklang mit theoretischen Erwartungen für Reflexionen bei nahe vertikalem Einfall. Die Tiefen der Conrad- und der Mohorovii-Diskontinuitäten wurden annähernd zu 19 km bzw. 33–34 km berechnet. Es besteht allgemeine Übereinstimmung mit den Explosionsregistrierungen des Grenet-Seismographen in Kiruna, und die Unterschiede können lediglich durch die unterschiedliche Frequenzempfindlichkeit der Instrumente erklärt werden.

     

Determination of period of oscillation and sensitivity of simple horizontal pendulums for tidal measurements

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