Climate variability and glacial processes in eastern Iceland during the past 700 years based on varved lake sediments

Striberger, J., Björck, S., Ingólfsson, Ó., Kjær, K. H., Snowball, I. & Uvo, C. B. 2010: Climate variability and glacial processes in eastern Iceland during the past 700 years based on varved lake sediments. Boreas, 10.1111/j.1502‐3885.2010.00153.x. ISSN 0300‐9483. Properties of varved sediments from Lake Lögurinn in eastern Iceland and their link to climate and glacial processes of Eyjabakkajökull, an outlet glacier of the Vatnajökull icecap, were examined. A varve chronology, which covers the period AD 1262–2005, was constructed from visual observations, high‐resolution images, X‐ray density and geochemical properties determined from X‐radiography and X‐ray fluorescence scanning. Independent dating provided by ¹³⁷Cs analysis and eight historical tephras verify the varve chronology. The thickness of dark‐coloured seasonal laminae, formed mainly of coarser suspended matter from the non‐glacial river Grímsá, is positively correlated (r=0.70) with winter precipitation, and our 743‐year‐long varve series indicates that precipitation was higher and more varied during the later part of the Little Ice Age. Light‐coloured laminae thickness, controlled mainly by the amount of finer suspended matter from the glacial river Jökulsáí Fljótsdal, increased significantly during the AD 1972 surge of Eyjabakkajökull. As a consequence of the surge, the ice‐dammed Lake Háöldulón formed and recurrently drained and delivered significant amounts of rock flour to Lake Lögurinn. Based on these observations, and the recurring cyclic pattern of periods of thicker light‐coloured laminae in the sediment record, we suggest that Eyjabakkajökull has surged repeatedly during the past 743 years, but with an increased frequency during the later part of the Little Ice Age.     

Periodicities in Irradiance and in other Solar Activity Indices During Cycle 23

Magnetic fields give rise to distinctive features in different solar atmospheric regimes. To study this, time variations of the flare index, sunspot number and sunspot area, each index arising from different physical conditions, were compared with the solar composite irradiance throughout cycle 23. Rieger-type periodicities in these time series were calculated using Fourier and wavelet transforms (WTs). The peaks of the wavelet power of these periodicities appeared between the years 1999 and 2002. We found that the solar irradiance oscillations are less significant than those in the other indices during this cycle. The irradiance shows non-periodic fluctuations during this time interval. The peaks of the flare index, sunspot number and sunspot total area were seen around 2000.4, 1999.9 and 2001.0, respectively. These periodicities appeared intermittently and were not simultaneous in different solar activity indices during the three years of the maximum phase of solar cycle 23.     

AN UPPER BOUND TO THE SOLAR OBLATENESS

Solar Physics - For more than a decade, it has been suggested that the diameter of the Sun may vary in time. This not only concerns variations of the equatorial diameter, but also any other...     

Failure and flow development of a collapse induced complex landslide: the 2005 Kuzulu (Koyulhisar, Turkey) landslide hazard

Koyulhisar located in a slope of hilly region and constructed in the side of a mountain along the North Anatolian Fault Zone is frequently subject to landslides. A catastrophic landslide occurred on the morning of 17 March 2005 in the North of the Kuzulu district of Koyulhisar (Sivas, Turkey). This landslide caused widespread loss of life, and damage to buildings, and lifelines. Fifteen people were dead and five were injured, 21 houses and a minaret were covered and damaged severely. The case study presented in this paper describes and analyses the results of the detailed surveys of an interesting landslide in Kuzulu district of Koyulhisar (Sivas, Turkey), based on field and laboratory measurements and monitoring of the slide area. Landslide initiated as a collapse, and developed into debris avalanches in the valley. This phenomenon caused a disaster in the Kuzulu district. The importance of this landslide in particular has been recognized both in terms of its consequence for the people and structures and in terms of its role in allowing an understanding of process and properties of landslide triggered by a collapse in limestone karst. In view of the potential for such events to occur again in this area and environs, understanding of the failure mechanism is very crucial.     

Metal (Al, Fe, Mn and Cu) distributions and origins of polycyclic aromatic hydrocarbons (PAHs) in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey

In this study, total metal (Al, Fe, Mn and Cu) and PAHs analyses have been done in the surface sediments. Sediment samples have been collected from seven parts of the Marmara Sea and the coast of Istanbul during 2009. Total Al, Fe, Mn and Cu contents vary between 1.8% and 5.4%; 1.1% and 2.8%; 122 and 259 μg g⁻¹; 27 and 416 μg g⁻¹, respectively. EF and CF values of Fe and Mn are lower than 1.5 and 1, respectively, in all the stations. Total PAH contents range between 135 and 6009 ng g⁻¹ in the surface sediments. The origin of PAHs has been found pyrolitic according to the Phe/Ant ratio in the all stations. Contrastingly, at K0, MKC and MY1 Stations, PAH origins have been observed petrogenic according to the Flu/Pyr ratio.     

Removal of Cu2+ and Pb2+ Ions Using CMC Based Thermoresponsive Nanocomposite Hydrogel

In this study, carboxymethylcellulose (CMC) based thermoresponsive nanocomposite hydrogel was synthesized for the removal of Cu²⁺ and Pb²⁺ ions from aqueous solutions. To prepare nanocomposite hydrogel, graft copolymerization of N‐isopropyl acrylamide (NIPAm) and acrylic acid (AA) onto CMC was carried out in Na‐montmorillonite (MMT)/water suspension media and ammonium persulfate (APS) used as initiator. The chemical structures of hydrogels were characterized by Fourier transform infrared (FT‐IR) and X‐ray diffraction spectroscopy (XRD). Lower critical solution temperature (LCST), pH responsivity, swelling, and deswelling properties of the hydrogels were also examined. In addition competitive and non‐competitive removal of Cu²⁺ and Pb²⁺ studies were carried out. According to heavy metal sorption studies results, removal capacities of nanocomposite hydrogel for both metal ions were found to be higher than those of pure hydrogel. The analyzed adsorption data showed that the adsorption process of Cu²⁺ and Pb²⁺ could be explained by pseudo‐second order kinetic model. Moreover, according to competitive sorption studies, it is found to be that both hydrogels are more selective to Cu²⁺ ion rather than Pb²⁺.     

Color Removal from Synthetic Textile Wastewater by Sono‐Fenton Process

In this study, the oxidative decolorization of C.I. reactive yellow 145 (RY 145) from synthetic textile wastewater including RY 145 and polyvinyl alcohol by Fenton and sono‐Fenton processes which are the combination of Fenton process with ultrasound has been carried out. The effects of some operating parameters which are the initial pH of the solution, the initial concentration of Fe²⁺, H₂O₂, and the dye, temperature, and agitation speed on the color and chemical oxygen demand (COD) removals have been investigated. The optimum conditions have been found as [Fe²⁺] = 20 mg/L, [H₂O₂] = 20 mg/L, pH 3 for Fenton process and [Fe²⁺] = 20 mg/L, [H₂O₂] = 15 mg/L, pH 3 for sono‐Fenton process by indirectly sonication at 35 kHz ultrasonic frequency and 80 W ultrasonic power. The color and COD removal efficiencies have been obtained as 91 and 47% by Fenton process, and 95 and 51% by sono‐Fenton processes, respectively. Kinetic studies have been performed for the decolorization of RY 145 under optimum conditions at room temperature. It has been determined that the decolorization has occurred rapidly by sono‐Fenton process, compared to Fenton process.     

Build‐up and depositional dynamics of an arc front volcaniclastic complex: the Miocene Tepoztlán Formation (Transmexican Volcanic Belt,Central Mexico)

Volcanic terrains such as magmatic arcs are thought to display the most complex surface environments on Earth. Ancient volcaniclastics are notoriously difficult to interpret as they describe the interplay between a single or several volcanoes and the environment. The Early Miocene Tepoztlán Formation at the southern edge of the Transmexican Volcanic Belt belongs to the few remnants of this ancestral magmatic arc, and therefore is thought to represent an example of the initial phase of evolution of the Transmexican Volcanic Belt. Based on geological mapping, detailed logging of lithostratigraphic sections, palaeocurrent data of sedimentary features and anisotropy of magnetic susceptibility, mapping of two‐dimensional panels from outcrop to field scale, and geochronological data in an area of ca 1000 km², three periods in the evolution of the Tepoztlán Formation were distinguished, which lasted around 4 Myr and are representative of a volcanic cycle (edifice growth phases followed by collapse) in a magmatic arc setting. The volcaniclastic sediments accumulated in proximal to medial distances on partly coalescing aprons, similar to volcanic ring plains, around at least three different stratovolcanoes. These volcanoes resulted from various eruptions separated by repose periods. During the first phase of the evolution of the Tepoztlán Formation (22·8 to 22·2 Ma), deposition was dominated by fluvial sediments in a braided river setting. Pyroclastic material from small, andesitic–dacitic composite volcanoes in the near vicinity was mostly eroded and reworked by fluvial processes, resulting in sediments ranging from cross‐bedded sand to an aggradational series of river gravels. The second phase (22·2 to 21·3 Ma) was characterized by periods of strong volcanic activity, resulting in voluminous accumulations of lava and tuff, which temporarily overloaded and buried the original fluvial system with its detritus. Continuous build‐up of at least three major volcanic centres further accentuated the topography and, in the third phase (21·3 to 18·8 Ma), mass flow processes, represented by an increase of debris flow deposits, became dominant, marking a period of edifice destruction and flank failures.     

Zircon evaporation ages and geochemistry of metamorphosed volcanic rocks from the Vinjamuru domain,Krishna Province: evidence for 1.78 Ga convergent tectonics along the southeastern margin of the Eastern Dharwar Craton

Palaeoproterozoic intermediate to potassic felsic volcanism in volcano‐sedimentary sequences could either have occurred in continental rift or at convergent magmatic arc tectonic settings. The Vinjamuru domain of the Krishna Province in Andhra Pradesh, SE India, contains such felsic and intermediate metavolcanic rocks, whose geochemistry constrains their probable tectonic setting and which were dated by the zircon Pb evaporation method in order to constrain their time of formation. These rocks consist of interlayered quartz–garnet–biotite schist, quartz–hematite–baryte–sericite schist as well as cherty quartzite, and represent a calc‐alkaline volcanic sequence of andesitic to rhyolitic rocks that underwent amphibolite‐facies metamorphism at ~1.61 Ga. Zircons from four felsic metavolcanic rock samples yielded youngest mean ²⁰⁷Pb/²⁰⁶Pb ages between 1771 and 1791 Ma, whereas the youngest zircon age for a meta‐andesite is 1868 Ma. A ~2.43 Ga zircon xenocryst reflects incorporation of Neoarchaean basement gneisses. Their calc‐alkaline trends, higher LILE, enriched chondrite‐normalized LREE pattern and negative Nb and Ti anomalies on primitive mantle‐normalized diagrams, suggest formation in a continental magmatic arc tectonic setting. Whereas the intermediate rocks may have been derived from mantle‐source parental arc magmas by fractionation and crustal contamination, the rhyolitic rocks had crustal parental magmas. The Vinjamuru Palaeoproterozoic volcanic eruption implies an event of convergent tectonism at the southeastern margin of the Eastern Dharwar Craton at ~1.78 Ga forming one of the major crustal domains of the Krishna Province. Copyright © 2012 John Wiley & Sons, Ltd.     

Gaseous emission comparison of a compression–ignition engine fueled with different biodiesels

In this study, it was performed a comparison of the performance and emissions of two methyl ester fuels: one obtained from animal fat and the other from crude canola oil, in a compression-ignition engine against diesel fuel. The experimental results compared with diesel fuel showed that significant reductions could be obtained by biodiesel derived from animal fat in carbon monoxide and oxides of nitrogen emissions. Carbon dioxide emissions showed a trend of decreasing with the biodiesel fuels. An increase in brake specific fuel consumption was observed for different biodiesel fuels when compared with diesel fuel. It was concluded that animal tallow methyl ester performed better than canola oil methyl ester, whereas slightly higher brake torque is observed with canola oil methyl ester.