Chloride and Organic Chlorine in Soil

Chloride is ubiquitous in soil, but the past years of research have revealed that organic matter also contains chlorine, in amounts similar to that of phosphorus. Hence, one of the major constituents of soil organic matter has previously been overlooked, and still very little is known about the turnover of organic chlorine in soil. In spite of the obvious connection between chloride and organic chlorine, organic chlorine rarely is considered when the biogeochemical cycling of chloride is in focus, and chloride rarely is taken into account when the occurrence and formation of natural organic chlorine compounds are in focus. The aim of the paper is to review ten years of research concerning the biogeochemical cycling of organic chlorine in soil, and to tie the biogeochemical cycling of organic chlorine to that of chloride.     

Origin of lunar fragmental matrix breccias—Highly siderophile element constraints

Ejecta at North Ray crater (Apollo 16) sampled a unique section of the lunar highlands not accessible at most other landing sites and provide important constraints on the composition of late accreted materials. New data on multiple aliquots of four fragmental matrix breccias and a fragment‐laden melt breccia from this site display a variety of highly siderophile element patterns which may represent the signatures of volatile element‐depleted carbonaceous chondrite‐like material, primitive achondrite, differentiated metal, and an impactor component that cannot be related to known meteoritic material. The latter component is prevalent in these rocks besides characterized by depletions in Re and Os compared to Ir, Ru and Pt, chondritic Re/Os, and a gradual depletion of Pd and Au. The observed characteristics are more consistent with fractionations by nebular processes, like incomplete condensation or evaporation, than with lunar crustal processes, like partial melting or volatilization. The impactor signature preserved in these breccias may stem from primitive meteorites with a refractory element composition moderately different from known chondrites. The presence of distinct impactor components within the North Ray crater breccias together with observed correlations of characteristic element ratios (e.g., Re/Os, Ru/Pt, Pd/Ir) in different impact lithologies of four Apollo landing sites constrains physical mixing processes ranging from the scale of gram‐sized samples to the area covered by the Apollo missions.     

Retrofit of non-seismically designed beam-column joints by post-tensioned superelastic shape memory alloy bars

A series of tests on three full-scale substandard exterior beam-column joints were performed to investigate the efficiency of the proposed retrofit configuration, which is the use of externally applied post-tensioned shape memory alloy (SMA) bars. A major group of structural deficiencies resulting from lack of shear reinforcement in the joint, use of low strength concrete and plain round bars were taken into account in the construction of test specimens. While the reference specimen represents the as-built subassembly, the other two were retrofitted by the post-tensioned SMA and steel bars to compare the contribution of superelastic and conventional material on the response. The specimens were exposed to quasi-static cyclic loading up to 8% drift ratio to simulate an intensive level of seismic hazard. The reference specimen underwent a brittle shear failure as excessive cracks mostly concentrated in the joint panel while there was almost no damage in the rest of the RC components. A joint failure with enhanced response quantities was observed in the specimen retrofitted by post-tensioned steel bars. The specimen incorporating the retrofit solution via post-tensioned SMA bars was capable of performing an adequate performance and promoting minimization of the damage in the joint panel, which results in more ductile behavior. The hysteretic response of the SMA retrofitted specimen was validated with a refined numerical model in ATENA Science software. Experimentally observed response was also verified by an analytical model based on fracture mechanics considering the nonlinear behavior of plain concrete under tension. Due to inherent uncertainties in material constitutive laws, the analytical model was evolved to a stochastic level to propose a more advanced model for estimating the capacity of the reference and retrofitted joint. It is found that the experimental results were within the prominent range of Probability Density Functions (i.e. mean ± 1 SD) of the estimated joint tensile stress especially for the shear damaged specimens.     

Estimation of site effects using strong motion data of BYTNet array in Turkey

Simultaneous estimation of effects of source, propagation path, and local site amplification was carried out using observed strong motion records in a frequency range from 0.8 to 20 Hz for the purpose of empirical evaluation of the local site effects in different geological conditions in the northwestern part of Turkey. The analyzed data are S-wave portions of 162 accelerograms from 39 shallow events observed at 14 sites of BYTNet array. A spectral separation method was applied to the observed S-wave spectra. The solutions for source spectra, inelasticity factor of propagation path for S-waves (Q _s-value), and factor of site amplification at each site were obtained in a least squares sense. In the analysis, we assumed that the factor of the site amplification at a reference site is the same as that of theoretical amplification of S-waves to the soil model whose bottom layer has an S-wave velocity around 2.15 km/s. The estimated Q _s-value of the propagation path is modeled as Q _s(f)?=?87.4f^0.78. The estimated site amplifications are characterized into three groups. The sites in the first group belong to rock site with no dominant peaks at a frequency range of 2 to 10 Hz. The second group of hard soil sites is characterized with moderately dominant peaks at a frequency of 5 Hz. The last group for soft soil sites has common peaks at a frequency of 4 Hz with larger amplitudes than those in the hard soil group. We, then, compare the amplifications with average S-wave velocity in top 30 m of the shallow S-wave profiles and proposed linear empirical formula between them at each frequency. We, furthermore, inverted the observed amplification factors into S-wave velocity and Q _s-value profiles of the deep soil over the basement.     

Daily pan evaporation modelling using multi‐layer perceptrons and radial basis neural networks

This paper reports on investigations of the abilities of three different artificial neural network (ANN) techniques, multi‐layer perceptrons (MLP), radial basis neural networks (RBNN) and generalized regression neural networks (GRNN) to estimate daily pan evaporation. Different MLP models comprising various combinations of daily climatic variables, that is, air temperature, solar radiation, wind speed, pressure and humidity were developed to evaluate the effect of each of these variables on pan evaporation. The MLP estimates are compared with those of the RBNN and GRNN techniques. The Stephens‐Stewart (SS) method is also considered for the comparison. The performances of the models are evaluated using root mean square errors (RMSE), mean absolute error (MAE) and determination coefficient (R²) statistics. Based on the comparisons, it was found that the MLP and RBNN computing techniques could be employed successfully to model the evaporation process using the available climatic data. The GRNN was found to perform better than the SS method. Copyright © 2008 John Wiley & Sons, Ltd.     

Studies on the effect of burden width on blast-induced vibration in open-pit mines

This study concerns the correlation between burden and blast-induced vibrations in open-pit mines. For this purpose, two different mines were studied. In these mines, the vibrations caused by explosions at burdens having widths ranging from 3 to 14 m were measured from various distances. From the results, it was found for these cases that burden width has a significant impact on vibrations. Consequently, it was proven that vibrations decrease as burden increases.     

Selective diffraction with possible application to solar research

The writer describes diffraction phenomena in transmission gratings made as strips of alternating color. He discusses diffraction in slits formed in semitransparent material including liquid or gaseous layers and particularly when line- and band-absorption is present. He suggests that atmospheric seeing should be influenced by selective diffraction in telluric lines. He also discusses possible seeing effects in the solar atmosphere and prominences and hints at the possibility that irregular or semiregular selective diffraction may appear in the deep layers of sunspots possibly contributing to the scattering of light.