Engineering properties of Hınıs ignimbrites and their usability as a building stone (Erzurum, Turkey)

The survival of several ancient monuments made of ignimbrites in Hınıs town (Erzurum-Anatolia), which has suffered from intense annual temperature fluctuations and strong seismic activity, can mainly be attributed to use of suitable building stones. This paper examines the usability as building stones of Middle Miocene Hınıs ignimbrites that widely outcrop in and around Hınıs town. The petrographical, geochemical, mechanical, and physical properties determined lead to categorization of the ignimbrites as four different types. The Hınıs ignimbrites contain dasite–trachy–andesite and rhyolite. Rhyolite is the strongest material whereas the other types, being more porous, are weaker, lighter, and have good heat-insulation properties. Being light (easily transportable, machinable, and workable), good heat insulators, environmentally friendly (because of natural ventilation), sufficiently elastic to sustain seismic loading in the area under study, and more cost-effective than artificial stones, Hınıs ignimbrites are certainly a preferable option for use as light building stone. These ignimbrites are not suitable for use as floor covering, however, (because of rapid abrasion) or for building structural columns (because of low strength).     

Single zircon ages from high-grade rocks of the Jianping Complex, Liaoning Province, NE China

The high-grade rocks of the Jianping Complex in Liaoning Provi nce, NE China, belong to the late Archaean to earliest Proterozoic granulite belt of the North China craton. Single zircon ages obtained by the Pb–Pb evaporation method and SHRIMP analyses document an evolutionary history that began with deposition of a cratonic supracrustal sequence some 2522–2551 Ma ago, followed by intrusion of granitoid rocks beginning at 2522 Ma and reaching a peak at about 2500 Ma. This was followed by high-grade metamorphism, transforming the existing rocks into granulites, charnockites and enderbites some 2485–2490 Ma ago. The intrusion of post-tectonic granites at 2472 Ma is associated with widespread metamorphic retrogression and ends the tectono–metamorphic evolution of this terrain. A similar evolutionary sequence has also been recorded in the granulite belt of Eastern Hebei Province. We speculate that the Jianping Complex was part of an active continental margin in the late Archaean that became involved in continental collision and crustal thickening shortly after its formation. There is a remarkable similarity between the 2500 Ma North China granulite belt and the equally old granulite belt of Southern India, suggesting that the two crustal domains could have been part of the same active plate margin in latest Archaean times.     

Variation of the elastic constants of tourmaline with chemical composition

Elastic wave velocities and lattice parameters of five tourmaline specimens with different chemical compositions have been measured. The piezoelectric effects on the elastic constants have been found to be small and can be neglected. Variations of the elastic wave velocities and elastic constants of the different tourmaline specimens indicate that: (i) partial substitution of Al by Fe in the structure decreases the shear wave velocities, (ii) replacement of Na by Ca increases the resistance of the structure against shear deformation involving C ₆₆, (iii) replacement of Al by Mg seems to decrease the resistance of the structure against longitudinal deformation involving C ₃₃. Elastic constants C ₁₁, C ₃₃, C ₄₄ and C ₆₆ of the different tourmaline specimens used in this study differ individually by 1.7 percent to 6.7 percent, indicating that the large differences (up to 21%) between the values reported by previous authors cannot be explained in terms of the chemical composition alone.     

Author index 1984 (volumes 67–71)

Magnetic properties of samples from Bell Island sedimentary rocks have been studied. X-ray analysis indicates that the main magnetic mineral is hematite in all samples. The other iron-bearing minerals identified are siderite and chamosite. Microscope observations of thin sections suggest that the rocks consist of oolitic hematite in a matrix of siderite or calcite. The intensity of natural remanent magnetization (NRM) varies in the range of (0.03–0.4 A m^?1), depending on the percentage of hematite. The thermal demagnetization curves of NRM show in some cases a sharp increase in magnetization at temperatures in the range 500–600°C. The peaks that occur in these demagnetization curves are due to a chemical change of siderite during repeated laboratory heating. X-ray analysis confirmed that the newly formed material is magnetite. Since the original NRM has been masked by the new intergrown material, this would result in a serious error in the determination of paleomagnetic pole positions. The samples showing this behaviour were not considered for paleomagnetic study. The samples containing oolitic hematite in a calcite matrix exhibit very high stability of NRM, including directional stability until almost 670°C. For these samples, a virtual pole position based on N = 6 samples (32 specimens) demagnetized to 665°C is 34°N, 114°E, not far from published Ordovician poles for the North American craton.     

Multi-chronometric ages and origin of Archaean tonalitic gneisses in Finnish Lapland: A case for long crustal residence time

The Tojottamanselkä gneisses of the Koitelainen region, northern Finland, have been dated by the Sm-Nd and the common Pb methods. The Sm-Nd data of seven samples from a small area (100 m × 100 m) define an isochron ofT=3.06±0.12 (2) Ga, with correspondingI _Nd=0.50848±9 (2), or _Nd(T)=–3.7±1.8. This age is in good agreement with the zircon U-Pb discordia age (3.1 Ga) reported by Kröner et al. (1981) and is interpreted as the time of magmatic emplacement. The distinctly negative _Nd(T) value is found for the first time for Archean tonalitic gneisses and implies derivation of these magmas by remelting of continental material with a long (200–500 Ma) crustal residence time. A few samples, on the other hand, possess _Nd(T) values close to zero, hence they are thought to be derived by partial melting of basaltic sources with nearchondritic REE distribution patterns.Common Pb isotopic data yield an isochron age of 2.64±0.24 (2) Ga which is in agreement, within error limit, with the published Rb-Sr isochron age of 2.73±0.24 Ga (Kröner et al. 1981). The age of ca. 2.7 Ga is interpreted as the time of regional metamorphism during which both Pb and Sr isotopes were rehomogenised.The tonalitic gneisses have highly fractionated REE patterns with (La/Yb)_N ratios varying from 9 to 43. Like most Archean gneisses of TTG composition (tonalite-trondhjemite-granodiorite), they could be derived by partial melting of crustal sources of basaltic to granodioritic compositions. Direct derivation by melting of mantle peridotites is excluded.The present geochemical study indicates that the Tojottamanselkä gneisses have had a very complex history that involved multi-stage development. Together with the published age data for the basement gneisses and greenstone belts of eastern central Finland (Vidal et al. 1980; Martin et al. 1983a), we conclude that the Archean crustal development in Finland started at least 3.5 Ga ago and passed through a series of magmatic and metamorphic events at 3.1, 2.85, 2.65 and 2.5 Ga before the final intrusions of K-rich granites about 2.4 Ga ago.     

Late proterozoic island arc volcanics from Gebeit,Red Sea Hills,north-east Sudan

The area of Gebeit Mine in the northern Red Sea Hills, Sudan, is built up of voluminous volcanic rocks and minor volcaniclastic and clastic sequences. According to their chemical and modal compositions the Gebeit volcanics can be devided into four groups: (a) cpx-physic basalts with clinopyroxene and plagioclase as the dominant phenocrysts and minor opaques; (b) hbl-physic basalts with hornblende, clinopyroxene, plagioclase and subordinate magnetite including one rare dacite; (c) pl-phyric andesites with plagioclase phenocrysts in a matrix that is rich in magnetite; and (d) aphyric basalts. The compositional variation within the distinct volcanic groups can only partly be explained by fractional crystallization, and more than one magma source reservoir is required.Mineral and whole rock Sm/Nd data for the cpx-physic and hbl-physic basalts yield an isochron age of 832 ± 26 Ma (Nd_T = 6.74 ± 0.19, MSWD = 0.12) which is interpreted as the age of eruption. The Nd_t values for the aphyric basalts and pl-physic andesites range from 6.7 to 8.3, indicating the involvement of different depleted magma sources. The Nd and Sr isotopic data rule out any significant influence of older continental crust in the formation of the Gebeit volcanics and indicate an intraoceanic origin. This implies that the Gebeit terrane is a segment of juvenile crust that originated in a subduction-related environment and supports the arc accretion model for the Arabian-Nubian Shield.     

Detrital footprint of the Mozambique ocean: U–Pb SHRIMP and Pb evaporation zircon geochronology of metasedimentary gneisses in eastern Madagascar

The southern East African Orogen is a collisional belt where the identification of major suture zones has proved elusive. In this study, we apply U–Pb isotopic techniques to date detrital zircons from a key part of the East African Orogen, analyse their possible source region and discuss how this information can help in unravelling the orogen.U–Pb sensitive high-mass resolution ion microprobe (SHRIMP) and Pb evaporation analyses of detrital zircons from metasedimentary rocks in eastern Madagascar reveal that: (1) the protoliths of many of these rocks were deposited between 800 and 550 Ma; and (2) these rocks are sourced from regions with rocks that date back to over 3400 Ma, with dominant age populations of 3200–3000, 2650, 2500 and 800–700 Ma.The Dharwar Craton of southern India is a potential source region for these sediments, as here rocks date back to over 3400 Ma and include abundant gneissic rocks with protoliths older than 3000 Ma, sedimentary rocks deposited at 3000–2600 Ma and granitoids that crystallised at 2513–2552 Ma. The 800–700 Ma zircons could potentially be sourced from elsewhere in India or from the Antananarivo Block of central Madagascar in the latter stages of closure of the Mozambique Ocean. The region of East Africa adjacent to Madagascar in Gondwana reconstructions (the Tanzania craton) is rejected as a potential source as there are no known rocks here older than 3000 Ma, and no detrital grains in our samples sourced from Mesoproterozoic and early Neoproterozoic rocks that are common throughout central east Africa. In contrast, coeval sediments 200 km west, in the Itremo sheet of central Madagascar, have detrital zircon age profiles consistent with a central East African source, suggesting that two late Neoproterozoic provenance fronts pass through east Madagascar at approximately the position of the Betsimisaraka suture. These observations support an interpretation that the Betsimisaraka suture separates rocks that were derived from different locations within, or at the margins of, the Mozambique Ocean basin and therefore, that the suture is the site of subduction of a strand of Mozambique Ocean crust.     

Coupled evolution of back-arc and island arc-like mafic crust in the late-Neoproterozoic Agardagh Tes-Chem ophiolite, Central Asia: evidence from trace element and Sr–Nd–Pb isotope data

. We report major-element, trace-element and isotopic data of volcanic rocks from the late-Neoproterozoic (570 Ma) Agardagh Tes-Chem ophiolite in Central Asia, south-west of Lake Baikal (50.5°N, 95°E). The majority of samples are high-alumina basalts and basaltic andesites having island-arc affinities. They were derived from an evolved parental magma (Mg#̾.60, Cr~180 ppm, Ni~95 ppm) by predominantly clinopyroxene fractionation. The parental magma developed from a primary mantle melt by fractionation of about 12% of an olivine+spinel assemblage. The island-arc rocks have high abundances of incompatible trace elements (light rare-earth element abundances up to 100 times chondritic, chondrite-normalised (La/Yb)_n=14.6-5.1) and negative Nb anomalies (Nb/La=0.37-0.62), but low Zr/Nb ratios (7-14). Initial )_Nd values are around +5.5, initial Pb isotopic compositions are ²⁰⁶Pb/²⁰⁴Pb=17.39-18.45, ²⁰⁷Pb/²⁰⁴Pb=15.49-15.61, ²⁰⁸Pb/²⁰⁴Pb=37.06-38.05. Enrichment of large-ion lithophile elements within this group is significant (Ba/La=11-130). Another group of samples consists of back-arc basin-related volcanic rocks. They are most likely derived from the same depleted mantle source as the island-arc rocks, but underwent higher degrees of melting (8-15%) and are not influenced by slab components. They have lower abundances of incompatible trace elements, flat rare-earth element patterns [(La/Yb)_n=0.6-2.4] and higher )_Nd values (+7.8 to +8.5). Negative Nb anomalies are absent (Nb/La=0.81-1.30), but Zr/Nb is high (21-48). At least three components are necessary to explain the geochemical evolution of the volcanic rocks: (1) an enriched (ocean island-like) component characterised by a high Nb concentration (up to 30 ppm), an absent negative Nb anomaly, a low Zr/Nb ratio (~6.5), a low )_Nd value (around 0), and radiogenic ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb; (2) a back-arc basin component similar to N-MORB with a flat rare-earth element pattern and a high )_Nd value (around +8.5); and (3) an island-arc component from a mantle source which was modified by the downgoing slab. Crystal fractionation superimposed on mixing and source contamination by subducted sediments is suitable to explain the observed geochemical data. The most likely geodynamic environment to produce these characteristics is a young, intra-oceanic island-arc system and an associated back-arc basin.