Establishing Holocene sediment core chronologies for northern Ungava lakes, Canada, using humic acids (AMS C) and Pb

The absence of datable macrofossils in six sediment cores recovered from northern Ungava (Canada) lakes constituted a major challenge for the establishment of reliable lacustrine chronologies for the Holocene. Consequently, AMS radiocarbon dating of humic acids was used to assess age–depth in the cores. The reliability of the radiocarbon results near some of the core tops was evaluated through ²¹⁰Pb dating. The offset of sediment radiocarbon ages with their most probable time of formation and deposition in the lakes was found to be in the order of about 1000 years for recently deposited sediments. However, the basal dates in one core covering the entire postglacial period yielded a remarkable fit with previously established dates performed on marine shells at the maximum marine limit. Hence, the aim of this study was to describe how the two dating methods can be combined to address some of the problems paleolimnologists face when trying to assign ages to high-latitude lake sediment records. Suggestions are made for improving the quality of age–depth models developed in future studies for northernmost Québec and other comparable regions where paleolimnologists must deal with the combined challenges of very slow sediment accumulation rates in lakes, an extreme paucity of datable material and the sequestration of old carbon in the watersheds.     

Sedimentology,palaeoenvironments and biostratigraphy of the Pliocene–Pleistocene carbonate platform of Grande‐Terre (Guadeloupe,Lesser Antilles forearc)

Pliocene and Pleistocene deposits from Grande‐Terre (Guadeloupe archipelago, French Lesser Antilles) provide a remarkable example of an isolated carbonate system built in an active margin setting, with sedimentation controlled by both rapid sea‐level changes and tectonic movements. Based on new field, sedimentological and palaeontological analyses, these deposits have been organized into four sedimentary sequences (S1 to S4) separated by three subaerial erosion surfaces (SB0, SB1 and SB2). Sequences S1 and S2 (‘Calcaires inférieurs à rhodolithes’) deposited during the Late Zanclean to Early Gelasian (planktonic foraminiferal Zones PL2 to PL5) in low subsidence conditions, on a distally steepened ramp dipping eastward. Red algal‐rich deposits, which dominate the western part of Grande‐Terre, change to planktonic foraminifer‐rich deposits eastward. Vertical movements of tens of metres were responsible for the formation of SB0 and SB1. Sequence S3 (‘Formation volcano‐sédimentaire’, ‘Calcaires supérieurs à rhodolithes’ and ‘Calcaires à Agaricia’) was deposited during the Late Piacenzian to Early Calabrian (Zones PL5 to PT1a) on a distally steepened, red algal‐dominated ramp that changes upward into a homoclinal, coral‐dominated ramp. Deposition of Sequence S3 occurred during a eustatic cycle in quiet tectonic conditions. Its uppermost boundary, the major erosion surface SB2, is related to the Cala1 eustatic sea‐level fall. Finally, Sequence S4 (‘Calcaires à Acropora’) probably formed during the Calabrian, developing as a coral‐dominated platform during a eustatic cycle in quiet tectonic conditions. The final emergence of the island could then have occurred in Late Calabrian times.     

Transformation of Irradiance Measurements into Spectral Actinic Flux for Photolysis Rates Determination

The actinic flux is the only radiometric quantity suitable for photolysisfrequency determination. It is derived from solar spectral irradiancemeasurements performed by a portable spectroradiometer in the 300–850nm wavelength range. The spectral irradiance is first divided into a directpart and a diffuse part, according to the atmospheric conditions, and thenconverted into the corresponding actinic flux quantity. As an intermediary,the ratio of diffuse actinic flux to diffuseirradiance is calculated by the spherical harmonics radiative code withrespect to wavelength, solar zenith angle, surface albedo, and aerosolproperties.The results of extensive sensitivity studies of asa function of the main atmospheric parameters are discussed and lead to theconclusion that aerosol optical depth is the major critical value for aprecise determination. The global algorithm totransform spectral irradiance into actinic flux is finally applied forphotodissociation rate calculations by convolution of the obtained actinicflux spectra with the absorption cross-sections and quantum yields of themolecule studied. Photolysis rates of different atmospheric photooxidants havebeen measured with this spectroradiometric method during the summers of 1993and 1994 in Brittany and in Portugal. The ozone and nitrogen dioxidephotodissociation rates obtained present a good agreement with thej(O₃) and j(NO₂) actinometerresults, for the same experimental conditions in Brittany.     

Lösmaterialackumulationer i blockhaven på Varangerhalvön i Nordnorge—en problemdis- kussion

Malmström, B. og Palmér, O.: Lösmaterialackumulationer i blockhaven på Varangerhalvön i Nordnorge—en problemdiskussion. Geografisk Tidsskrift 82: 82–87, Lund, 15. november 1982.

A type of mounds consisting of unconsolidated deposits mainly situated in blockfields is presented. Comparisons are made with pingo-like remnants in northern Scandinavia described by other authors.     

The formation of boundary clinopyroxenes and associated glass veins in type B1 CAIs

Abstract— We used focused ion beam thin section preparation and scanning transmission electron microscopy (FIB/STEM) to examine the interfacial region between spinel and host melilite for spinel grains in type B1 inclusions from the Allende and Leoville carbonaceous chondrites. Boundary clinopyroxenes decorating spinel surfaces have compositions similar to those of coarser clinopyroxenes from the same region of the inclusion, suggesting little movement after formation. Host melilite displays no anomalous compositions near the interface and late‐stage minerals are not observed, suggesting that boundary pyroxenes did not form by crystallization of residual liquid. Allende spinels display either direct spinel‐melilite contact or an intervening boundary clinopyroxene between the two phases. Spinel‐melilite interfacial regions in a Leoville B1 are more complex, with boundary clinopyroxene, as observed in Allende, but also variable amounts of glass, secondary calcite, perovskite, and an Mg‐, Al‐, OH‐rich and Ca‐, Si‐poor crystalline phase that may be a layered double hydrate. One possible scenario of formation for the glass veins is that open system alteration of melilite produced a porous, hydrated aggregate of Mg‐carpholite or sudoite + aluminous diopside that was shock melted and quenched to a glass. The hydrated crystalline phase we observed may have been a shocked remnant of the precursor phase assemblage, but is more likely to have formed later by alteration of the glass. In the mantle, boundary clinopyroxenes may have been crystallized from Ti‐rich liquids formed by the direct dissolution of perovskite and an associated Sc‐Zr‐rich phase or as a reaction product between dissolving perovskite and liquid. In the core, any perovskite and associated Ti‐enriched liquids that may have originally been present disappeared before the growth of boundary clinopyroxene, and the observed boundary clinopyroxene may have nucleated and grown from the liquid, along with the larger core clinopyroxene.     

Electron acceleration within coronal loops: A wave-particle process?

A simple model as given which aims at explaining how electrons could be accelerated within solar coronal loops due to their trapping by quasi-monochromatic whistler waves.Proceedings of the Second CESRA Workshop on Particle Acceleration and Trapping in Solar Flares, held at Aubigny-sur-Nère (France), 23–26 June, 1986.     

Évolution temporelle et architecture interne d'un banc sableux estuarien : la Longe de Boyard (littoral atlantique,France)

The evolution and the internal architecture of an estuary type sand ridge has been studied with a set of bathymetric data recorded during the last two centuries and with a dense grid of recent very high resolution seismic profiles. Bathymetric data of the so-called, Longe de Boyard sand ridge, displays sand losts due to wave and tide erosion. Internal geometry, through seismic profile analysis, indicates two main phases of deposition recording both, a recent high energy environment and an older low energy one, respectively. Such an evolution is believed to record changes in sedimentation processes mainly related to the end of the Holocene transgression (8 000–5 000 yr BP). To cite this article: É. Chaumillon et al., C. R. Geoscience 334 (2002) 119–126.