Stratigraphy of fossil pigments and Cladophora and its relationship with deposition of tephra in Lake Mývatn,Iceland

Fossil plant pigments and Cladophora fragments were analyzed in a 6.53 m long sediment profile from Lake Mývatn, Iceland, covering most of its history of about 2300 years. A decrease in myxoxanthophyll (produced by Cyanobacteria) with time and an increase in the benthic Cladophora reflects a gradual shift from planktonic to benthic primary production as water depth is reduced (to 3.15 m at the core site) because of sediment accumulation.Two periods of relatively high concentrations of myxoxanthophyll coincided with relatively frequent deposition of tephra (volcanic ash) but did neither conform with tectonic activity which might have changed the water level nor the available climatic record. Sediment depth, tephra content and percent undegraded chlorophyll (an indicator of pigment preservation) together could explain 56.7% of the variation in myxoxanthophyll. It is hypothesized that temporary increases in myxoxanthophyll resulted from periodic nutrient enrichment by fresh tephra deposited in the watershed or because tephra increased the erosion of organic soil in the water catchment area.Fluctuations in Cladophora show an inverse relationship with myxoxanthophyll in the uppermost 4 m of the core, and may result from a shading effect of planktonic Cyanobacteria on the phytobenthos or competition for nutrients released by the bottom sediments.     

Prograde and retrograde metamorphic fabrics – a key for understanding burial and exhumation in orogens (Bohemian Massif)

In the Orlica–?nie?nik Dome (NE Bohemian massif), alternating belts of orthogneiss with high‐pressure rocks and belts of mid‐crustal metasedimentary–metavolcanic rocks commonly display a dominant subvertical fabric deformed into a subhorizontal foliation. The first macroscopic foliation is subvertical, strikes NE–SW and is heterogeneously folded by open to isoclinal folds with subhorizontal axial planes parallel to the heterogeneously developed flat‐lying foliation. The metamorphic evolution of the mid‐crustal metasedimentary rocks involved successive crystallization of chlorite–muscovite–ilmenite–plagioclase–garnet, followed by staurolite‐bearing and then kyanite‐bearing assemblages in the subvertical fabric. This was followed by garnet retrogression, with syntectonic crystallization of sillimanite and andalusite parallel to the shallow‐dipping foliation. Elsewhere, andalusite and cordierite statically overgrew the flat‐lying fabric. With reference to a P–T pseudosection for a representative sample, the prograde succession of mineral assemblages and the garnet zoning pattern with decreasing grossular, spessartine and X_Fe are compatible with a P–T path from 3.5–5 kbar/490–520 °C to peak conditions of 6–7 kbar/～630 °C suggesting burial from 12 to 25 km with increasing temperature. Using the same pseudosection, the retrograde succession of minerals shows decompression to sillimanite stability at ～4 kbar/～630 °C and to andalusite–cordierite stability at 2–3 kbar indicating exhumation from 25 km to around 9–12 km. Subsequent exhumation to ～6 km occurred without apparent formation of a deformation fabric. The structure and petrology together with the spatial distribution of the metasedimentary–metavolcanic rocks, and gneissic and high‐pressure belts are compatible with a model of burial of limited parts of the upper and middle crust in narrow cusp‐like synclines, synchronous with the exhumation of orogenic lower crust represented by the gneissic and high‐pressure rocks in lobe‐shaped and volumetrically more important anticlines. Converging P–T–D paths for the metasedimentary rocks and the adjacent high‐pressure rocks are due to vertical exchanges between cold and hot vertically moving masses. Finally, the retrograde shallow‐dipping fabric affects both the metasedimentary–metavolcanic rocks and the gneissic and high‐pressure rocks, and indicates that the ～15‐km exhumation was mostly accommodated by heterogeneous ductile thinning associated with unroofing of a buoyant crustal root.     

Identification of potential subsidence related to pumping in the Almería basin (SE Spain)

Ground subsidence of detrital deposits in the Almería basin (SE Spain) was studied using the remote sensing technique of Differential Interferometry SAR (DInSAR). This basin is one of the most arid in Europe, receiving an average rainfall of 250 mm per year. Over the last 60 years the region has experienced an enormous agricultural and urban expansion, whose water demand has been largely supplied from groundwater, leading to the current situation of overexploitation of water resources. This paper outlines the likely relationship between groundwater abstraction and subsidence. To this end, 34 ERS and Envisat images, taken between 2003 and 2009, were analysed to estimate ground surface deformations, and hence, compared with water table variations measured in a number of piezometers in the basin. The analysis shows a clear parallelism between the variations in piezometric level and deformation of the ground surface. In addition, the zones of greatest subsidence coincide with those areas where groundwater abstractions are concentrated. Subsidence over the examined period varies from 10 to 30 mm, with extreme values as high as 50 mm, which translates to a rate of between 1·7 and 5 mm/year, reaching maximum rates of 8 mm/year at some points. Given such subsidence rates, damage to urban infrastructures are, for the moment, incipient. Copyright © 2011 John Wiley & Sons, Ltd.     

A Ta,Ti–rich oxide mineral assemblage from the Nancy beryl–columbite–phosphate granitic pegmatite,San Luis,Argentina

Mineralogy and Petrology - An assemblage of tantalite-(Mn), tantalian rutile, tapiolite-(Fe), titanowodginite, ferrotitanowodginite, and hydroxycalciomicrolite occurs in the Nancy granitic...     

A Fractal Interaction Model for Winding Paths through Complex Distributions: Application to Soil Drainage Networks

Water interacts with soil through pore channels putting mineral constituents and pollutants into solution. The irregularity of pore boundaries and the heterogeneity of distribution of soil minerals and contaminants are, among others, two factors influencing that interaction and, consequently, the leaching of chemicals and the dispersion of solute throughout the soil. This paper deals with the interaction of irregular winding dragging paths through soil complex distributions. A mathematical modelling of the interplay between multifractal distributions of mineral/pollutants in soil and fractal pore networks is presented. A Hölder path is used as a model of soil pore network and a multifractal measure as a model of soil complex distribution, obtaining a mathematical result which shows that the Hölder exponent of the path and the entropy dimension of the distribution may be used to quantify such interplay. Practical interpretation and potential applications of the above result in the context of soil are discussed. Since estimates of the value of both parameters can be obtained from field and laboratory data, hopefully this mathematical modelling might prove useful in the study of solute dispersion processes in soil.     

A 2000 year record of climate variations reconstructed from Haukadalsvatn,West Iceland

The sediment fill of Haukadalsvatn, a lake in northwest Iceland, preserves a record of environmental change since deglaciation, 13 ka ago. The rapid sedimentation rate over the past 2 ka (ca. 4 m ka⁻¹) provides a high-resolution archive of late Holocene environmental change. Physical and chemical environmental proxies extracted from cores from the Haukadalsvatn sediment fill provide a reconstruction of sub-decadal-scale climate variability in Iceland over the past 2 ka. Over this interval biogenic silica (BSi) reflects warm April–May temperatures, whereas total organic carbon (TOC) peaks represent an increased flux of carbon to the lake from eolian-derived soil erosion following periods of cold summers accompanied by dry, windy winters. The proxy-based temperature reconstructions show a broad interval of warmth through Medieval times, but this warmth is punctuated by multi-decadal cold intervals. The transition into the Little Ice Age occurred in two steps, with initial summer cooling 1250–1300 AD, and a more severe drop in summer temperatures between 1450 and 1500 AD; both are periods of severe explosive volcanism. Multi-decadal patterns of cold and warm conditions have some characteristics of a North Atlantic Oscillation (NAO)-like signal, but instrumental records and proxy-based reconstructions of the NAO index contain little power in the frequencies most strongly expressed in our data set. Although severe soil erosion in Iceland is frequently equated with settlement, our reconstructions indicate that soil erosion began several centuries before settlement, whereas for several centuries after settlement, when summer temperatures were relatively high, there was little or no soil erosion. Only during the transition into and during the Little Ice Age did soil erosion become a major feature of the record. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

ADM1‐Based Robust Interval Observer for Anaerobic Digestion Processes

A robust state estimation scheme is proposed for anaerobic digestion (AD) processes to estimate key variables under the most uncertain scenarios (namely, uncertainties on the process inputs and unknown reaction and specific growth rates). This scheme combines the use of the IWA Anaerobic Digestion Model No. 1 (ADM1), the interval observer theory and a minimum number of measurements to reconstruct the unmeasured process variables within guaranteed lower and upper bounds in which they evolve. The performance of this robust estimation scheme is evaluated via numerical simulations that are carried out under actual operating conditions. It is shown that under some structural and operational conditions, the proposed robust interval observer (RIO) has the property of remaining stable in the face of uncertain process inputs, badly known kinetics and load disturbances. It is also shown that the RIO is indeed a powerful tool for the estimation of biomass (composed of seven different species) from a minimum number of measurements in a system with a total of 32 variables from which 24 correspond to state variables.